Handbook of Inorganic and Organometallic Chemistry / S. Schwefel. Sulfur. (System-Nr. 9) / S-Sulphur-Nitrogen Compounds. S-N-Verbindungen / Compounds with Sulfur of Oxidation Number II

Norbert Baumann, Hans J Fachmann, Reimund Jotter, Alfons Kubny, Gmelin (Autoren)

Buch | Hardcover

XXIV, 323 Seiten

1994 | 8., Aufl.
Springer Berlin (Verlag)
9783540937012 (ISBN)

Infos

This volume treats the acyclic sulfur(II)-nitrogen compounds with one-coordinate and two-coordinate sulfur. Sulfur imide (S=NH) and N-organyl-sulfur imides (S=NR) are unstable compounds which can be stabilized by coordination to transition metals or trapped, for example, by Ä2 + 4Ü cycloaddition with 1,3-butadiene. Among dithionitryl (1+) salts, only ÄS=N=SÜ+AsF6- has been studied extensively. Cycloaddition with alkenes and triple bond compounds produce 1,3,2-dithiazolium salts. Thiohydroxylamine, HSNH2, has been detected in the gas phase. Numerous examples of N,N-diorganyl-amino-halogeno-sulfanes (XSNR2, X = F, Cl, Br, I; R = organyl) and salts of the cation (XS)2N+ (X = Cl, Br) are known. N,N-Diorganyl-amino-chloro-sulfanes are important synthetic reagents.

Produkt-Details

• Reihe/Serie: Handbook of Inorganic and Organometallic Chemistry ; Part 10 / Part a | 1.1300
• Mitarbeit: Chef-Herausgeber: Alfons Kubny
• Sprache: englisch
• Gewicht: 905 g
• Einbandart: gebunden
• Themenwelt: Naturwissenschaften ► Chemie ► Anorganische Chemie
• Schlagworte: HC/Chemie/Anorganische Chemie
• ISBN-13: 9783540937012 / 9783540937012
• Zustand: Neuware