Handbook of Reagents for Organic Synthesis (eBook)

Reagents for Heteroarene Synthesis

André B. Charette (Herausgeber)

eBook Download: PDF

2017
John Wiley & Sons (Verlag)
9781118704882 (ISBN)

Infos

The Handbook is a compilation of 99 articles on diverse reagents and catalysts that describe the synthesis of heteroarenes, the building blocks of a wide range of chemicals used in pharma and chemical industries. Articles are selected from the e-EROS database and edited to make sure that it includes only the material relevant to the topic of the book and focus on the synthetic aspects. This makes the articles very focused on the needs of readers wanting information on specific syntheses of specific heteroarenes. In addition, the chemistry of each “parent heteroarene” is also included to ensure that the reader rapidly finds important information.

The Handbook is a part of the Handbook of Reagents for Organic Chemistry series, aiming at collecting articles on a particular theme that individual researchers in academia or industry can use on a daily basis.

André B. Charette
Université de Montréal, Montréal, Canada

Inhalt

Handbook of Reagents for Organic Synthesis: Reagents for Heteroarene Synthesis 1
Contents 9
Preface 11
Introduction 13
Recent Review Articles and Monographs 15
Short Note on InChIs and InChIKeys 19
General Abbreviations 21
A 23
Acetaldoxime 23
Acetone Hydrazone 29
Acetonitrile 33
Acetonitrile N-Oxide 40
N-Aminophthalimide 41
1-Amino-pyridinium iodide 46
Ammonium Nitrate 49
Ammonium Acetate 51
Ammonium Bicarbonate 52
B 55
Benzonitrile N-Oxide 55
Benzoyl Isothiocyanate 58
N-[Bis(methylthio)methylene]-p-toluenesulfonamide 59
Bromoacetone 69
1-tert-Butyloxycarbonyl-1-methylhydrazine 74
C 79
2-Chloro-1,3-dimethylimidazolinium chloride 79
Copper(I) Chloride 83
Copper(II) Chloride 97
Copper(I) Iodide 105
Copper(II) Sulfate 115
Copper(II) Trifluoromethanesulfonate 126
Cyclopentadienylbis(triphenylphosphine)cobalt(I) 137
D 141
(Diacetoxyiodo)benzene 141
Diaminomaleonitrile 150
Diazo(trimethylsilyl)methyllithium 151
Dibromoformaldehyde Oxime 157
Dichloro Bis(acetonitrile) Palladium 159
Dichlorobis(triphenylphosphine)-palladium(II) 174
Di-?-chlorodichlorobis[(1,2,3,4,5-..)-1,2,-3,4,5- pentamethyl-2,4-cyclopentadien-1-yl]diiridium 186
2,3-Dichloro-5,6-dicyano-1,4-benzoquinone 194
Dichloroformaldehyde Oxime 206
Dichlorotris(triphenylphosphine)ruthenium(II) 208
(Diethoxyphosphoryl)acetonitrile oxide 213
Diethyl Oxalate 214
2,2-Difluoroethylamine 217
Diiminosuccinonitrile 221
1,3-Diisopropyl-1,3-propanedione 222
2,5-Dimethoxytetrahydrofuran 225
N,N-Dimethylacetamide Dimethyl Acetal 230
Dimethyl Diazomalonate 237
Dimethyl 2,3-Pentadienedioate 252
Dimethyl 1,2,4,5-Tetrazine-3,6-dicarboxylate 258
2,4-Dinitrophenylhydrazine 266
Diphenyl Cyanocarbonimidate 269
Dirhodium(II) Tetraacetate 271
Dirhodium Tetrakis(heptafluorobutyramide) 287
Di-p-tolylcarbodiimide 289
E 295
Ethyl 2-Diazo-3-oxo-3-phenylpropanoate 295
Ethyl 2-Diazo-3-oxybutyrate 297
Ethyl 2-Diazo-4,4,4-trifluoro-3-oxobutanoate 303
Ethyl Ethoxymethylenecyanoacetate 306
F 311
Formamidine Acetate 311
G 313
Gold(I) Chloride 313
Gold(III) Chloride 320
Guanidine 344
H 349
2,5-Hexanedione 349
Hydrogen Sulfide 352
Hydroxylamine 357
I 365
Indium Tribromide 365
Iodine 380
Iron(III) Bromide 396
Iron(III) Chloride 401
M 409
Malonyl Chloride 409
?-Methacrolein N-tert-Butylimine 411
Methyl glycine 412
Methyl Isocyanate 415
S-Methylisothiourea 417
4-Methyloxazole 419
Methyl Thioglycolate 420
O 423
Oxo(trimanganese) Heptaacetate 423
Oxygen 424
P 437
Palladium(II) Acetate 437
Palladium(II) Chloride 471
Phenyl Isocyanide 489
Phenylhydrazine 490
Phenyliodine(III) Bis(trifluoroacetate) 494
Phosphorus Oxychloride 503
Pivalic Acid 511
Polyphosphoric Acid 519
Potassium Ethyl Xanthate 525
Potassium Monoperoxysulfate 534
S 553
Selenium(IV) Oxide 553
Semicarbazide 564
Silver(I) Hexafluoroantimonate 569
Sodium Nitrite 572
Sodium Sulfide 583
Sodium Tetrachloroaurate(III) 595
Sulfur 599
T 605
N,N,N’,N’-Tetrabromobenzene-1,3-disulfonamide (TBBDS) 605
Tetrakis(triphenylphosphine)-palladium(0) 607
3-Thiapentanedioic acid 616
Thiourea 618
o-Tolyl Isocyanide 620
p-Tolylsulfonylmethyl isocyanide 621
Trifluomethyldiazomethane 629
Trifluoroethylamine 634
Trifluoromethanesulfonic anhydride 638
1,1,1-Trifluoro-N-phenylmethanesulfenamide 655
2-(Trimethylsilyl)phenyl Triflate 657
Triphenylphosphinegold(I) Chloride 660
List of Contributors 665
Reagent Formula Index 675
Index 677
End User License Agreement 709

Produkt-Details

• Erscheint lt. Verlag: 31.5.2017
• Sprache: englisch
• Themenwelt: Naturwissenschaften ► Chemie ► Organische Chemie
• Themenwelt: Naturwissenschaften ► Chemie ► Physikalische Chemie
• Schlagworte: Chemie • Chemistry • heteroarenes heterocycles synthesis reagents catalysts reaction conditions safety purification storage • Heteroaromaten • Methods - Synthesis & Techniques • Natural Products • Naturstoffchemie • Organische Chemie • Organische Chemie / Methoden, Synthesen, Verfahren • Pharmaceutical & Medicinal Chemistry • Pharmazeutische u. Medizinische Chemie
• ISBN-13: 9781118704882 / 9781118704882