Solutions Manual for Principles of Physical Chemistry, 3rd Edition (eBook)

Hans Kuhn, David H. Waldeck, Horst-Dieter Försterling (Autoren)

eBook Download: PDF

2024 | 3. Auflage
736 Seiten
Wiley (Verlag)
978-1-119-85292-6 (ISBN)

Infos

This is a Solutions Manual to Accompany with solutions to the exercises in the main volume of Principles of Physical Chemistry, Third Edition.

This book provides a unique approach to introduce undergraduate students to the concepts and methods of physical chemistry, which are the foundational principles of Chemistry. The book introduces the student to the principles underlying the essential sub-fields of quantum mechanics, atomic and molecular structure, atomic and molecular spectroscopy, statistical thermodynamics, classical thermodynamics, solutions and equilibria, electrochemistry, kinetics and reaction dynamics, macromolecules, and organized molecular assemblies. Importantly, the book develops and applies these principles to supramolecular assemblies and supramolecular machines, with many examples from biology and nanoscience. In this way, the book helps the student to see the frontier of modern physical chemistry developments.

The book begins with a discussion of wave-particle duality and proceeds systematically to more complex chemical systems in order to relate the story of physical chemistry in an intellectually coherent manner. The topics are organized to correspond with those typically given in each of a two course semester sequence. The first 13 chapters present quantum mechanics and spectroscopy to describe and predict the structure of matter: atoms, molecules, and solids. Chapters 14 to 29 present statistical thermodynamics and kinetics and applies their principles to understanding equilibria, chemical transformations, macromolecular properties and supramolecular machines. Each chapter of the book begins with a simplified view of a topic and evolves to more rigorous description, in order to provide the student (and instructor) flexibility to choose the level of rigor and detail that suits them best. The textbook treats important new directions in physical chemistry research, including chapters on macromolecules, principles of interfaces and films for organizing matter, and supramolecular machines -- as well as including discussions of modern nanoscience, spectroscopy, and reaction dynamics throughout the text.

Inhalt

Cover 1
Title Page 5
Copyright 6
Contents 7
Preface Third Edition 11
Acknowledgment 13
Chapter 1 Wave–Particle Duality 15
1.1 Exercises 15
1.2 Problems 21
Chapter 2 Essential Aspects of Structure and Bonding 27
2.1 Exercises 27
2.2 Problems 34
Chapter 3 Schrödinger Equation 42
3.1 Exercises 42
3.2 Problems 54
Chapter 4 Hydrogen Atom 72
4.1 Exercises 72
4.2 Problems 84
Chapter 5 Atoms and Variational Principle 104
5.1 Exercises 104
5.2 Problems 117
Chapter 6 A Quantitative View of Chemical Bonding 138
6.1 Exercises 138
6.2 Problems 146
Chapter 7 Bonding Described by Electron Pairs and Molecular Orbitals 158
7.1 Exercises 158
7.2 Problems 170
Chapter 8 Molecules with PI?Electron Systems 182
8.1 Exercises 182
8.2 Problems 197
Chapter 9 Absorption of Light 214
9.1 Exercises 214
9.2 Problems 227
Chapter 10 Emission of Light 253
10.1 Exercises 253
10.2 Problems 259
Chapter 11 Nuclei: Particle and Wave Properties 264
11.1 Exercises 264
11.2 Problems 283
Chapter 12 Nuclear Spin 303
12.1 Exercises 303
12.2 Problems 307
Chapter 13 Solids and Intermolecular Forces 309
13.1 Exercises 309
13.2 Problems 324
Chapter 14 Thermal Motion of Molecules 338
14.1 Exercises 338
14.2 Problems 347
Chapter 15 Energy Distribution in Molecular Assemblies 356
15.1 Exercises 356
15.2 Problems 376
Chapter 16 Work w, Heat q, and Internal Energy U 395
16.1 Exercises 395
16.2 Problems 407
Chapter 17 Reversible Work wrev, Reversible Heat qrev, and Entropy S 418
17.1 Exercises 418
17.2 Problems 432
Chapter 18 General Conditions for Spontaneity and its Application to Equilibria of Ideal Gases and Dilute Solutions 449
18.1 Exercises 449
18.2 Problems 467
Chapter 19 Formal Thermodynamics and Its Application to Phase Equilibria 483
19.1 Exercises 483
19.2 Problems 495
Chapter 20 Real Gases 511
20.1 Exercises 511
20.2 Problems 527
Chapter 21 Real Solutions 541
21.1 Exercises 541
21.2 Problems 554
Chapter 22 Reaction Equilibria in Aqueous Solutions and Biosystems 564
22.1 Exercises 564
22.2 Problems 577
Chapter 23 Chemical Reactions in Electrochemical Cells 589
23.1 Exercises 589
23.2 Problems 600
Chapter 24 Chemical Kinetics 612
24.1 Exercises 612
24.2 Problems 627
Chapter 25 Transition States and Chemical Reactions 640
25.1 Exercises 640
25.2 Problems 655
Chapter 26 Macromolecules 669
26.1 Exercises 669
26.2 Problems 681
Chapter 27 Organized Molecular Assemblies 694
27.1 Exercises 694
27.2 Problems 706
Chapter 28 Supramolecular Machines 714
28.1 Exercises 714
28.2 Problems 725
Chapter 29 Origin of Life. Matter Carrying Information 731
29.1 Exercises 731
29.2 Problems 732
EULA 736

Produkt-Details

• Erscheint lt. Verlag: 4.9.2024
• Sprache: englisch
• Themenwelt: Naturwissenschaften ► Chemie ► Physikalische Chemie
• Schlagworte: atomic spectroscopy • chemical bonding • De Broglie • electronic structure • Electron tunneling • molecular structure • Pauli exclusion • quantum beats • quantum confinement • Quantum dots • quantum mechanics • spin-orbit interactions • Variational Principle
• ISBN-10: 1-119-85292-7 / 1119852927
• ISBN-13: 978-1-119-85292-6 / 9781119852926