Layered Double Hydroxides and Oxides
John Wiley & Sons Inc (Verlag)
9781394264308 (ISBN)
Layered Double Hydroxides and Oxides delivers a first-of-its-kind and highly thorough overview of layered double hydroxides (LDHs) and layered double oxides (LDOs) in the context of catalysis, highlighting the distinctive structure-activity properties inherent in LDH- and LDO-based catalytic nanomaterials with emphasis on materials design, synthesis, and characterization as well as sustainable applications including batteries, solar fuels, fossil fuels, biomass, fossil chemical conversions, and environmental remediations of pollutants.
Layered Double Hydroxides and Oxides includes information on:
Physicochemical, optical, and electronic properties and synthesis with controlled structure properties.
Water splitting for hydrogen generation, electrocatalytic fuel cells, energy storage in sodium-ion batteries, and methane-reforming syngas generation and conversion.
Photocatalytic and electrocatalytic CO2 reduction, catalytic fixation of nitrogen, and conversion of biomass to chemicals and fuel.
Removal of organic wastewater pollutants, gas chemical sensing and detection, and antimicrobial and antibacterial disinfectants.
Layered Double Hydroxides and Oxides is an excellent reference on the subject for academic researchers and professional engineers/scientists working in the research and development areas of inorganic chemistry and catalysis, materials science, advanced nanomaterials, environmental science, solar energy, fossil energy conversion, batteries and energy storage.
Dr. Peter R. Makgwane is a Full Professor at the University of South Africa (UNISA) Institute of Catalysis and Energy Solutions (ICES). His research focuses on catalysis for green and sustainable processes. Dr. Ram K. Gupta is an Associate Vice President for Research and Support and a Professor of Chemistry at Pittsburg State University. He was recently named by Stanford University as being among the top 2% of research scientists worldwide.
About the Editors xvii
List of Contributors xix
Preface xxvii
Part I Introduction and Fundamentals 1
1 Layered Double Hydroxides and Oxides – An Introduction and Scope of Applications 3
Katekani Shingange and Peter R. Makgwane
1.1 Introduction 3
1.2 Classification and Basic Properties of Layered Double Hydroxides and Oxides 4
1.3 Application Scope of LDHs and LDOs in Catalytic-Driven Technologies 6
1.4 Conclusion 13
References 13
2 Structure Aspects of Layered Double Hydroxides and Oxides: Physicochemical, Optical, and Electronic Properties 19
Jodinio Lemena, Nkhosikhona Dlamini, Rethabile Makole, Hendrik C. Swart, Richard A. Harris, Jacobus J. Terblans, Peter R. Makgwane, and David E. Motaung
2.1 Introduction 19
2.2 Structure Properties of LDHs and LDOs 20
2.3 Effect of Synthesis Method and Morphology on the Physicochemical, Electronic, and Optical Properties 31
2.4 Conclusion 33
References 33
3 Synthesis of Layered Double Hydroxides and Oxides Catalysts with Controlled Structure Properties 43
Aditi De and Subrata Kundu
3.1 Introduction 43
3.2 Fundamentals of Layered Double Hydroxides and Oxides 44
3.3 Synthesis and Strategic Approaches for LDHs and LDOs 48
3.4 Challenges, Recent Advances, and Future Perspectives in Synthesis Techniques 64
3.5 Conclusion 69
3.6 Acknowledgments 70
References 70
Part II Energy Generation and Storage 75
4 Layered Double Hydroxides and Oxides Catalysts in Photocatalytic Water Splitting for Hydrogen Generation 77
Kriti Shrivastava and Ankur Jain
4.1 Introduction 77
4.2 Structure of Layered Double Hydroxides and Oxides 79
4.3 LDH/LDO-Based Photocatalyst for Hydrogen Production by Water Splitting 80
4.4 LDHs Materials in Photocatalytic Water Splitting H 2 Production 81
4.5 Conclusion 90
References 91
5 Photoelectrochemical Hydrogen Production via Water Splitting with Layered Double Hydroxides and Oxides Catalysts 99
Yogita Dahiya, Ankur Jain, and Debasish Sarkar
5.1 Introduction 99
5.2 Photoelectrochemical Water Splitting 100
5.3 Layered Double Hydroxides 105
5.4 Conclusion 119
References 120
6 Electrocatalytic Fuel Cells Based on Layered Double Hydroxides and Oxides 127
Bhawna Rathi, Monika Shrivastav, Rajnish Dhiman, Ankur Jain, and Manoj Kumar
6.1 Introduction 127
6.2 Selection Standards to Choose Electrocatalysts, Support, and Their Mechanism 131
6.3 Layered Double Hydroxides Electrocatalysts in Fuel Cells Applications 135
6.4 Layered Double Hydroxides Electrocatalysts in Fuel Cells Applications 143
6.5 Industrial Perspective of Fuel Cell Technology and the Context of LDHs/LDOs 145
References 147
7 Layered Double Hydroxides and Oxides Electrocatalysts for the Generation of Hydrogen 151
Suprobhat Singha Roy and Subrata Kundu
7.1 Introduction 151
7.2 Structure of LDHs and Their Electrocatalytic Properties for Hydrogen Production 152
7.3 Types of Metal Oxides and Their Impact on Electrochemical Hydrogen Production 153
7.4 Water Splitting Mechanism 154
7.5 Strategies to Develop Catalysts for HER and OER 158
7.6 LDH Materials for Water Splitting Application 159
7.7 Recent Development of Metal Oxides for Water Splitting Application 165
7.8 Other Strategies Counter to HER 169
7.9 Challenges and Solutions 172
7.10 Conclusion and Future Perspective 173
Acknowledgments 173
References 173
8 Layered Double Hydroxides and Oxides for Energy Storage in Sodium-Ion Batteries 179
Prajakta Dattakumar Dange and Pratap Kollu
8.1 Introduction 179
8.2 Layered Double Hydroxides 180
8.3 Layered Double Oxides 189
8.4 Conclusion 192
References 193
9 Layered Double Hydroxides and Oxides Catalysts in Methane Reforming, Syngas Generation, and Conversion 197
Jodinio Lemena, Peter R. Makgwane, and David E. Motaung
9.1 Introduction 197
9.2 Overview of Methane and Syngas Conversion Processes 198
9.3 Application of LDHs and LDOs in Methane and Syngas Conversions 202
9.4 Catalysts Stability, Deactivation, and Regenerations 210
9.5 Industrial Perspective of LDHs and LDOs Catalysts in Methane and Syngas Conversions 210
9.6 Conclusion 211
Acknowledgments 211
References 211
Part III Chemical Conversionsenergy Generation and Storage 219
10 Layered Double Hydroxide and Oxide Catalysts in Thermocatalytic Hydrogenation of CO 2 to Chemicals 221
Sivuyisiwe Mapukata, Nyiko Chauke, Andile Mkhohlakali, William Moloto, Reagan Mohlala, Mpho Ledwaba, and Mpfunzeni Raphulu
10.1 Introduction 221
10.2 Overview of CO 2 Hydrogenation Using LDHs and LDOs 222
10.3 Thermo-catalytic Hydrogenation of CO 2 Using LDH and LDO Catalysts 224
10.4 Photocatalytic Hydrogenation of CO 2 to Chemicals Using LDH and LDO Catalysts 229
10.5 CO 2 Hydrogenation Enhancement Strategies 234
10.6 Conclusions 236
Acknowledgments 237
References 237
11 Layered Double Hydroxides Catalysts in Photocatalytic CO 2 Reduction to Chemicals 247
Dhivya Sundar, Sambandam Anandan, Cheng-Hua Liu, and Jerry J. Wu
11.1 Introduction 247
11.2 Structure and Synthesis of LDH 249
11.3 LDHs for Photocatalytic CO 2 Reduction 250
11.4 Conclusion 260
Acknowledgment 261
References 261
12 Layered Double Hydroxides and Oxides for Electrocatalytic CO 2 Reduction to Chemicals 269
Shailendra K. Jha, Niki S. Jha, Alka Kumari, and Rehash Ranjan
12.1 Introduction 269
12.2 Fundamental Aspects and Challenges of Electrocatalytic CO 2 Reduction 270
12.3 LDHs as Electrocatalyst for CO 2 Reduction Reaction 273
12.4 Oxides as Electrocatalyst for CO 2 Reduction Reaction 279
12.5 Conclusions 285
References 286
13 Photo (Electro) Catalytic Fixation of Nitrogen with Layered Double Hydroxides and Oxides Catalysts 295
Rehash Ranjan and Shailendra K. Jha
13.1 Introduction 295
13.2 Benefits and Challenges of Photo (Electro) Catalytic N 2 Reduction 297
13.3 Mechanistic Aspects of Photo (Electro) Catalytic N 2 Fixation Reactions 298
13.4 Essential Activity Descriptors for N 2 Fixation 300
13.5 LDHs and LDOs Catalysts for N 2 Fixation 301
13.6 LDH Design Strategies for Enhanced Photo (Electro) Catalytic N 2 Fixation 307
13.7 Conclusions 309
References 310
14 Layered Double Hydroxides and Oxides in Photocatalytic Organic Chemical Conversions 317
David M. Mabena, Tumisang Lekgetho, and Mabuatsela V. Maphoru
14.1 Introduction 317
14.2 Mechanisms of LDH-Based Photocatalytic Reaction 319
14.3 Oxidation Reactions 321
14.4 Hydrogenation Reactions 326
14.5 Coupling and Esterification Reactions 331
14.6 Conclusions 335
References 336
15 Layered Double Hydroxide-Based Catalysts for Conversion of Biomass to Chemicals and Fuels 343
Qian Wang, Huifang Wu, Yang Zhao, Xuanlin Guo, Xinlan Zhang, and Junting Feng
15.1 Introduction 343
15.2 LDHs Catalysts in Oxidation Reactions 345
15.3 LDHs Catalysts in Hydrogenation Reactions 348
15.4 LDHs Catalysts in Cyclization Reactions 354
15.5 Reductive Amination 356
15.6 Catalytic Steam-Reforming of Biomass 361
15.7 LDHs Catalysts in Catalytic C—C Coupling of Biomass 363
15.8 Conclusion and Future Perspectives 365
References 367
Part IV Environmental Applications 375
16 Layered Double Hydroxides Photocatalysts for Degradation Organic Pollutants 377
Rajesh Sahu, Tarun Patodia, and Ankur Jain
16.1 Introduction 377
16.2 Properties and Synthesis of LDHs 379
16.3 Mechanism of LDH as a Photocatalyst 381
16.4 LDHs in Photocatalytic Degradation of Organic Pollutants 381
16.5 Conclusion 391
Acknowledgment 391
References 392
17 Layered Double Hydroxides and Oxides Catalysts for Fenton and Persulfate-Driven Removal of Organic Wastewater Pollutants 401
Michael B. Mensah, Prince Asante, Julius R. Ogbey, Benjamin Kokloku, Nathaniel N. Nubuor, Isaac Aidoo, Wisdom Dzansi, and Nathaniel O. Boadi
17.1 Introduction 401
17.2 Advanced Oxidation Processes 402
17.3 LDHs and LDOs 403
17.4 Catalytic Mechanisms in Fenton-Like Reactions 404
17.5 Catalytic Mechanisms in Persulfate Activation 405
17.6 Comparative Analysis of LDHs and LDOs in Fenton and Persulfate Reactions 406
17.7 Applications in Organic Pollutant Removal 411
17.8 Challenges and Future Perspectives 413
17.9 Innovations in LDH/LDO Design for Enhanced Catalysis 415
17.10 Prospects for Integrating LDHs/LDOs with Other Treatment Technologies 418
17.11 Conclusion 419
References 419
18 Layered Double Hydroxide and Oxide Catalysts for Remediation of Gaseous Air Pollutants 429
Katekani Shingange, Nyiko Chauke, Mandla Chabalala, Sivuyisiwe Mapukata, and Teboho Mokhena
18.1 Introduction 429
18.2 Overview of LDHs and Oxide Catalysts 430
18.3 Evolution of Catalysts for Air Pollution Control 431
18.4 Gaseous Air Pollutants 432
18.5 Mechanisms of Catalytic Remediation 433
18.6 Applications and Performance Evaluation of LDH Catalysts 438
18.7 Challenges and Future Directions 443
18.8 Conclusion 446
Acknowledgments 447
References 447
19 Layered Double Hydroxide Adsorbents for Removal of Metal Ions from Water Contaminants 459
Peyman Ghorbani, Aydin Hassani, Alireza Abbasi, and Paria Eghbali
19.1 Introduction 459
19.2 LDHs Fundamental, Structure, and Functionalization 461
19.3 LDHs Properties 469
19.4 Mechanism and Application of LDHs in Adsorption of Metal Ions from Water 471
19.5 Recyclability, Desorption, and Regeneration 479
19.6 Conclusions 485
References 486
20 Layered Double Hydroxides Catalytic Materials in Gas Chemical Sensing and Detection 497
Thabang J. Theka, Ratshilumela S. Dima, Themba Ntuli, Pontsho S. Mbule, Tlabo C. Leboho, and Katekani Shingange
20.1 Introduction 497
20.2 Overview of LDHs 498
20.3 Modification of LDHs for Gas Sensing 499
20.4 Gas Sensing Performance of LDH-Based Materials 501
20.5 Conclusion 507
References 508
21 Layered Double Hydroxides and Their Antimicrobial and Antibacterial Catalytic Activity Disinfections 515
Pratiksha Pise, Revanasiddappa Moolemane, Suresh Babu Naidu Krishna, and Peter R. Makgwane
21.1 Introduction 515
21.2 Mechanisms Underlying Antimicrobial Action 517
21.3 Antibacterial Activity of LDHs 519
21.4 Disinfection Applications of LDHs 521
21.5 Toxicity and Safety Considerations 522
21.6 LDHs in Photocatalytic Antimicrobial Disinfection 525
21.7 LDHs in Photocatalytic Antibacterial Disinfection 525
21.8 Conclusions 527
References 528
Index 531
| Erscheinungsdatum | 13.12.2025 |
|---|---|
| Verlagsort | New York |
| Sprache | englisch |
| Gewicht | 680 g |
| Themenwelt | Naturwissenschaften ► Chemie |
| ISBN-13 | 9781394264308 / 9781394264308 |
| Zustand | Neuware |
| Informationen gemäß Produktsicherheitsverordnung (GPSR) | |
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