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Handbook of Energy Materials in Supercapacitors and Storage Devices -

Handbook of Energy Materials in Supercapacitors and Storage Devices

Buch | Hardcover
640 Seiten
2026
Wiley-Scrivener (Verlag)
978-1-119-90103-7 (ISBN)
CHF 318,90 inkl. MwSt
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Accelerate your understanding of modern energy storage with this one-stop resource that provides a comprehensive guide to the basics, materials, and recent advancements in high-efficiency supercapacitor technology.

The increasing population, environmental pollution, and growing demand for energy underscores the importance of highly efficient energy storage devices. Supercapacitors, often referred to as ultracapacitors, have emerged as a pivotal technology in the realm of energy storage. Increasing demand for supercapacitors arises from the high energy density required by various modern applications like electric vehicles, UPS systems, wind turbines, space vehicles, regenerative braking, load leveling systems, etc. The above-mentioned applications require an improvement in working voltage (by preventing/reducing reaction between electrode and electrolyte surface), specific capacitance, and energy density (by increasing the surface area, addition of transition metal oxides/conducting polymers, etc.) of the existing supercapacitors. Global research is directed towards blending the high energy density of batteries with the high-power density of traditional capacitors, thereby enabling the supercapacitors to be ideal for applications demanding rapid charge and discharge cycles, high power output, and long cycle life.

This book is designed to cover the basics of supercapacitors and provide a current account of the recent advances in this field. It provides the basics of various materials, different stages of growth in this field, and recent developments, making it a one-stop resource for understanding and advancing the field of supercapacitor technology.

Readers will find in the volume;



A detailed explanation of the electrochemical processes and energy storage mechanisms in supercapacitors, with a detailed introduction to supercapacitors;
A comprehensive review of various electrode materials, including carbon-based materials, metal oxides, and conducting polymers;
A detailed discussion on different electrolyte types (aqueous, organic, and ionic liquids) and their impact on supercapacitor performance;
An exploration of the design considerations and manufacturing techniques for supercapacitors.

Audience

The book will be a valuable resource for researchers, engineers, and industry professionals involved in various fields, including electronics, automotive, renewable energy, and grid storage.

C. Sarathchandran, PhD is an assistant professor in the Department of Science, Amrita School of Engineering, Amrita Vishwa Vidyapeetham, Chennai, Tamil Nadu, India. His doctoral thesis centered around the development of epoxy resin poly- (trimethylene terephthalate) based blend systems for aerospace applications. His research interests include the development of supercapacitors, batteries, and aerogels for various applications. S. A. Ilangovan, PhD is the Deputy Director at the Vikram Sarabhai Space Center, Trivandrum, Kerala, India, with more than 20 years of research experience in supercapacitors and batteries. He has published more than 20 research articles, ten patents, and one book. Sabu Thomas, PhD is the former Vice-Chancellor at Mahatma Gandhi University, and currently at the International and Inter University Centre for Nanoscience and Nanotechnology, Mahatma Gandhi University, Kottayam, Kerala, India, as well as the Department of Physics and Electronics, CHRIST (Deemed to be University), Bengaluru, Karnataka, India. He has published more than 80 books, 750 research articles, and several patents.

Preface xv

1 Introduction to Supercapacitors 1
Shebin Stephen, S. A. Ilangovan, Sujatha S., Bibin John, Ajeesh K. S. and C. Sarathchandran

1.1 Introduction 1

1.2 Conclusion 8

1.3 Acknowledgement 8

2 Electric Double-Layer Capacitors 11
Phuoc Anh Le

2.1 Introduction to Electric Double-Layer Supercapacitors 11

2.2 General Principles and Related Theories 12

2.3 Designing of Electric Double-Layer-Based Supercapacitors 15

2.4 Applications 17

2.5 Recent Developments 18

2.6 Conclusions 24

3 Electrochemical Supercapacitors Based on Pseudocapacitance 35
Renu Dhahiya, Dinesh, Mukul Gupta, Parasmani Rajput, Pankaj Sharma and Ashok Kumar

3.1 Introduction 36

3.2 Theory of Pseudocapacitance 37

3.3 Design and Fabrication of Pseudocapacitors 39

3.4 Self-Discharge and Potential Recovery in Pseudocapacitors 43

3.5 Recent Advances in Pseudocapacitors 47

3.6 Application 53

3.7 Future Trends 55

4 Porous Carbon-Based Materials for Supercapacitor Applications 65
Deeksha Nagpal, Anup Singh, Ajay Vasishth, Subha Pratihar, Ashok Kumar and Shyam Sundar Pattnaik

4.1 Introduction 66

4.2 Mechanism of Charge Storage in Carbon-Based Materials 67

4.3 Self-Discharge and Potential Decay in Carbon‑Based Materials 70

4.4 Carbon-Derived from Various Sources and their Performance Evaluations 74

4.5 Recent Trends and Future Applications of Carbon-Based Material for Supercapacitors 78

5 Porous Activated Carbon-Based Materials for Supercapacitor Applications 91
Surendra K. Martha, Sadananda Muduli and Tapan K. Pani

5.1 Introduction 92

5.2 Charge Storage Mechanism in Porous Carbon-Based Supercapacitors 93

5.3 Self-Discharge and Potential Decay in Carbon‑Based Materials 100

5.4 Carbon Derived from Various Sources and Their Performance Evaluation 104

5.5 Recent Trends and Future Applications 118

6 Biomass-Based Carbon Nanomaterials for Energy Storage 129
Debajani Tripathy, Bibhuti B. Sahu, Ankita Subhrasmita Gadtya and Srikanta Moharana

6.1 Introduction 130

6.2 Overview of Carbon-Based Nanostructured Materials 132

6.3 Synthesis of Carbon-Based Nanostructure Materials 133

6.4 Synthetic Approach for Biomass-Derived Carbon 134

6.5 Surface Alternation of Carbon Nanostructured Materials 137

6.6 Biomass-Derived Carbon for Energy Conversion and Storage Systems 141

6.7 Future Challenges 154

6.8 Conclusions 155

7 Carbon Nanotube as Electrode Material for Supercapacitors 161
Sanjeev Verma, Tapas Das, Shivani Verma, Vikas Kumar Pandey, Saurabh Kumar Pandey, Juhi Singh and Bhawna Verma

7.1 Introduction 162

7.2 CNT (Carbon Nanotube) 162

7.3 Supercapacitor Electrodes Using Carbon Nanotube 164

7.4 Summary 168

8 Graphene-Based Polymeric Composites with Potential Applications in Supercapacitors 175
Ankita Subhrasmita Gadtya, Debajani Tripathy and Srikanta Moharana

8.1 Introduction 176

8.2 Overview of Graphene-Polymer Composites 178

8.3 Supercapacitors 183

8.4 Graphene-Based Different Polymeric Composites 187

8.5 Graphene-Based Fluoropolymer Composites for SCs 187

8.6 Graphene-Based Conducting Polymer Composites for SCs 191

8.7 Conclusions 194

9 Graphene-Based Materials for Supercapacitor Applications 203
Vikas Kumar Pandey and Bhawna Verma

10 Metal Oxides and Their Role in Pseudocapacitors 219
Rutuja A. Chavan and Anil V. Ghule

10.1 General Introduction 220

10.2 Role of Metal Oxides 224

10.3 Different Types of Metal Oxides Explored in Supercapacitors 225

10.4 Performance Evaluation 226

10.5 Future Scope 242

11 Advances in Design and Application of Nanostructured TMOs and Their Composites for High‑Performance Supercapacitors 255
Sheng Qiang Zheng, Siew Shee Lim, Maxine Swee-Li Yee, Chuan Yi Foo, Choon Yian Haw, Wee Siong Chiu, Chin Hua Chia and Poi Sim Khiew

11.1 Introduction 256

11.2 Electrochemical Role of Metal Oxides 260

11.3 Different Types of Metal Oxides as Electrode Materials 264

11.4 Performance Parameters of Electrochemical Capacitors 281

11.5 Conclusion and Future Perspectives 284

12 Ceramic Oxide Based Supercapacitors 295
Thangavelu Kokulnathan, Sabarison Pandiyarajan, Balasubramanian Sriram and Shobana Sebastin Mary Manickaraj

Introduction 296

Metal Oxide Ceramics 296

Vanadium Oxide 300

Manganese Oxide 301

Iron Oxide 303

Cobalt Oxide 304

Nickel Oxide 305

Aluminum Oxide 305

Spinel Oxide Ceramics 307

Multi-Elemental Oxide Ceramic 309

Past, Current, and Future Progress 310

13 Conductive Polymers and Composites for Supercapacitors: Recent Trends and Future Scope 325
Silki Sardana, A.S. Maan and Anil Ohlan

13.1 Introduction 325

13.2 CPs for Supercapacitors 328

13.3 CP-Based Composites for Supercapacitors 332

13.4 Recent Trends on CP-Based Supercapacitors 334

13.5 CP-Based Flexible Supercapacitors 339

13.6 Future Scope of CP-Based Supercapacitors 342

13.7 Conclusions 342

14 Graphitic Carbon Nitride (g-C3N4)-Based Materials for Supercapacitor Applications 351
Himadri Tanaya Das, Swapnamoy Dutta, Elango Balaji T., Payaswini Das and Nigamananda Das

14.1 Introduction 352

14.2 Different Carbon Materials as Electrodes in Supercapacitors 353

14.3 g-C3N4  as Electrode Material in Supercapacitor 355

14.4 g-C3N4  Composites and Their Use as Supercapacitors 358

14.5 Future Prospects 362

14.6 Conclusion 363

15 Introduction to MXenes for Supercapacitor Applications 371
Selcan Karakuº and Razium Ali Soomro

15.1 Introduction 372

15.2 Strategies for the Synthesis of 2D MXenes 374

15.3 MXene-Based Supercapacitors 378

15.4 Concluding Remarks and Future Perspectives 381

16 MXenes for Supercapacitor Applications 387
Mayank K. Singh, Sarathkumar Krishnan and Dhirendra K. Rai

16.1 Introduction 388

16.2 Synthesis Technique 390

16.3 Bottom-Up Techniques 393

16.4 Properties of MXenes 393

16.5 MXenes and Its Composites 395

16.6 MXenes in Various Electrolytes 403

16.7 Challenges and Future Perspectives 404

17 Hybrid Supercapacitors: Recent Trends and Future Scope 415
Basudeba Maharana, Rajan Jha and Shyamal Chatterjee

17.1 Introduction 416

17.2 Types of Hybrid Supercapacitors 417

17.3 Components of Hybrid Supercapacitors 419

17.4 Recent Trends in HSCs 423

17.5 Future Scopes and Challenges 431

17.6 Conclusions 435

18 Electrolytes and Their Role in Supercapacitor Technology 445
Dipanwita Majumdar, Padma Sharma and Niki Sweta Jha

18.1 Introduction 446

18.2 Classes of Electrolytes for Supercapacitors 450

18.3 Conclusions and Outlooks 476

19 Designing Supercapacitors and Supercapacitor Materials by Counting Ions 497
Shrisudersan Jayaraman

19.1 Introduction 498

19.2 Theoretical Framework 499

19.3 Experimental Results and Discussion 528

19.4 Conclusions and Summary 534

19.5 Appendix: Experimental Details 537

20 Global Market, Applications, and Leading Suppliers for Supercapacitors: An Introduction 543
Shebin Stephen George and C. Sarathchandran

20.1 Introduction to the Global Market of Supercapacitors 543

20.2 Applications of Supercapacitors 545

20.3 Safety Issues Associated with Supercapacitors 549

20.4 Conclusion 549

21 Applications of Supercapacitor 553
Raunak Pandey, Santhosh G., Sarvajith Malali Sudhakara, Nannan Wang and Santosh K. Tiwari

21.1 Introduction 554

21.2 Energy-Harvesting Sources 555

21.3 Applications of Supercapacitors 559

21.4 Transport 576

21.5 Medical 586

21.6 Industrial 589

21.7 Military 591

21.8 Conclusion 593

Bibliography 593
Index 611

Erscheinungsdatum
Sprache englisch
Themenwelt Technik Maschinenbau
ISBN-10 1-119-90103-0 / 1119901030
ISBN-13 978-1-119-90103-7 / 9781119901037
Zustand Neuware
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