Iron-Catalyzed Synthesis of Fused Aromatic Compounds via C–H Bond Activation

Arimasa Matsumoto (Autor)

Buch | Softcover

74 Seiten

2016 | Softcover reprint of the original 1st ed. 2014
Springer Verlag, Japan
978-4-431-56248-1 (ISBN)

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Iron catalysts in organic synthesis are strongly in demand because iron is non-toxic, inexpensive and the most abundant transition metal in the earth, although their use is still limited compared with that of rare, precious metals such as palladium, ruthenium and rhodium. This thesis describes the first practical example of iron catalysis in the carbon–hydrogen bond activation reaction to synthesized fused aromatic ring compounds. By using a unique combination of iron catalyst and dichloride oxidant, various kind of naphthalene and phenanthrene derivatives were synthesized via annulation reaction with alkynes including direct C–H bond activation process. This achievement opens the new possibility of low-valent iron catalysis and expands synthetic methods for a sustainable society.

General Introduction.- Iron-Catalyzed Naphthalene Synthesis from Alkyne and Grignard Reagent.- Iron-Catalyzed Phenanthrene Synthesis from Alkyne and Grignard Reagent.- Iron-Catalyzed Phenanthrene Synthesis from Alkyne and Aryl Bromide Mediated by Metallic Magnesium.- Summary and Perspectives.

Erscheinungsdatum	04.03.2022
Reihe/Serie	Springer Theses
Zusatzinfo	105 Illustrations, black and white; XIII, 74 p. 105 illus.
Verlagsort	Tokyo
Sprache	englisch
Maße	155 x 235 mm
Themenwelt	Naturwissenschaften ► Chemie ► Organische Chemie
Themenwelt	Technik ► Maschinenbau
Schlagworte	Alkyne Annulation • C–H Bond Activation • Fused Aromatic Compounds • Iron Catalysis • Iron Catalyst • Naphthalene Derivatives • Phenanthrene Derivatives
ISBN-10	4-431-56248-6 / 4431562486
ISBN-13	978-4-431-56248-1 / 9784431562481
Zustand	Neuware