Synthesis and Applications of New Spin Crossover Compounds

Buch | Softcover

254 Seiten

2019
MDPI (Verlag)
9783039213610 (ISBN)

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The crystal chemistry of spin crossover (SCO) behavior in coordination compounds can potentially be in association with smart materials—promising materials for applications as components of memory devices, displays, sensors and mechanical devices and, especially, actuators, such as artificial muscles. This Special Issue is devoted to various aspects of SCO and related research, comprising 18 interesting original papers on valuable and important SCO topics. Significant and fundamental scientific attention has been focused on the SCO phenomena in a wide research range of fields of fundamental chemical and physical and related sciences, containing the interdisciplinary regions of chemical and physical sciences related to the SCO phenomena. Coordination materials with bistable systems between the LS and the HS states are usually triggered by external stimuli, such as temperature, light, pressure, guest molecule inclusion, soft X-ray, and nuclear decay. Since the first Hofmann-like spin crossover (SCO) behavior in {Fe(py)2[Ni(CN)4]}n (py = pyridine) was demonstrated, this crystal chemistry motif has been frequently used to design Fe(II) SCO materials to enable determination of the correlations between structural features and magnetic properties.

Erscheinungsdatum	20.11.2019
Verlagsort	Basel
Sprache	englisch
Maße	170 x 244 mm
Themenwelt	Naturwissenschaften ► Geowissenschaften ► Mineralogie / Paläontologie
	Naturwissenschaften ► Physik / Astronomie ► Atom- / Kern- / Molekularphysik
	Naturwissenschaften ► Physik / Astronomie ► Thermodynamik
Schlagworte	1,2,3-triazole • 1,2-bis(4-pyridyl)ethane • 57Fe Mössbauer spectroscopy • aminoxyl • Amorphous • Atropisomerism • [Au(dmit)2]−, [Au(dddt)2]− • charge-transfer phase transition • chiral propeller structure • C–H···π interactions • cobalt(II) ion • Cobalt Oxide • Coordination Complexes • coordination polymer • Coordination polymers • counter-anion • Crystal engineering • crystal structure • Cu(II) complexes • DFT calculation • Dielectric Response • dinuclear triple helicate • dipyridyl-N-alkylamine ligands • dithiooxalato ligand • EPR spectroscopy • fatigability • Fe(II) • Fe(II) complex • [Fe(III)(3-OMesal2-trien)]+ • Fe(III) complex • Fe(III) coordination complexes • ferromagnetism • hetero metal complex • hexadentate ligand • High Spin • high spin (HS) • Hydrogen Bonding • impurity effect • intermolecular interactions • ion-pair crystals • iron(II) • iron(II) complexes • iron (II), spin crossover • iron mixed-valence complex • lattice energy • LIESST effect • linear pentadentate ligand • low spin (LS) • Magnetic properties • magnetic susceptibility • magnetic transition • magnetization • magnetostructural correlations • metal dithiolene complexes • mononuclear • mosaicity • N/A • nitroxides • optical conductivity spectrum • Optical microscopy • paramagnetic ligand • phase transition • phase transitions • qsal ligand • Reaction Diffusion • Schiff Base • Single Crystal • soft X-ray induced excited spin state trapping • Solvate • solvent effects • Spin Crossover • Spin-Crossover • spin cross-over (SCO) • spin-crossover transition • spin polaron • spin-state crossover • Spin transition • spiral structure • SQUID • Structural disorder • structure phase transition • substitution of 3d transition metal ion • supramolecular coordination polymer • supramolecular isomerism • Switch • thermal hysteresis • Thermochromism • UV-Vis Spectroscopy • X-ray absorption spectroscopy • X-ray diffraction • π-π interactions
ISBN-13	9783039213610 / 9783039213610
Zustand	Neuware