Advances in Physical Organic Chemistry (eBook)

D. Bethell (Herausgeber)

eBook Download: PDF

1994 | 1. Auflage
368 Seiten
Elsevier Science (Verlag)
978-0-08-058168-2 (ISBN)

Infos

In pursuit of the objective of the series which is to present considered reviews of areas concerned with quantitative study of organic compounds and their behaviourNphysical organic chemistry in its broadest senseNina manner accessible to a general readership, this twenty-ninth volume contains five contributions on a diversity of topics. Two of these reflect the increasing importance of physical organic studies in providing fundamental knowledge relevant to the development of new materials with novel physical properties. The others represent more traditional areas of physical organic interest, where recent research has thrown new light.

Key Features
* Electron storage and transfer in organic redox systems with multiple electrophores
* Chirality and molecular recognition in monolayers at the air/water interface
* Transition state theory revisited
* Neighboring group participation by carbonyl groups in ester hydrolysis
* Electrophilic bromination of carbonDcarbon double bonds: structure solvent and mechanism

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In pursuit of the objective of the series which is to present considered reviews of areas concerned with quantitative study of organic compounds and their behaviourNphysical organic chemistry in its broadest senseNina manner accessible to a general readership, this twenty-ninth volume contains five contributions on a diversity of topics. Two of these reflect the increasing importance of physical organic studies in providing fundamental knowledge relevant to the development of new materials with novel physical properties. The others represent more traditional areas of physical organic interest, where recent research has thrown new light. - Electron storage and transfer in organic redox systems with multiple electrophores- Chirality and molecular recognition in monolayers at the air/water interface- Transition state theory revisited- Neighboring group participation by carbonyl groups in ester hydrolysis- Electrophilic bromination of carbonDcarbon double bonds: structure solvent and mechanism

Inhalt

Front Cover 1
Advances in Physical Organic Chemistry, Volume 29 4
Copyright Page 5
Contents 6
Preface 8
Contributors to Volume 29 9
Chapter 1. The Stabilization of Transition States by Cyclodextrins and other Catalysts 10
1 Introduction 10
2 Cyclodextrins 12
3 Transition state stabilization 18
4 Non-covalent catalysis 22
5 Covalent catalysis 31
6 Other catalysts 55
7 Future prospects 71
Chapter 2. Crystallographic Approaches to Transition State Structures 96
1 Introduction 96
2 Structure–structure correlations 104
3 Structure–reactivity correlations 134
4 Extrapolation to transition state structures 182
Chapter 3. Electron Transfer in the Thermal and Photochemical Activation of Electron Donor–Acceptor Complexes in Organic and Organometallic Reactions 194
1 Introduction 194
2 Direct observation of transient ion pairs by charge-transfer activation of EDA complexes 197
3 Time-resolved picosecond spectroscopic studies of charge-transfer complexes 199
4 Variable charge-transfer structures of nitrosonium-EDA complexes leading to thermal and photo-induced electron transfer 233
5 Charge-transfer activation as the unifying theme in electrophilic aromatic substitution–nitration 246
6 Concluding remarks 271
Chapter 4. Homoaromaticity 282
1 Introduction 282
2 Cationic homoaromaticity 287
3 Neutral homoaromaticity 303
4 Anionic homoaromaticity 323
5 Radical homoaromaticity 325
6 Theoretical treatment 329
7 Conclusion 332
Author Index 342
Cumulative Index of Authors 360
Cumulative Index of Titles 362

Produkt-Details

• Erscheint lt. Verlag: 27.1.1994
• Sprache: englisch
• Themenwelt: Sachbuch/Ratgeber
• Themenwelt: Schulbuch / Wörterbuch
• Themenwelt: Naturwissenschaften ► Chemie ► Analytische Chemie
• Themenwelt: Naturwissenschaften ► Chemie ► Organische Chemie
• Themenwelt: Naturwissenschaften ► Chemie ► Physikalische Chemie
• Themenwelt: Naturwissenschaften ► Physik / Astronomie ► Festkörperphysik
• Themenwelt: Technik
• ISBN-10: 0-08-058168-4 / 0080581684
• ISBN-13: 978-0-08-058168-2 / 9780080581682