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Surfactant Science and Technology - Drew Myers

Surfactant Science and Technology

(Autor)

Buch | Hardcover
352 Seiten
1992 | 2nd Revised edition
John Wiley & Sons Inc (Verlag)
9780471188414 (ISBN)
CHF 143,65 inkl. MwSt
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Completely updated and enlarged, this second edition is a compilation of many of the most fundamental and useful concepts of surfactant action and application. This revised version includes new chapters to facilitate and clarify the coverage of topics, such as liquid crystal phases and surfactant-polymer interactions. It is written for those who need to use surfactants, but do not have the time to acquire a comprehensive knowledge of them.

Preface to the Second Edition; Preface to the First Edition; Chapter One - Surfactant Science and Technology: An Overview; Introduction; A Brief History of Surfactant Science and Technology; Surfaces, Interfaces, and Surfactant Structures; The Nature of Interfaces; Molecules at Interfaces; The Surfactant "Personality"; Surfactant Building Blocks; The Economic Role of Surfactants; Modern Surfactant Consumption; The Economic and Technological Future; Surfactants in the Environment; A Surfactant Glossary; The Shape of Things To Come; Chapter Two - The Organic Chemistry of Surfactants; Introduction; The Many Faces of Dodecane; The Classification of Surfactants; Surfactant Solubilizing Groups; Common Surfactant Hydrophobic Groups; The Natural Fatty Acids; Paraffins; Olefins; Alkylbenzenes; Alcohols; Alkylphenols; Polyoxypropylenes; Fluorocarbons; Silicone Surfactants; Anionic Surfactants; Sulfate Esters; Fatty Alcohol Sulfates; Sulfated Fatty Acid Condensation Products; Sulfated Ethers; Sulfated Fats and Oils; Sulfonic Acid Salts; Aliphatic Sulfonates; Alkylaryl Sulfonates; alpha--Sulfocarboxylic Acids and Their Derivatives; Miscellaneous Sulfo Ester and Amide Surfactants; Alkyl Glyceryl Ether Sulfonates; Carboxylate Soaps and Detergents; Ligninsulfonates; Phosphoric Acid Esters and Related Surfactants; Cationic Surfactants; Textiles and Cleaning Applications; Antibacterial Applications; Corrosion Protection; Ore Flotation; Asphalt Emulsions; Miscellaneous Applications; Nonionic Surfactants; Polyoxyethylene--Based Surfactants; Derivatives of Polyglycerois and Other Polyols; Block Copolymer Nonionic Surfactants; Miscellaneous Nonionic Surfactants; Amphoteric Surfactants; Imidazoline Derivatives; Surface Active Betaines and Sulfobetaines; Phosphatides and Related Amphoteric Surfactants; Chapter Three - Surfactants In Solution: Micellization and Related Association Phenomena; Introduction; Surfactant Solubility; The Phase Spectrum of Surfactants In Solution; The History and Development of Micellar Theory; Manifestations of Micelle Formation; Thermodynamics of Dilute Surfactant Solutions; Classical Theories of Micelle Formation; Free Energy of Micellization; Molecular Geometry and the Formation of Association Colloids; Experimental Observations of Micellar Systems; Micellar Aggregation Numbers; The Critical Micelle Concentration; The Hydrophobic Group; The Hydrophilic Group; Counterion Effects on Micellization; The Effect of Additives on The Micellization Process; Electrolyte Effects on Micelle Formation; The Effect of pH; The Effects of Added Organic Materials; The Effect of Temperature on Micellization; Micelle Formation in Mixed Surfactant Systems; Micelle Formation in Nonaqueous Media; Chapter Four - Solubilization, Microemulsions, and Miceliar Catalysis; Introduction; Solubilization In Surfactant Micelles; The "Geography" of Solubilization in Micelles; Surfactant Structure and the Solubilization Process; Solubilization and the Nature of the Additive; The Effect of Temperature on Solubilization Phenomena; The Effects of Nonelectrolyte Cosolutes; The Effects of Added Electrolyte; Miscellaneous Factors Affecting Solubilization; Microemulsions; Surfactants, Cosurfactants, and Microemulsion Formation; Micellar Catalysis; Micellar Catalysis in Aqueous Solvent; Micellar Catalysis in Nonaqueous Solvents; Chapter Five - Liquid Crystals, Vesicles and Lipid Membranes; Introduction; Liquid Crystals; Liquid Crystalline Phases in Simple Binary Systems; Temperature and Additive Effects on Phase Behavior; Vesicles and Bilayer Membranes; Vesicles; Biological Membranes; Membrane Surfactants or Lipids; Polymerized Vesicles and Bilayers; Chapter Six - Surfactant--Polymer Interactions; Introduction; Surfactant--Polymer Complex Formation; Nonionic Polymers; Ionic Polymers and Proteins; Polymers, Surfactants, and Solubilization; Our Daily Bread; Chapter Seven - Surface Activity and the Liquid/Vapor Interface; Introduction; Interfaces and the Adsorption Phenomenon; A Thermodynamic Picture of Adsorption; The Effect of Surface Curvature; The Surface Tension of Solutions; Surfactants and the Reduction of Surface Tension; Efficiency, Effectiveness, and Surfactant Structure; Chapter Eight - Emulsions; Introduction; The Liquid/Liquid Interface; General Considerations of Emulsion Stability; The Lifetimes of Typical Emulsions; Theories of Emulsion Stability; Emulsion Type and the Nature of the Surfactant; Surface Activity and Emulsion Stability; Mixed Surfactant Systems and Interfacial Complexes; Liquid Crystals and Emulsion Stability; Surfactant Structure and Emulsion Performance; The Hydrophile--Lipophile Balance (HLB); The Effects of Additives on HLB; Phase Inversion Temperature (PIT); Application of HLB and PIT in Emulsion Formulation; Multiple Emulsions; Nomenclature for Multiple Emulsions; Preparation and Stability of Multiple Emulsions; Primary Emulsion Breakdown; The Surfactants and Phase Components; Chapter Nine - Foams; Introduction; The Physical Basis for Foam Formation; The Physical Role of the Surfactant in Foams; Foam Formation and Surfactant Structure; Liquid Crystals and Foam Stability; The Effects of Additives on Surfactant Foaming Properties; Foam Inhibition; Chemical Structures of Antifoaming Agents; A Summary of the Foaming and Antifoaming Activity of Additives; Chapter Ten - Surfactants at the Solid/Liquid Interface; Introduction; The Nature of Solid Surfaces; Liquid versus Solid Surfaces; Adsorption at the Solid/Liquid Interface; Adsorption Isotherms; Mechanisms of Surfactant Adsorption; The Electrical Double Layer; The Mechanics of Surfactant Adsorption; Adsorption and the Nature of the Adsorbent Surface; Nonpolar, Hydrophobic Surfaces; Polar, Uncharged Surfaces; Surfaces Having Discrete Electrical Charges; Surfactant Structure and Adsorption from Solution; Surfaces Possessing Strong Charge Sites; Adsorption by Uncharged, Polar Surfaces; Surfactants at Nonpolar, Hydrophobic Surfaces; The Effect of Surfactant Adsorption on the Character of the Solid Surface; Wetting and Related Phenomena; Surfactant Manipulation of the Wetting Process; Some Practical Aspects of Wetting Control by Surfactants; Detergency and Soil Removal; The Cleaning Process; Soil Types; Solid Soil Removal; Liquid Soil Removal; Redeposition; Correlations of Surfactant Structure and Detergency; Nonaqueous Cleaning Solutions; Enhanced Oil Recovery; Suspension of Solids in Liquids; A Final Comment; Bibliography; References; Index

Erscheint lt. Verlag 15.5.1992
Verlagsort New York
Sprache englisch
Maße 160 x 240 mm
Gewicht 680 g
Einbandart gebunden
Themenwelt Naturwissenschaften Chemie Physikalische Chemie
ISBN-13 9780471188414 / 9780471188414
Zustand Neuware
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