A Theoretical Study of Pd-Catalyzed C-C Cross-Coupling Reactions
Seiten
2016
|
Softcover reprint of the original 1st ed. 2013
Springer International Publishing (Verlag)
978-3-319-34866-7 (ISBN)
Springer International Publishing (Verlag)
978-3-319-34866-7 (ISBN)
This volume shows readers how theoretical calculations are used to determine, elucidate and propose mechanisms for Pd-catalyzed C-C cross-coupling reactions.
Find out how theoretical calculations are used to determine, elucidate and propose mechanisms for Pd-catalyzed C-C cross-coupling reactions in Max Garcia Melchor's outstanding thesis. Garcia Melchor investigates one of the most significant and useful types of reactions in modern organic synthesis; the Pd-cross coupling reaction. Due to its versatility, broad scope and selectivity under mild conditions, this type of reaction can now be applied in fields as diverse as the agrochemical and pharmaceutical industry. Garcia Melchor studies the reaction intermediates and transition states involved in the Negishi, the copper-free Sonogashira and the asymmetric version of Suzuki-Miyaura coupling. He also characterizes and provides a detailed picture of the associated reaction mechanisms. The author has won numerous prizes for this work which has led to over eight publications in internationally renowned journals.
Find out how theoretical calculations are used to determine, elucidate and propose mechanisms for Pd-catalyzed C-C cross-coupling reactions in Max Garcia Melchor's outstanding thesis. Garcia Melchor investigates one of the most significant and useful types of reactions in modern organic synthesis; the Pd-cross coupling reaction. Due to its versatility, broad scope and selectivity under mild conditions, this type of reaction can now be applied in fields as diverse as the agrochemical and pharmaceutical industry. Garcia Melchor studies the reaction intermediates and transition states involved in the Negishi, the copper-free Sonogashira and the asymmetric version of Suzuki-Miyaura coupling. He also characterizes and provides a detailed picture of the associated reaction mechanisms. The author has won numerous prizes for this work which has led to over eight publications in internationally renowned journals.
General introduction.- Computational methods.- Objectives.- The Negishi reaction mechanism.- The Cu-free Sonogashira reaction mechanism.- An asymmetric Suzuki-Miyaura reaction mechanism.- General conclusions.
| Erscheinungsdatum | 29.08.2016 |
|---|---|
| Reihe/Serie | Springer Theses |
| Zusatzinfo | XVIII, 136 p. 76 illus., 68 illus. in color. |
| Verlagsort | Cham |
| Sprache | englisch |
| Maße | 155 x 235 mm |
| Themenwelt | Naturwissenschaften ► Chemie ► Organische Chemie |
| Naturwissenschaften ► Chemie ► Physikalische Chemie | |
| Schlagworte | catalysis • Catalytic Cycle • C-C Bond Formation • Chemistry and Materials Science • Cross-couplings • DFT Calculations • Homogeneous catalysis • Organic Chemistry • Organometallic Reactivity • Palladium • Palladium Complexes • Quantum and theoretical chemistry • Reactions Mechanisms • theoretical and computational chemistry • Theoretical calculations |
| ISBN-10 | 3-319-34866-3 / 3319348663 |
| ISBN-13 | 978-3-319-34866-7 / 9783319348667 |
| Zustand | Neuware |
| Informationen gemäß Produktsicherheitsverordnung (GPSR) | |
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