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Handbook of Biopolymer-Based Materials (eBook)

From Blends and Composites to Gels and Complex Networks
eBook Download: EPUB
2013
Wiley-VCH (Verlag)
9783527652471 (ISBN)

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This first systematic scientific reference in the area of micro- and nanostructured biopolymer systems discusses in two volumes the morphology, structure, dynamics, properties and applications of all important biopolymers, as well as their blends, composites, interpenetrating networks and gels.

Selected leading researchers from industry, academia, government and private research institutions around the globe comprehensively review recent accomplishments in the field. They examine the current state of the art, new challenges, and opportunities, discussing all
the synthetic routes to the generation of both micro- and nano-morphologies, as well as the synthesis, characterization and application of porous biopolymers.

An outstanding resource for anyone involved in the fi eld of eco-friendly biomaterials for advanced technologies.


Sabu Thomas is a Professor of Polymer Science and Engineering at Mahatma Gandhi University (India) and Director of the 'School of Chemical Sciences' and of the 'Center for Nanoscience and Nanotechnology' of the same university. He has published over 500 research papers in peer reviewed international journals on polymer composites, nanocomposites, membrane separation, polymer blends and
alloys, and polymer recycling, has an h-index of 57 and has edited 23 books. Professor Thomas is also a Fellow of the Royal Society of Chemistry and a Fellow of the New York Academy of Sciences. His work has been awarded with the Professor Sukumar Maithy Award, the Bronze Medal of the Chemical Research Society of India (CRSI) and the Materials Research Society of India (MRSI) award, among others.

Dominique Durand is a Research Director Emeritus at the CNRS and former Director of the Polymers, Colloids and Interfaces Laboratory at the University of Maine, Le Mans (France). His research focuses on experimental studies and modeling of static and dynamic properties of complex systems, such as covalent networks, associating polymers and biopolymer gels. He is the author or co-author of over 210 research papers, reviews, and book chapters.

Christophe Chassenieux is a Professor at the University of Maine, Le Mans (France) since 2005, after being an Assistant Professor at the University Pierre et Marie Curie, Paris. His research interests encompass properties of polymer gels and self-assemblies of amphiphilic polymers. He is the co-author of 50 research articles, book chapters and patents.

Parameswaranpillai Jyotishkumar is DST INSPIRE Faculty at the Department of Polymer Science and Rubber Technology, Kerala (India). He has completed his PhD from Mahatma Gandhi University, Kottayam. Dr. Jyotishkumar's research focuses on polymer blends, nanocomposites, and bio-nanocomposites. He is the author or co-author of 30 research articles and book chapters.

Sabu Thomas is a Professor of Polymer Science and Engineering at Mahatma Gandhi University (India) and Director of the 'School of Chemical Sciences' and of the 'Center for Nanoscience and Nanotechnology' of the same university. He has published over 500 research papers in peer reviewed international journals on polymer composites, nanocomposites, membrane separation, polymer blends and alloys, and polymer recycling, has an h-index of 57 and has edited 23 books. Professor Thomas is also a Fellow of the Royal Society of Chemistry and a Fellow of the New York Academy of Sciences. His work has been awarded with the Professor Sukumar Maithy Award, the Bronze Medal of the Chemical Research Society of India (CRSI) and the Materials Research Society of India (MRSI) award, among others. Dominique Durand is a Research Director Emeritus at the CNRS and former Director of the Polymers, Colloids and Interfaces Laboratory at the University of Maine, Le Mans (France). His research focuses on experimental studies and modeling of static and dynamic properties of complex systems, such as covalent networks, associating polymers and biopolymer gels. He is the author or co-author of over 210 research papers, reviews, and book chapters. Christophe Chassenieux is a Professor at the University of Maine, Le Mans (France) since 2005, after being an Assistant Professor at the University Pierre et Marie Curie, Paris. His research interests encompass properties of polymer gels and self-assemblies of amphiphilic polymers. He is the co-author of 50 research articles, book chapters and patents. Parameswaranpillai Jyotishkumar is DST INSPIRE Faculty at the Department of Polymer Science and Rubber Technology, Kerala (India). He has completed his PhD from Mahatma Gandhi University, Kottayam. Dr. Jyotishkumar's research focuses on polymer blends, nanocomposites, and bio-nanocomposites. He is the author or co-author of 30 research articles and book chapters.

VOLUME 1

BIOPOLYMERS: STATE OF THE ART, NEW CHALLENGES, AND OPPORTUNITIES
Introduction
Biopolymers: A Niche For Fundamental Research in Soft Matter Physics
Biopolymers: An Endless Source of Applications
Topics Covered by the Book
Conclusions

GENERAL OVERVIEW OF BIOPOLYMERS: STRUCTURE, PROPERTIES, AND APPLICATIONS
Introduction
Plant Cell Wall Polysaccharides
Biocomposites
Future Outlook

BIOPOLYMERS FROM PLANTS
Introduction
Lipid and Phenolic Biopolymers
Carbohydrate Biopolymers: Polysaccharides
Isoprene Biopolymers: Natural Rubber
Concluding Remarks

BACTERIAL BIOPOLYMERS AND GENETICALLY ENGINEERED BIOPOLYMERS FOR GEL SYSTEMS APPLICATION
Introduction
Microbial Polysaccharides as Biopolymers
Microbial Biopolymers as Drug Delivery Vehicle
Polyanhydrides
Recombinant Protein Polymer Production
Recombinant Genetically Engineered Biopolymer : Elastin
Collagen as an Ideal Biopolymer
Biopolymers for Gel System
Hydrogels of Biopolymers for Regenerative Medicine
Supermacroporous Cryogel Matrix from Biopolymers
Biopolymers Impact on Environment
Conclusion

BIOPOLYMERS FROM ANIMALS
Introduction
Chitin and Hyaluronic Acid in the Living World
Milestones in Chitin History
From Trehalose to Chitin
Chitin Synthase
Regulation of Chitin Synthesis in Fungi
Organization of Chitin in the Fungal Cell Wall
Organization of Chitin in the Arthropod Cuticle
Chitin-Organizing Factors
Secretion and Cuticle Formation
Transcriptional Regulation of Cuticle Production
Chitin Synthesis Inhibitors
Noncuticular Chitin in Insects
Chitin as a Structural Element
Application of Chitin
Conclusion

POLYMERIC BLENDS WITH BIOPOLYMERS
Introduction
Starch-Based Blends
Blends with Chitosan (One Amino Group Too Much . . . )
Future Perspectives

MACRO-, MICRO-, AND NANOCOMPOSITES BASED ON BIODEGRADABLE POLYMERS
Introduction
Biodegradable Polymers
Biocomposites
Nanobiocomposites

IPNS DERIVED FROM BIOPOLYMERS
Introduction
Types of IPNs
IPNs Derived from Biopolymers
Manufacture of IPNs
Characterization of IPNs
Applications of IPNs
Conclusions

ASSOCIATING BIOPOLYMER SYSTEMS AND HYALURONATE BIOMATERIALS
Introduction
Synthesis and Self-Association of Hydrophobically Modified Derivatives of Chitosan and Hyaluronic Acid in Aqueous Solution
Design of Novel Biomaterials Based on Chemically Modified Derivatives of Hyaluronic Acid
Conclusions

POLYMER GELS FROM BIOPOLYMERS
Introduction
Experimental Methods
Polymerization and Gelation Kinetics
Sol - Gel Transition and Universality Discussion
Imprinting the Gels
Heterogeneity of Hydrogels
Ionic p-Type and n-Type Semiconducting Gels
Conclusions

CONFORMATION AND RHEOLOGY OF MICROBIAL EXOPOLYSACCHARIDES
Introduction
Conformation of Polysaccharides
Secondary Solid-State Structures for Microbial Polysaccharides
Conformation in Solution: Solution Properties and Applications
Gelling Properties in the Presence of Salts
Conclusions

SULFATED POLYSACCHARIDES IN THE CELL WALL OF RED MICROALGAE
Introduction
Sulfated Polysaccharides from Red Microalgae - General Overview
Sulfated Polysaccharides of Red Microalgal Cell Walls: Chemical Aspects
Proteins in the Cell Wall of Red Microalgae
Rheology of Red Microalgal Polysaccharide Solutions
Modifications of the Sulfated Polysaccharides
Red Microalgal Sulfated Polysaccharide Bioactivities

VOLUME 2

DIELECTRIC SPECTROSCOPY AND THERMALLY STIMULATED CURRENT ANALYSIS OF BIOPOLYMER SYSTEMS

SOLID-STATE NMR SPECTROSCOPY OF BIOPOLYMERS

EPR SPECTROSCOPY OF BIOPOLYMERS

X-RAY PHOTOELECTRON SPECTROSCOPY: A TOOL FOR STUDYING BIOPOLYMERS

LIGHT-SCATTERING STUDIES OF BIOPOLYMER SYSTEMS

X-RAY SCATTERING AND DIFFRACTION OF BIOPOLYMERS

LARGE-SCALE STRUCTURAL CHARACTERIZATION OF BIOPOLYMER SYSTEMS BY SMALL-ANGLE NEUTRON SCATTERING

MICROSCOPY OF BIOPOLYMER SYSTEMS

RHEO-OPTICAL CHARACTERIZATION OF BIOPOLYMER SYSTEMS

RHEOLOGICAL BEHAVIOR OF BIOPOLYMER SYSTEMS

PHYSICAL GELS OF BIOPOLYMERS: STRUCTURE, RHEOLOGICAL AND GELATION PROPE VOLUME 1

BIOPOLYMERS: STATE OF THE ART, NEW CHALLENGES, AND OPPORTUNITIES
Introduction
Biopolymers: A Niche For Fundamental Research in Soft Matter Physics
Biopolymers: An Endless Source of Applications
Topics Covered by the Book
Conclusions

GENERAL OVERVIEW OF BIOPOLYMERS: STRUCTURE, PROPERTIES, AND APPLICATIONS
Introduction
Plant Cell Wall Polysaccharides
Biocomposites
Future Outlook

BIOPOLYMERS FROM PLANTS
Introduction
Lipid and Phenolic Biopolymers
Carbohydrate Biopolymers: Polysaccharides
Isoprene Biopolymers: Natural Rubber
Concluding Remarks

BACTERIAL BIOPOLYMERS AND GENETICALLY ENGINEERED BIOPOLYMERS FOR GEL SYSTEMS APPLICATION
Introduction
Microbial Polysaccharides as Biopolymers
Microbial Biopolymers as Drug Delivery Vehicle
Polyanhydrides
Recombinant Protein Polymer Production
Recombinant Genetically Engineered Biopolymer : Elastin
Collagen as an Ideal Biopolymer
Biopolymers for Gel System
Hydrogels of Biopolymers for Regenerative Medicine
Supermacroporous Cryogel Matrix from Biopolymers
Biopolymers Impact on Environment
Conclusion

BIOPOLYMERS FROM ANIMALS
Introduction
Chitin and Hyaluronic Acid in the Living World
Milestones in Chitin History
From Trehalose to Chitin
Chitin Synthase
Regulation of Chitin Synthesis in Fungi
Organization of Chitin in the Fungal Cell Wall
Organization of Chitin in the Arthropod Cuticle
Chitin-Organizing Factors
Secretion and Cuticle Formation
Transcriptional Regulation of Cuticle Production
Chitin Synthesis Inhibitors
Noncuticular Chitin in Insects
Chitin as a Structural Element
Application of Chitin
Conclusion

POLYMERIC BLENDS WITH BIOPOLYMERS
Introduction
Starch-Based Blends
Blends with Chitosan (One Amino Group Too Much . . . )
Future Perspectives

MACRO-, MICRO-, AND NANOCOMPOSITES BASED ON BIODEGRADABLE
POLYMERS
Introduction
Biodegradable Polymers
Biocomposites
Nanobiocomposites

IPNS DERIVED FROM BIOPOLYMERS
Introduction
Types of IPNs
IPNs Derived from Biopolymers
Manufacture of IPNs
Characterization of IPNs
Applications of IPNs
Conclusions

ASSOCIATING BIOPOLYMER SYSTEMS AND HYALURONATE BIOMATERIALS
Introduction
Synthesis and Self-Association of Hydrophobically Modified Derivatives of Chitosan and Hyaluronic Acid in Aqueous Solution
Design of Novel Biomaterials Based on Chemically Modified Derivatives of Hyaluronic Acid
Conclusions

POLYMER GELS FROM BIOPOLYMERS
Introduction
Experimental Methods
Polymerization and Gelation Kinetics
Sol?Gel Transition and Universality Discussion
Imprinting the Gels
Heterogeneity of Hydrogels
Ionic p-Type and n-Type Semiconducting Gels
Conclusions

CONFORMATION AND RHEOLOGY OF MICROBIAL EXOPOLYSACCHARIDES
Introduction
Conformation of Polysaccharides
Secondary Solid-State Structures for Microbial Polysaccharides
Conformation in Solution: Solution Properties and Applications
Gelling Properties in the Presence of Salts
Conclusions

SULFATED POLYSACCHARIDES IN THE CELL WALL OF RED MICROALGAE
Introduction
Sulfated Polysaccharides from Red Microalgae ? General Overview
Sulfated Polysaccharides of Red Microalgal Cell Walls: Chemical Aspects
Proteins in the Cell Wall of Red Microalgae
Rheology of Red Microalgal Polysaccharide Solutions
Modifications of the Sulfated Polysaccharides
Red Microalgal Sulfated Polysaccharide Bioactivities

VOLUME 2

DIELECTRIC SPECTROSCOPY AND THERMALLY STIMULATED CURRENT ANALYSIS OF BIOPOLYMER SYSTEMS

SOLID-STATE NMR SPECTROSCOPY OF BIOPOLYMERS

EPR SPECTROSCOPY OF BIOPOLYMERS

X-RAY PHOTOELECTRON SPECTROSCOPY: A TOOL FOR STUDYING BIOPOLYMERS

LIGHT-SCATTERING STUDIES OF BIOPOLYMER SYSTEMS

X-RAY SCATTERING AND DIFFRACTION OF BIOPOLYMERS

LARGE-SCALE STRUCTURAL CHARACTERIZATION OF BIOPOLYMER SYSTEMS BY SMALL-ANGLE NEUTRON SCATTERING

MICROSCOPY OF BIOPOLYMER SYSTEMS

RHEO-OPTICAL CHARACTERIZATION OF BIOPOLYMER SYSTEMS

RHEOLOGICAL BEHAVIOR OF BIOPOLYMER SYSTEMS

PHYSICAL GELS OF BIOPOLYMERS: STRUCTURE, RHEOLOGICAL AND GELATION PROPERTIE

List of Contributors

Esra Alveroglu

Istanbul Technical University

Department of Physics

Maslak

34469 Istanbul

Turkey

Shoshana (Malis) Arad

Ben-Gurion University of the Negev

Department of Biotechnology Engineering

POB 653 Beer-Sheva 84105

Israel

Robin Augustine

Mahatma Gandhi University

Centre for Nanoscience and Nanotechnology

Priyadarshini Hills

Kottayam 686560

Kerala

India

Rachel Auzély-Velty

Université Joseph Fourier

Centre de Recherches sur les Macromolécules Végétales (CERMAV-CNRS)

601 rue de la Chimie

38041 Grenoble

France

Luc Avérous

Université de Strasbourg

BioTeam/ICPEES-ECPM, UMR 7515

25 rue Becquerel

67087 Strasbourg Cedex 2

France

Deepa Bhanumathy Amma

Bishop Moore College

Department of Chemistry

Mavelikara 690110

Kerala

India

Deborah Blanchard

Université Joseph Fourier

Centre de Recherches sur les Macromolécules Végétales (CERMAV-CNRS)

601 rue de la Chimie

38041 Grenoble

France

Ana Maria Botelho do Rego

Technical University of Lisbon

Institute of Nanoscience and Nanotechnology

Centro de Química-Física Molecular

Av. Rovisco Pais

1049-001 Lisboa

Portugal

Sami Boufi

University of Sfax

Faculté des Sciences de Sfax

Laboratoire des Sciences des

Matériaux et Environnement

BP 1171-3000 Sfax

Tunisia

Denis Bouyer

Université de Montpellier

Institut Européen des Membranes

2, Place Eugene Bataillon

34967 Montpellier

Cedex 2

France

Christophe Chassenieux

LUNAM Université du Maine

IMMM UMR CNRS 6283

Dept. Polymères, Colloïdes, Interfaces

1 Avenue Olivier Messiaen

72085 Le Mans Cedex 9

France

Mindong Chen

Nanjing University of Information Science & Technology

Department of Chemistry

Nanjing 210044

China

Wenguo Cui

The First Affiliated Hospital of Soochow University

Department of Orthopedics

188 Shizi Street

Suzhou, Jiangsu 215006

China

and

Soochow University

Orthopedic Institute

708 Renmin Road

Suzhou, Jiangsu 215007

China

Uro Cvelbar

Joef Stefan Institute

F4 Plasma Laboratory

Jamova 39

1000 Ljubljana

Slovenia

Jany Dandurand

Université Paul Sabatier

CIRIMAT UMR CNRS 5085

Physique des Polymères 3R1B2

118 route de Narbonne

31062 Toulouse cedex 02

France

Jacques Desbrieres

Université de Pau et des Pays de l'Adour

IPREM

Helioparc Pau Pyrenees

2 Avenue P. Angot

64053 Pau Cedex 09

France

Marli Miriam de Souza Lima

Universidade Estadual de Maringa

Pharmacy Departement LAFITEC

Av. Colombo, 5790 - Zona 07

CEP 87020-900 Maringa

Parana, Brasil

Dominique Durand

LUNAM Université du Maine

IMMM UMR CNRS 6283

Dept. Polymères, Colloïdes, Interfaces

1 Avenue Olivier Messiaen

72085 Le Mans Cedex 9

France

Tao Feng

Shanghai Institute of Technology

Department of Food Science and Technology

School of Perfume and Aroma Technology

120 Caobao Road

Shanghai 200235

China

Ana Maria Ferraria

Technical University of Lisbon

Institute of Nanoscience and Nanotechnology

Centro de Química-Física Molecular

Av. Rovisco Pais

1049-001 Lisboa

Portugal

Chris Ford

University of Southampton

School of Biological Sciences

Highfield Campus

Southampton SO17 1BJ

UK

Tim J. Foster

University of Nottingham

School of Biosciences

Division of Food Sciences

Sutton Bonington Campus

Loughborough Leicestershire LE12 5RD

UK

Ali Gelir

Istanbul Technical University

Department of Physics

Maslak

34469 Istanbul

Turkey

Anne George

Medical College Kottayam

Department of Anatomy

Gandhinagar

Kottayam 686008

Kerala

India

and

Center of Excellence for Polymer Materials and Technologies

Tehnoloski Park 24

1000 Ljubljana

Slovenia

Hero Jan Heeres

University of Groningen

Department of Chemical Engineering

Nijenborgh 4

9747 Groningen

The Netherlands

Antonio Heredia

Facultad de Ciencias

Departamento de Biología Molecular y Bioquímica

Campus de Teatinos, s/n

29071 Málaga

Spain

Ferenc Horkay

National Institute of Child Health and Human Development NICHD

13 South Dr Room 3W16, MSC 5772

Bethesda Md 20892-5772

USA

Changmin Hu

Shanghai Jiao Tong University

School of Biomedical Engineering and Med-X Research Institute

1954 Hua Shan Road

Shanghai 200030

China

Parameswaranpillai Jyotishkumar

INSPIRE Faculty

Department of Polymer Science and Rubber Technology

Cochin University of Science and Technology, Kochi-682022

Vassilis Kiosseoglou

Aristotle University of Thessaloniki

School of Chemistry

Laboratory of Food Chemistry and Technology

54124 Thessaloniki

Greece

Vanja Kokol

University of Maribor

Faculty of Mechanical Engineering

Institute for Engineering Materials and Design

Smetanova ul. 17

2000 Maribor

Slovenia

Ashok Kumar

Indian Institute of Technology Kanpur

Department of Biological Sciences and Bioengineering

Kanpur 208016

Uttar Pradesh

India

Rakesh Kumar

Birla Institute of Technology, Mesra.

Patna Campus

Department of Applied Chemistry

P.O. - B. V. College, Patna - 800014, Bihar

India

Colette Lacabanne

Université Paul Sabatier

CIRIMAT UMR CNRS 5085

Physique des Polymères 3R1B2

118 route de Narbonne

31062 Toulouse cedex 02

France

Oshrat Levy-Ontman

Sami Shamoon College of Engineering

Department of Chemical Engineering

Beer-Sheva 84100

POB 950

Israel

Dagang Liu

Nanjing University of Information Science & Technology

Department of Chemistry

Nanjing 210044

Ningliu Rd 219

China

Fei Lu

Nanjing University of Information Science & Technology

Department of Chemistry

Nanjing 210044

China

Phedra Marius

University of Southampton

School of Biological Sciences

Highfield Campus

Southampton SO17 1BJ

UK

Siji K. Mary

Bishop Moore College

Department of Chemistry

Mavelikara 690110

Kerala

India

Camille Michon

AgroParisTech

UMR1145 Ingénierie Procédés Aliments

Agro

Paristech/Inra/Cnam

1 avenue des Olympiades

91300 MASSY

France

Bernard Moussian

University of Tübingen

Interfaculty Institute for Cell Biology

Department of Animal Genetics

Auf der Morgenstelle 28

72076 Tübingen

Germany

Miran Mozeti

Joef Stefan Institute

F4 Plasma Laboratory

Jamova 39

1000 Ljubljana

Slovenia

and

Center of Excellence for Polymer Materials and Technologies

Tehnoloski Park 24

1000 Ljubljana

Slovenia

Taco Nicolai

LUNAM Université du Maine

IMMM UMR CNRS 6283

Dept. Polymères, Colloïdes, Interfaces

1 Avenue Olivier Messiaen

72085 Le Mans Cedex 9

France

Yoshiharu Nishiyama

Centre de Recherches sur les Macromolécules Végétales (CERMAV-CNRS), BP53, 38041 Grenoble cedex 9,

France

Adamantini Paraskevopoulou

Aristotle University of Thessaloniki

School of Chemistry

Laboratory of Food Chemistry and Technology

54124 Thessaloniki

Greece

Francesco Picchioni

University of Groningen

Department of Chemical Engineering

Nijenborgh 4

9747 Groningen

The Netherlands

Eric Pollet

Université de Strasbourg

LIPHT-ECPM, EAc (CNRS) 4379

25 rue Becquerel

67087 Strasbourg Cedex 2

France

Laly A. Pothen

Bishop Moore College

Department of Chemistry

Mavelikara 690110

Kerala

India

Rajakumari Rajendran

Mahatma Gandhi University

Centre for Nanoscience and...

Erscheint lt. Verlag 16.4.2013
Sprache englisch
Themenwelt Naturwissenschaften Chemie Organische Chemie
Technik
Schlagworte accomplishments • Applications • area • Biomaterial • Biomaterialien • biomaterials • biomedical engineering • Biomedizintechnik • Biopolymer • Biopolymere • biopolymers • Blends • Chemie • Chemistry • Field • first systematic • Globe • important • Industrial Chemistry • Industry • Institutions • Materials Science • Materialwissenschaften • micro • Morphology • Nanomaterialien • nanomaterials • nanostructured • Nanotechnologie • nanotechnology • Polymer Science & Technology • Polymerwissenschaft u. -technologie • private • Properties • Reference • Researchers • Scientific • Systems • Technische u. Industrielle Chemie • two
ISBN-13 9783527652471 / 9783527652471
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