Terpyridines (eBook)

Multifaceted Ligands for Diverse Applications

Ulrich S. Schubert, Andreas Winter, George R. Newkome (Autoren)

eBook Download: EPUB

2025 | 1. Auflage
544 Seiten
Wiley-VCH (Verlag)
9783527849758 (ISBN)

Infos

A thorough overview of terpyridine applications

In Terpyridines: Multifaceted Ligands for Diverse Applications, a team of distinguished researchers delivers an up-to-date summary of the most recent developments in the synthesis and application of terpyridine compounds. The authors introduce the history and fundamentals of terpyridine ligands before moving on to discuss their complexes and main-group elements. In addition, self-healing and shape-memory materials, as well as 2D and 3D supramolecular networks based on terpyridine are described.

Readers will also find:

• A thorough introduction to terpyridine complexes for biomedical applications
• Comprehensive explorations of energy-storage applications, photovoltaic applications, and the application of terpyridine complexes to light-emitting device technology
• Practical discussions of electrocatalytic applications, including water splitting and CO2 reduction
• In-depth studies of metallo-supramolecular polymers, networks, self-assembly processes, and self-sorting mechanisms.

Perfect for organic, complex, and polymer chemists, Terpyridines: Multifaceted Ligands for Diverse Applications will also benefit physical chemists with an interest in the synthesis and applications of prominent terpyridine complexes.

Ulrich S. Schubert is a full professor at Friedrich Schiller University Jena (Germany) since 2007. His research is focused on innovative materials as key elements for healthcare, sustainability, and energy.

Andreas Winter is a research associate at Friedrich Schiller University Jena (Germany). His research is focused on the synthesis of metallo-supramolecular materials for opto-electronic and energy conversion applications.

George R. Newkome is a research professor in the Center for Molecular Biology and Biochemistry at Florida Atlantic University (USA). He is a pioneer in cascade polymer research and is an expert in their construction and supramolecular applications.

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List of Abbreviations

A-2780

human ovarian carcinoma cell line

A-2780r

cisplatin-resistant variant of A-2780

A-375

human malignant melanoma cell line

A-549

human lung carcinoma cell line

A-549r

cisplatin-resistant variant of A549

AC

alternating current

ACA

alloxazine 7/8-carboxylic acid

acac

acetylacetonate

AFM

atomic-force microscopy

AI

artificial intelligence

AIE

aggregation-induced emission

AIQ

aggregation-induced quenching

Alq3

tris(8-hydroxyquinoline)aluminum

AM

air mass

AN

acceptor number

aRFB

aqueous redox-flow battery

aRFID

active radio frequency identification

ASC

asymmetric supercapacitor

ATRP

atom-transfer radical polymerization

B. subtilis

Bacillus subtilis

BASF

Badische Anilin- und Sodafabrik

BCP

2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline (“bathocuproine”)

BD

black dye

BEL-7402

human hepatocellular carcinoma cell line

BHJ

bulk heterojunction

bmim

1-butyl-3-methylimidazolium

BODIPY

boron-dipyrromethene

bpy

2,2′-bipyridine

Br-tpy

4′-bromo-2,2′:6′,2″-terpyridine

BSA

bovine serum albumin

C

capacity or capacitance

CAL-51

human breast adenocarcinoma cell line

CAN

ceric ammonium nitrate or covalent adaptive networks

CBM

conduction-band minimum

CBD

chronic beryllium disease

CBP

4,4′-bis(9H-carbazol-9-yl)biphenyl

C^C^C

tris-cyclometalating tridentate ligand (coordination via three C-atoms)

CCDC

Cambridge Crystallographic Data Centre

C^C^N

bis-cyclometalating tridentate ligand (coordination via two C- and one N-atoms)

CD

circular dichroism

CDCA

3a,7a-dihydroxy-5b-cholic acid

cds

cadmium sulfate

CDSA

coordination-driven self-assembly

CE

coulombic efficiency, coloration efficiency or current efficiency

chdc

cyclohexyl-1,4-dicarboxylic acid

CID

collision-induced dissociation

CIE

Commission Internationale d′Eclairage

CIGS

copper indium gallium (di)selenide

Cl-tpy

4′-chloro-2,2′:6′,2″-terpyridine

CMC

carboxymethyl cellulose

CN

coordination number

C^N

mono-cyclometaling bidentate ligand (coordination via one C- and one N-atom)

C^N^C

bis-cyclometalating tridentate ligand (coordination via two C- and one N-atoms)

C^N^N

mono-cyclometalating tridentate ligand (coordination via one C- and two N-atoms)

CNT

carbon nanotube

cod

cycloocta-1,5-diene

COF

covalent-organic framework

CONASH

coordination nanosheet

CORM

CO-releasing molecule

COSY

correlated (NMR) spectroscopy

cryo-TEM

cryogenic transition-electron microscopy

CRP

controlled radical polymerization

CS

charge-separated

CSS

charge-separated state

CT

charge-transfer

CuCAAC

CuI-catalyzed alkyne-azide cycloaddition (reaction)

CV

cyclic voltammetry

CVP

chemical vapor deposition

Đ

dispersity

DA

donor-acceptor

DBN

1,5-diazabicyclo(4.3.0)non-5-ene

DCA

deoxycholic acid

dcbpy

2,2′-bipyridine-4,4′-dicarboxylic acid

dceb

4,4′-di(carboxyethyl)-2,2′-bipyridine

dcpp

2,6-bis(2-carboxypyridyl)pyridine

DCvC

dynamic covalent chemistry

ddpd

N,N′-dimethyl-N,N′-di(pyridin-2-yl)pyridine-2,6-diamine

DDQ

2,3-dichloro-5,6-dicyano-1,4-benzoquinone

DFT

density functional theory

DHP

1,4-dihydropyridine

DIB

dual-ion battery

DLP

digital light processing

DLS

dynamic light scattering

dmbpy

4,4′-dimethyl-2,2′-bipyridine

DMC

dimethyl carbonate

DMF

N,N-dimethylformamide

DMFC

direct methanol fuel cells

DMSO

dimethylsulfoxide

DN

donor number

DNA

deoxyribonucleic acid

DoCS

density of coordination sites

DOSY

diffusion ordered spectroscopy (NMR)

DPA

dipyrido[4,3-b;5,6-b]acridine

dpb

2,6-di(pyridin-2-yl)benzene

DPEPO

bis[2-(diphenylphosphino)phenyl] ether oxide

dpp

2,4-di(pyridin-2-yl)pyrazolate or 3,5-di(pyridin-2-yl)pyrazolate or 2,9-diphenyl-1,10-phenanthroline or 2,6-diphenylpyridine

dppep

cis-1,2-bis(diphenylphosphino)ethene

dppp

1,3-bis(diphenylphosphino)propane

DPV

differential pulse voltammetry

dppz

dipyrido[3,2-a: 2′,3′-c]phenazine

dpq

dipyrido-[3,2-d:2′,3′-f]-quinoxaline

dqp

2,6-di(quinoline-8-yl)pyridine

DSC

differential scanning calorimetry

DSIR

Department of Scientific and Industrial Research

DSSC

dye-sensitized solar cell

E. coli

Escherichia coli

EA

ethylammonium

EC

electrochromic or ethylene carbonate

Eca-109

human esophageal carcinoma cell line

ECD

electrochemical doping

ECE

pathway of two one-electron transfers with an in-between chemical reaction

ED

electrodynamical doping

EDLC

electric double-layer capacitor

EDOT

3,4-ethylenedioxythienyl

EDTA

ethylenediaminetetraacetic acid

EE

energy efficiency

EEC

pathway of two consecutive one-electron transfers and a subsequent chemical reaction

Eg

energy-band gap

EIL

electron-injection layer

EL

electroluminescence

emim

1-ethyl-3-methylimidazolium

en

1,2-ethylenediamine

EN

electronegativity

EPR

electron paramagnetic resonance (spectroscopy)

EQE

external quantum efficiency

ERC

electrochemical reduction of CO2

ESI

electrospray ionization

ET

electron transfer or energy transfer

EthBr

ethidium bromide

ETL

electron-transport layer

ETM

electron-transport material

EU

European Union

EV

electric vehicle

F

Faraday constant (96,485 As mol−1)

FA

formamidinium

fac

facial

FC

electrostatic force

Fc/Fc+

ferrocene/ferrocenium cation

FDA

(United States) Food and Drug Administration

FF

fill factor

FIA

fluoride-ion affinity

FID

fluorescent intercalator displacement

FRP

free-radical polymerization

FTO

fluorine-doped tin oxide

fwhm

full width at half maximum

G′

storage modulus (rheology)

G**

loss modulus (rheology)

G4

G-quadruplex (DNA)

GalSL

galactosphingolipid

GlcSL

glucosphingolipid

GCE

glassy-carbon electrode

gMS2

gradient tandem mass spectrometry

GM05757

normal human fibroblast cell line

GM07492

normal human fibroblast cell line

GO

graphene oxide

GS

ground state

GSL

glycosphingolipids

G0/G1

phases of the cell cycle

H-bonding

hydrogen bonding

H0

Hammet acidity function

HBC

hexa-peri-hexabenzocoronene

HCT-116

human colon carcinoma cell line

HC71T-8

human colon carcinoma cell line

HDA

hetero-Diels-Alder

HEK-293T

human embryonic kidney cell line

HeLa

cervical cancer cell line from Henrietta Lacks

HepG2

human liver hepatocellular carcinoma cell line

HER

hydrogen-evolution reaction

HETTAP

heteroleptic terpyridine and phenanthroline (complexation)

HEV

hybrid electric vehicle

HIA

hydride-ion affinity

HL-7702

→ LO2

HOMO

highest occupied molecular orbital

HOPG

highly...

Produkt-Details

• Erscheint lt. Verlag: 10.12.2025
• Sprache: englisch
• Themenwelt: Naturwissenschaften ► Chemie
• ISBN-13: 9783527849758 / 9783527849758