Supramolecular Polymers and Assemblies (eBook)

From Synthesis to Properties and Applications

Ulrich S. Schubert, George R. Newkome, Andreas Winter (Autoren)

eBook Download: EPUB

2021
Wiley-VCH GmbH (Verlag)
978-3-527-83240-8 (ISBN)

Infos

Explore modern characterization methods and new applications in this modern overview of supramolecular polymer chemistry

Supramolecular Polymers and Assemblies: From Synthesis to Properties and Applications delivers a superlative summary and description of general concepts and definitions in the field. The book offers informative and accessible treatments of crucial concepts like metal-containing compounds, hydrogen bonding, ionic interactions, pi-pi stacking, and more.

Characterization remains a primary focus of the book throughout, making it extremely useful for practitioners in the field. Emphasis is also placed on metallo-supramolecular polymers and materials which have found applications in areas like smart or intelligent materials and systems with special photochemical and photophysical properties, like LEDs and solar cells. Applications, including self-healing materials, opto-electronics, sensing, and catalysis are all discussed as well.

The book details many of the exciting developments in the field of supramolecular chemistry that have occurred since the 1987 Nobel Prize was awarded to pioneers in this rapidly developing field. Readers will also benefit from the inclusion of:

• A thorough introduction to supramolecular assemblies based on ionic interactions
• Explorations of supramolecular polymers based on hydrogen-bonding interactions, metal-to-ligand interactions, p-Electronic interactions, crown-ether recognition, cucurbiturils, and host-guest chemistry of calixarenes
• A discussion of cyclodextrins in the field of supramolecular polymers
• Examinations of supramolecular polymers based on the host-guest chemistry of pillarenes, and those formed by orthogonal non-covalent interactions
• A treatment of the characterization of supramolecular polymers

Supramolecular Polymers and Assemblies: From Synthesis to Properties and Applications will earn a place in the libraries of researchers and practitioners of the material science, as well as polymer chemists seeding a one-stop reference for supramolecular polymers.

Ulrich S. Schubert, PhD, is Full-Professor at the Friedrich-Schiller-University Jena (Chair of Organic and Macromolecular Chemistry) in Germany. He has published over 530 scholarly papers, 20 patents, and edited or written 5 scientific books.

George R. Newkome, PhD, is Affiliate Research Professor at the Center for Molecular Biology and Biotechnology in Jupiter, Florida, USA.

Andreas Winter, PhD, joined the group of Professor U. S. Schubert at the Eindhoven University of Technology in The Netherlands and the Friedrich-Schiller University Jena, Germany. His research is focused on the synthesis of emissive and luminescent metallo-supramolecular assemblies.

Autor

Ulrich S. Schubert was born in Tübingen (Germany) in 1969. He studied chemistry in Frankfurt and Bayreuth (both Germany) and at the Virginia Commonwealth University, Richmond (USA). His Ph.D. studies were performed at the Universities of Bayreuth and South Florida. After a postdoctoral training with J.-M. Lehn at the University of Strasbourg (France), he moved to the TU Munich (Germany) and obtained his Habilitation in 1999. During 1999-2000, he was Professor at the University of Munich and during 2000-2007 Full-Professor at the TU Eindhoven (the Netherlands). Since 2007, he is Full-Professor at the Friedrich Schiller University Jena, Germany. Prof. Schubert is founder and director of the Jena Center for Soft Matter (JCSM) and the Center for Energy and Environmental Chemistry Jena (CEEC Jena). He received a VICI award of the Netherlands Organization for Scientific Research (NWO) and is Fellow of the ACS Division of Polymer Chemistry, Polymer Division (USA), the Royal Society of Chemistry (FRSC, UK), and the National Academy of Inventors (NAI, USA). Prof. Schubert is Elected Member of the German National Academy of Science and Engineering (acatech) and External Scientific Member of the Max Planck Society (MPI for Colloid & Interfaces, Golm). He has currently an h-Index of 107 and since 2016 is listed as ISI "Highly cited researcher". Andreas Winter was born in Herne (Germany) and studied chemistry at the University of Dortmund (Germany) where he graduated in organic chemistry in 1999. In 2003 he received his Ph.D. in chemistry (University of Paderborn, Germany) for work on applications of the Mannich reaction in the synthesis of pyridine derivatives under supervision of Professor N. Risch, and stayed on as a postdoc. Subsequently, in 2005 he joined the group of Prof. U. S. Schubert (Eindhoven University of Technology, The Netherlands and Friedrich-Schiller University Jena, Germany). His research is focused on the synthesis of emissive and luminescent metallo-supramolecular assemblies. George R. Newkome received his B.S. and Ph.D. in chemistry from Kent State University. He joined Louisiana State University in 1968, becoming a full professor in 1978 and Distinguished Research Master in 1982. In 1986, he moved to the University of South Florida as Vice President for Research and Professor of Chemistry, becoming a Distinguished Research Professor in 1992. In 2001, he was appointed as Oelschlager Professor of Science and Technology at the University of Akron, where he is also Professor of Polymer Science and Chemistry, Vice President for Research, Dean of the Graduate School, and President of the University's Research Foundation. He has published over 450 papers as well as 50+ U. S. patents, 9 books, and 16 edited books and journals. His research is focused on supramacromolecular chemistry, molecular dendritic and fractal assemblies, nanochemistry, inorganic-organic interfaces, molecular inclusion chemistry, molecular electronics, and photonics.

Inhalt

Supramolecular Polymers: General Considerations
Supramolecular Assemblies Based on Ionic Interactions
Supramolecular Polymers, Based on Hydrogen-Bonding Interactions
Supramolecular Polymers, Based on Metal-to-Ligand Interactions
Supramolecular Polymers, Based on p-Electronic Interactions
Supramolecular Polymers, Based on Crown-ether Recognition
Supramolecular Polymers Based on Cucurbiturils
Supramolecular Polymers, Based on the Host-Guest Chemistry of Calixarenes
Cyclodextrins in the Field of Supramolecular Polymers
Supramolecular Polymers, Based on the Host-Guest Chemistry of Pillarenes
Supramolecular Polymers, Formed by Orthogonal Non-covalent Interactions
Characterization of Supramolecular Polymers

Textauszug

Abbreviations

18C6	18‐crown‐6

A	adenine or absorbance

A2	second virial coefficient

acac	acetoacetate

ACQ	aggregation‐caused quenching

AFM	atomic force microscopy

AF4	asymmetric flow field flow fractionation

AIE	aggregation‐induced emission

Alq3	tris(8‐hydroxyquinolinato)aluminium

ATP	adenosine triphosphate

ATRP	atom transfer radical polymerization

AUC	analytical ultracentrifugation

bdt	1,2‐benzenedithiolate

bFGF	basic fibroblast growth factor

Bn

benzyl

BODIPY

boron‐dipyrromethene

BMP32C10

bis(m‐phenylene)‐32‐crown‐10

BPP34C10

bis(p‐phenylene)‐34‐crown‐10

BSA	Bovine serum albumin

B21C7

benzo‐21‐crown‐7

cac	critical aggregation concentration

CB[n]

cucurbit[n]uril; n = number of glycuril units

CD	circular dichroism or cyclodextrin

CDSA	crystallization‐driven self‐assembly

ceff	effective concentration

Ce6	chlorin‐e6

cgc	critical gelation concentration

Ch+	cycloheptatrienyl cation

ChE	cholinesterase

CIA	calixarene‐induced aggregation

CIE	commission Internationale de l′Éclairage

CLSM	confocal laser scanning microscopy

cmc	critical micellar concentration

CNT	carbon nanotube

CONASH

coordination nanosheet

cpc	critical polymerization concentration

CPK (models)

3D molecular models

CS	cold spray

CT	charge transfer

CuCAAC

Cu(I)‐catalyzed azide‐to‐alkyne cycloaddition

CV	cyclic voltammetry

CVD	chemical vapor deposition

DABCO

1,4‐diazabicyclo[2.2.2]octane

DBU	1,8‐diazabicyclo[5.4.0]undec‐7‐ene

DB24C8

Dibenzo‐24‐crown‐8

DCC	dynamic covalent chemistry

DEB	diethyl barbiturate

DHP	dihexyldecylphosphonate

DLS	dynamic light scattering

DMAc	dimethyl acetamide

DMF	dimethyl formamide

DMSO	dimethylsulfoxide

DNA	deoxyribonucleic acid

DP	degree of polymerization

DPP	diphenylphenanthrene or diketopyrrolopyrrole

DOSY	diffusion‐ordered (NMR) spectroscopy

DOX	doxorubicin

DQ	(1H) double quantum

DSC	differential scanning calorimetry

Ð	dispersity

E	molar absorptivity

EDTA	ethylenediamine tetraacetic acid

EPR	electron paramagnetic resonance

EM	effective molarity

ESI	electrospray ionization

exTTF

π‐extended tetrathiafulvalene

f	packing factor

fH	host molar fraction

FAB	fast atom bombardment

Fc+	ferrocenium cation

FDA	U.S. Food and Drug Administration

FE	field emission

FEB	frequency‐domain electric birefringence

FF	fill factor

FRET	Föster‐type resonance energy transfer

FRP	free‐radical polymerization

FTICR

Fourier‐transform ion cyclotron resonance

FT‐IR

Fourier‐transform infrared

GAL1	Galectin‐1

gMS2	gradient tandem MS2

ΔG0	Gibbs free energy

HBC	hexabenzocoronene

HDPE	high‐density polyethylene

HEEDTA

hydroxyethylethylenediaminetriacetic acid

HER	hydrogen‐evolution reaction

HETPHEN

heteroleptic phenanthroline

HFIP	1,1,1,3,3,3‐hexafluoroisopropanol

HG	host–guest complex

HPLC	high‐performance liquid chromatography

HOMO	highest occupied molecular orbital

HOPG	highly‐ordered pyrolytic graphite

HSAB	hard and soft acid and bases

HSCT	host‐stabilized charge transfer

I	scattered intensity

IDP	isodesmic supramolecular polymerization

IM	ion mobility

IR

infrared

ISA	ionic self‐assembly

ITC	isothermal titration calorimetry

ITO	indium tin oxide

Ka	association constant

Kd	dissociation constant

L	persistence length of polymer

LB	Langmuir–Blodgett

LC	liquid crystal (or liquid crystalline)

LCD	liquid crystal display

LCST	lower critical solution temperature

LED	light‐emitting diode

LSI	liquid secondary ion

LT	low temperature

LUMO	lowest unoccupied molecular orbital

Mn	molar mass

Mw	molecular weight

MALDI

matrix‐assisted laser desorption/ionization

MALS	multi‐angle light scattering

MAS	magic angle spinning

Mb

myglobin

MDI	methylenediphenyl‐4,4′‐diisocyanate

mebip

2,6‐bis(1‐methyl‐1H‐benzo[d]imidazole‐2‐yl)pyridine

MFP	molecular force probe

MLCT	metal‐to‐ligand charge transfer

MMLCT

metal‐metal‐to‐ligand charge transfer

MM2	molecular modeling 2...

Produkt-Details

• Erscheint lt. Verlag: 1.3.2021
• Sprache: englisch
• Themenwelt: Naturwissenschaften ► Chemie ► Organische Chemie
• Schlagworte: Chemie • Chemistry • Materialeigenschaften • Materials Science • Materialwissenschaften • Polymere • Polymer Science & Technology • Polymersynthese • polymer synthesis • Polymerwissenschaft u. -technologie • properties of materials • supramolecular assembly characterization • supramolecular chemistry • supramolecular polymer applications • supramolecular polymer characterization • Supramolecular polymeric chemistry • supramolecular polymer properties • supramolecular polymer synthesis • Supramolekulare Chemie
• ISBN-10: 3-527-83240-8 / 3527832408
• ISBN-13: 978-3-527-83240-8 / 9783527832408