The Organometallic Chemistry of the Transition Metals (eBook)

Robert H. Crabtree (Autor)

eBook Download: EPUB

2019 | 7. Auflage
John Wiley & Sons (Verlag)
9781119465867 (ISBN)

Infos

Provides vital information on organometallic compounds, their preparation, and use in synthesis, and explores the fundamentals of the field and its modern applications

Fully updated and expanded to reflect recent advances, the new, seventh edition of this bestselling text presents students and professional chemists with a comprehensive introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and detailed descriptions of contemporary applications. Increased focus is given to organic synthesis applications, nanoparticle science, and green chemistry. This edition features up-to-date examples of fundamental reaction steps and greater emphasis on key topics like oxidation catalysis, CH functionalization, nanoclusters and nanoparticles, and green chemistry. New coverage is added for computational chemistry, energy production, and biochemical aspects of organometallic chemistry.

The Organometallic Chemistry of the Transition Metals, Seventh Edition provides new/enhanced chapter coverage of ligand-assisted additions and eliminations; proton-coupled electron transfer; surface, supported, and cooperative catalysis; green, energy, and materials applications; and photoredox catalysis. It covers coordination chemistry; alkyls and hydrides; Pi-complexes; and oxidative addition and reductive elimination. The book also features sections on insertion and elimination; spectroscopy; metathesis polymerization and bond activation; and more.

• Provides an excellent foundation of the fundamentals of organometallic chemistry
• Includes end-of-chapter problems and their solutions
• Expands and includes up-to-date examples of fundamental reaction steps and focuses on important topics such as oxidation catalysis, CH functionalization, nanoparticles, and green chemistry
• Features all new coverage for computational chemistry, energy production, and biochemical aspects of organometallic chemistry

The Organometallic Chemistry of the Transition Metals, Seventh Edition is an insightful book that will appeal to all advanced undergraduate and graduate students in organic chemistry, organometallic chemistry, inorganic chemistry, and bioinorganic chemistry, as well as any practicing chemist in those fields.

Robert H. Crabtree F.R.S. is Whitehead Professor of Chemistry at Yale, a Fellow of the Royal Society and of the American Chemical Society, and a member of the American Academy and of the National Academy of Sciences.

Textauszug

List of Abbreviations

[ ]	Encloses complex molecules or ions

□	Vacant site or labile ligand

°	Degrees Celsius

1°, 2°, 3°

Primary, secondary, tertiary.

A	Associative substitution (Section 4.4)

acac	Acetylacetonate

AIBN	Azobisisobutyronitrile (radical initiator)

AO	Atomic orbital

Ar	Aryl (e.g. C6H5)

at.	Pressure in atmospheres

bipy	2,2′‐Bipyridyl

Bu

Butyl

cata

Catalyst

Chap.

Chapter

CIDNP

Chemically induced dynamic nuclear polarization (Section 6.3)

CN	Coordination number

cod	1,5‐Cyclooctadiene

coe	Cyclooctene

cot	Cyclooctatetraene

Cp, Cp*

C5H5, C5Me5

Cy	Cyclohexyl

∂+	Partial positive charge

δ	Chemical shift (NMR)

Δ	Crystal field splitting (Section 1.4)

ΔEN	Electronegativity difference

ΔG ‡ ΔH ‡ ΔS ‡

Free energy, enthalpy and entropy of activation needed to reach the transition state for a reaction.

D	Dissociative substitution mechanism (Section 4.3)

D–C	Dewar–Chatt model of M(C=C) bonding involving weak back donation (Section 5.1)

dσ, dπ

σ‐Acceptor and π‐donor metal orbitals (see Section 1.4)

diars

Me2AsCH2CH2AsMe2

dpe or dppe

Ph2PCH2CH2PPh2

dmf	Dimethylformamide

dmg	Dimethyl glyoximate

dmpe	Me2PCH2CH2PMe2

DMSO	Dimethyl sulfoxide

d n	Electron configuration (Section 1.4)

η	Hapticity in ligands with contiguous donor atoms (e.g. C2H4. See Section 2.1)

E, E+

Generalized electrophile such as H+

e	Electron, as in 18e rule

e.e.	Enantiomeric excess (Section 9.2)

en	H2NCH2CH2NH2

eq	Equivalent or equatorial

Et

Ethyl

EPR	Electron paramagnetic resonance

Eq.

Equation

eu	Entropy units

eV	Electron volt (1 eV = 23 kcal/mol)

EXAFS

X‐ray absorption edge fine structure spectroscopy

Fig.

Figure

Fp	(C5H5)(CO)2Fe

fac	Facial (stereochemistry)

GC	gas chromatography

Hal

Halogen

HBpz3

Tris(pyrazolyl)borate

HMPA	Hexamethyl phosphoramide O=P(NMe2)3

HOMO	Highest occupied molecular orbital

hs

High spin

I	Nuclear spin

I	Intermediate substitution mechanism

IPR	Isotopic perturbation of resonance (Section 10.8)

IR

Infrared

κ	Hapticity in ligands with noncontiguous donor atoms (e.g. H2NCH2CH2NH2. See Section 2.1)

L	Depending on the context, L can be a generalized ligand of any type, or else a 2e ligand in connection with the L model for ligand binding discussed in Section 2.1)

L n M

Metal fragment with n generalized ligands

lin

Linear

lp

lone pair

ls

low spin

LUMO	Lowest unoccupied molecular orbital

μ	Descriptor for bridging with a superscript for the number of metals bridged, as in M3(μ3‐CO)

m‐

Meta

MCP	Metalacyclopropane model of M(C=C) bonding involving strong back donation (Section 5.1)

Me

Methyl

mer	Meridional (stereochemistry)

m r	Reduced mass

MO	Molecular orbital

ν

Frequency

N	Group number of M (=number of valence e in the neutral atom).

nbd	Norbornadiene

NHC	N‐heterocyclic carbene (Section 4.2)

NHE	Normal hydrogen electrode, a common standard potential

NMR	Nuclear magnetic resonance (Sections 10.2-10.8)

NOE	Nuclear Overhauser effect (Section 10.7)

Np

Neopentyl

Nu, Nu−

Generalized nucleophile, such as H−

o‐

Ortho

OA	Oxidative addition

OAc

Acetate

oct	Octahedral (Table 2.6)

OS	Oxidation state (Section 2.4)

oz.	Ounce (28.35g)

p‐

Para

PE	Polyethylene

PP	Polypropylene

Ph

Phenyl

pin	Pinacolate

PNP	A pincer ligand with one nitrogen and two phosphorus donors

py

Pyridine

R

Alkyl

RE	Reductive elimination

RF	Radiofrequency

RF	Fluoroalkyl (e.g. CF3)

Sec.	Section of the book

SET	Single electron transfer (Section 8.6)

σ‐CAM

σ‐Complex assisted metathesis

solv

Solvent

sq. pl.

Square planar

sq. py.

Square pyramidal (Table 2.6)

T	A structure with three of the ligands disposed as in the letter T.

T 1	Spin–lattice relaxation time

tacn	1,4,7‐Triazacyclononane

tacn*

N,N′,N″‐trimethyl‐1,4,7‐triazacyclononane

tbe	t‐BuCH=CH2

tet	Tetrahedral

thf	Tetrahydrofuran ligand (but THF when a solvent)

triphos

MeC(CH2PPh2)3

TBP or trig. bipy

Trigonal bipyramidal (Table 2.6)

TMEDA

Me2NCH2CH2NMe2

TMS	Tetramethylsilyl or...

Produkt-Details

• Erscheint lt. Verlag: 3.7.2019
• Sprache: englisch
• Themenwelt: Naturwissenschaften ► Chemie ► Organische Chemie
• Schlagworte: Anorganische Chemie • biotech</p> • Chemie • Chemistry • Inorganic Chemistry • Inorganic Metal Ions • <p>organometallic chemistry • Materials Science • Organic Chemistry • organic molecules • Organische Chemie • Organometallchemie • Organometallic • Organometallic Chemistry • Organometallics • pharmaceuticals • Polymers • Polymer Science • product synthesis • Synthetic Organic Chemistry • transition metals
• ISBN-13: 9781119465867 / 9781119465867