S Sulfur-Nitrogen Compounds

Part 10a: Compounds with Sulfur of Oxidation Number II

Norbert Baumann, Hans-Jürgen Fachmann, Reimund Jotter, Alfons Kubny (Autoren)

Buch | Softcover

XXIV, 324 Seiten

2013 | 8. Eighth Edition 1994
Springer Berlin (Verlag)
9783662063538 (ISBN)

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The present volume describes acyclic Sulfur-nitrogen compounds with sulfur of the oxida tion number II. The first chapter deals with sulfur imide (S=NH), N-organyl-sulfur imides (S=NR, R = or ganyl), and metal complexes of sulfur imides. N-Organyl-sulfur imides have not been isolated, but they can be trapped, for example, by cycloaddition and stabilized by coordination to transi tion metals. 11 The following chapter present a detailed survey of other 8 -N compounds with one coordinate sulfur, e.g., dithionitrous acid (S=N-SH) and derivatives, the salts of the dithionitryl ion (1 +) ([S=N=S]+), and N-thionitroso-diorganyl-amines (S=NNR , R = organyl). Only the reac 2 tions of [S=N=S]+ AsF5, among the known [S=N=S]+ salts, have been extensively studied. Cycloadditions with alkenes and triple bonded compounds produce 1 ,3,2-dithiazolium salts and their derivatives. S=NN(CH )z and S=NN(C H )z form transition metal complexes. The 3 6 5 Iigand is coordinated via the S atom in a monodentate manner.

1 Sulfur Imide and Derivatives.- 2 Disulfur Nitride, Nitrogen Disulfide, SNS.- 3 Dithionitrous Acid and Derivatives.- 4 Salts of the Dithionitryl Ion (1+), [S=N=S]+.- 5 Dinitrogen Sulfide, SNN.- 6 N-Thionitroso-diorganylamines and Derivatives.- 7 Thiohydroxylamine and Derivatives.- 8 Thiooximes and Derivatives.- 9 Thiofulminic Acid and Derivatives.- 10 Isohypothiocyanous Acid Ion (1?), OCNS?.- 11 Thionitrous Acid and Derivatives.- 12 Sulfur Amide Halogenides and Derivatives.- 13 Sulfur Amide Hydroxide Derivatives, N,N-Substituted Amino-organyloxy-sulfanes.- 14 S-Phosphorus-Substituted Thiohydroxylamines and Derivatives.- Physical Constants and Conversion Factors.

Erscheint lt. Verlag	3.10.2013
Reihe/Serie	Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition
Reihe/Serie	S. Schwefel. Sulfur (System-Nr. 9)
Mitarbeit	Chef-Herausgeber: Alfons Kubny
Zusatzinfo	XXIV, 324 p. 1 illus. in color.
Verlagsort	Berlin
Sprache	englisch
Maße	178 x 254 mm
Gewicht	669 g
Themenwelt	Naturwissenschaften ► Chemie ► Allgemeines / Lexika
Themenwelt	Naturwissenschaften ► Chemie ► Anorganische Chemie
Schlagworte	Hydroxylamin • metals • Transition metal
ISBN-13	9783662063538 / 9783662063538
Zustand	Neuware