The Sol-Gel Handbook (eBook)

Synthesis, Characterization, and Applications

David Levy, Marcos Zayat (Herausgeber)

eBook Download: EPUB

2015
Wiley-VCH (Verlag)
978-3-527-67083-3 (ISBN)

Infos

This comprehensive three-volume handbook brings together a review of the current state together with the latest developments in sol-gel technology to put forward new ideas.
The first volume, dedicated to synthesis and shaping, gives an in-depth overview of the wet-chemical processes that constitute the core of the sol-gel method and presents the various pathways for the successful synthesis of inorganic and hybrid organic-inorganic materials, bio- and bio-inspired materials, powders, particles and fibers as well as sol-gel derived thin films, coatings and surfaces.
The second volume deals with the mechanical, optical, electrical and magnetic properties of sol-gel derived materials and the methods for their characterization such as diffraction methods and nuclear magnetic resonance, infrared and Raman spectroscopies.
The third volume concentrates on the various applications in the fields of membrane science, catalysis, energy research, biomaterials science, biomedicine, photonics and electronics.


David Levy is a Research Professor and head of the Sol-Gel Group at the Materials Science Institute of Madrid (ICMM) of the Consejo Superior de Investigaciones Cienti cas. His research interests are optical materials (bulk materials; thin- lm coatings as AR optical coatings, protection transparent coatings and functional coatings; oxide nanoparticles) and liquid crystal materials, by Sol-Gel processing and their applications. During his time at The Hebrew University of Jerusalem David Levy pioneered the sol-gel process for the preparation of organically doped silica-gel glasses. He has more than 130 publications and a number of patents to his name, and has received numerous prizes in recognition of his groundbreaking work on sol-gel materials, including the ?First Ulrich Prize? and the nomination to King Juan Carlos-I research award.

Marcos Zayat is currently vice-director of the Materials Science Institute of Madrid (ICMM). His scienti c interests are centered on the design of new optical coatings and the characterization of their physicochemical properties. After having obtained his PhD in Materials Science from The Hebrew University of Jerusalem in 1997, Marcos Zayat joined the ICMM where he continues developing sol-gel materials for optical and electrooptical applications. He has published more than fty original articles in prestigious scienti c journals.

Autor

David Levy is a Research Professor and head of the Sol-Gel Group at the Materials Science Institute of Madrid (ICMM) of the Consejo Superior de Investigaciones Cientí cas. His research interests are optical materials (bulk materials; thin- lm coatings as AR optical coatings, protection transparent coatings and functional coatings; oxide nanoparticles) and liquid crystal materials, by Sol-Gel processing and their applications. During his time at The Hebrew University of Jerusalem David Levy pioneered the sol-gel process for the preparation of organically doped silica-gel glasses. He has more than 130 publications and a number of patents to his name, and has received numerous prizes in recognition of his groundbreaking work on sol-gel materials, including the ?First Ulrich Prize? and the nomination to King Juan Carlos-I research award. Marcos Zayat is currently vice-director of the Materials Science Institute of Madrid (ICMM). His scienti c interests are centered on the design of new optical coatings and the characterization of their physicochemical properties. After having obtained his PhD in Materials Science from The Hebrew University of Jerusalem in 1997, Marcos Zayat joined the ICMM where he continues developing sol-gel materials for optical and electrooptical applications. He has published more than fty original articles in prestigious scienti c journals.

Inhalt

VOLUME 1: SYNTHESIS AND SHAPING

SOL-GEL CHEMISTRY
Chemistry and Fundamentals of the Sol-Gel Process
Green Chemistry and Non-Conventional Routes
Precursors, Chemistry, Synthesis, Solution (Alkoxides, Polymeric, Aqueous, Metal Salts)
Reactions towards Nanostructured or Multi-Component Oxides
SPECIAL TECHNIQUES USED IN SOL-GEL PROCESSING
Non-Hydrolytic Sol-Gel Technology
Ultraviolet (UV) Irradiation Assisted Processing
Ultrasound
ORGANIC-INORGANIC HYBRID MATERIALS
Molecular Chemistry and Approaches
Synthesis Strategies
Properties and Applications
BIOMATERIALS, BIOHYBRIDS AND BIOINSPIRED MATERIALS
Biohybrids and Related Materials
Bioceramics, Biocompatible and Environmentally-friendly Materials
Medical Applications
POWDERS, PARTICLES, BULK-MATERIALS, FIBERS AND NON-OXIDE MATERIALS
Sol-Gel Derived Powders (Micro-, Nano- Particles and Spheres); Properties and Applications
Formation of Bulk Materials (Ceramics, Glasses)
Self-Assembling
Processing of Fibers
Formation and Processing of Oxynitride Glasses and Nitrides, Carbides, Fluoride and Sulfide Materials
Composites
THIN FILMS, COATINGS AND SURFACES
Fundamentals of Sol-Gel Coatings
Chemistry and Deposition Methods of Sol-Gel Thin-Films
Thick Films
Special Coatings
PROCESSING OF POROUS MATERIALS AND AEROGELS
Morphology Control
Formation of Ordered Macroporous and Mesoporous Materials
Supramolecular and and Hierarchically Structured Sol-Gel Materials
Aerogels, Foams and Insulating Materials

VOLUME 2: PROPERTIES

STRUCTURAL AND RHEOLOGICAL CHARACTERIZATION
X-ray and Neutron Diffraction Studies
Solid State NMR
IR, XPS, Raman and Brillouin Spectroscopies
Surface and Porosity Characterization
New Characterization Techniques
MECHANICAL PROPERTIES
Mechanical Properties of Gels
Mechanical Properties of Sol-Gel Coatings
Mechanical Properties of Organic-Inorganic Hybrids
OPTICAL AND PHOTONIC PROPERTIES
Optics: Photophysics, Waveguides, Fluorescence, Nonlinear Optical Properties
Photonics
ELECTRICAL, SEMICONDUCTOR AND MAGNETIC PROPERTIES
Ferroelectric and Piezoelectric Properties
Electrical Properties, Electrodes
Magnetic and Magnetooptical Materials
Transparent Materials and Semiconductors
Graphene-based Materials

VOLUME 3: APPLICATIONS

APPLICATIONS FOR MEMBRANES AND CATALYSTS
Catalysts, Biocatalysts, Photocatalysts
Sensors and Controlled Release Applications
ENVIRONMENT AND ENERGY
Solar Cells
Battery and Fuel Cell Applications
Sol-Gel Derived Silicate Based Composites
Sol-Gel Protective, Conservation and Decorative Coatings
Green Materials
Solar and Space applications
APPLICATIONS TO ORGANIC AND BIO-MATERIALS
Fullerene, Nano-Composites, Nanotubes
Biomedical Applications
Entrapment and Encapsulation of Organic Molecules, Enzymes, Antibodies and Bacteria
FUNCTIONAL MATERIALS
Colored Coatings (Dyes, Metals and Pigments)
Micropatterning
Reflective and Antireflective Coatings
Coatings Applied to Windows and Devices
PHOTONIC SENSORS INCLUDING BIOSENSORS
Applications of PDMS as Microfluidic Channels in Sensor Devices
Enzyme Sensors
Using Sol-Gel Processes to Make Laser Devices
INDUSTRIALIZATION OF SOL-GEL SCIENCE & TECHNOLOGY AND INNOVATIVE APPLICATIONS
Practical Examples
Others
PART I: SOL-GEL CHEMISTRY AND METHODS
Chemistry and Fundamentals of the Sol?Gel Process
Nonhydrolytic Sol?Gel Methods
Integrative Sol?Gel Chemistry
Synthetic Self-Assembly Strategies and Methods
Processing of Sol?Gel Films from a Top-Down Route
Sol?Gel Precursors

PART II: SOL-GEL MATERIALS
Nanoparticles and Composites
Oxide Powders and Ceramics
Thin Film Deposition Techniques
Monolithic Sol?Gel Materials
Hollow Inorganic Spheres
Sol?Gel Coatings by Electrochemical Deposition
Nanofibers and Nanotubes
Nanoarchitectures by Sol?Gel from Silica and Silicate Building Blocks
Sol?Gel for Metal Organic Frameworks (MOFs)
Silica Ionogels and Ionosilicas Aerogels
Ordered Mesoporous Sol?Gel Materials: From Molecular Sieves to Crystal-Like Periodic Mesoporous Organosilicas
Biomimetic Sol?Gel Materials

PART III: CHARACTERIZATION TECHNIQUES FOR SOL-GEL MATERIALS
Solid-State NMR Characterization of Sol?Gel Materials: Recent Advances
Time-Resolved Small-Angle X-Ray Scattering
Characterization of Sol?Gel Materials by Optical Spectroscopy Methods
Properties and Applications of Sol?Gel Materials: Functionalized Porous Amorphous Solids (Monoliths)
Sol?Gel Deposition of Ultrathin High-¿ Dielectric Films

PART IV: PROPERTIES
Functional (Meso)Porous Nanostructures
Sol?Gel Magnetic Materials
Sol?Gel Electroceramic Thin Films
Organic?Inorganic Hybrids for Lighting
Sol?Gel TiO2 Materials and Coatings for Photocatalytic and Multifunctional Applications
Optical Properties of Luminescent Materials
Better Catalysis with Organically Modified Sol?Gel Materials
Hierarchically Structured Porous Materials
Structures and Properties of Ordered Nanostructured Oxides and Composite Materials

PART V: APPLICATIONS
Sol?Gel for Environmentally Green Products
Sol?Gel Materials for Batteries and Fuel Cells
Sol?Gel Materials for Energy Storage
Sol?Gel Materials for Pigments and Ceramics
Sol?Gel for Gas Sensing Applications
Reinforced Sol?Gel Silica Coatings
Sol?Gel Optical and Electro-Optical Materials
Luminescent Solar Concentrators and the Ways to Increase Their Efficiencies
Mesoporous Silica Nanoparticles for Drug Delivery and Controlled Release Applications
Sol?Gel Materials for Biomedical Applications
Self-Healing Coatings for Corrosion Protection of Metals
Aerogel Insulation for Building Applications
Sol?Gel Nanocomposites for Electrochemical Sensor Applications

Textauszug

List of Contributors

Carole Aimé

Sorbonne Universités

UPMC Univ Paris 06

CNRS, UMR 7574

Laboratoire de Chimie de la Matière Condensée de ParisJussieu

75005 Paris

France

Rui M. Almeida

Universidade de Lisboa

Instituto Superior Técnico

Departamento de Engenharia Química/CQE

Av. Rovisco Pais

1049-001 Lisbon

Portugal

David Almendro

CSIC

Instituto de Ciencia de Materiales de Madrid (ICMM)

Sol-Gel Group (SGG)

Sor Juana Inés de la Cruz, 3

28049 Madrid

Spain

Mario Aparicio

CSIC

Instituto de Cerámica y Vidrio

Kelsen 5, Campus de Cantoblanco

28049 Madrid

Spain

Pîlar Aranda

CSIC

Insitituto de Ciencia de Materiales de Madrid

c/Sor Juana Inés de la Cruz 3

28049 Madrid

Spain

Paulo Almeida

University of Beira Interior

Chemistry Department and CICS – Health Sciences Research Centre

6200-001 Covilhã

Portugal

David Avnir

The Hebrew University of Jerusalem

Institute of Chemistry

Centre for Nanoscience and Nanotechnology

91904 Jerusalem

Israel

Florence Babonneau

Sorbonne UniversitésUPMC Univ Paris 06

CNRS – Collège de France

Laboratoire de Chimie de la Matière Condensée de Paris

11 place Marcelin Berthelot

75005 Paris

France

R. Backov

Université de Bordeaux

Centre de Recherche Paul Pascal

Office 115, UPR 8641-CNRS

115 Avenue Albert Schweitzer

33600 Pessac

France

Ruben Baetens

KU Leuven (KUL)

Department of Civil Engineering

3000 Leuven

Belgium

Alejandro Baeza

Universidad Complutense de Madrid

Instituto de Investigación Sanitaria Hospital 12 de Octubre i+12

Facultad de Farmacia

Departamento de Química Inorgánica y Bioinorgánica

Plaza Ramón y Cajal s/n

28040 Madrid

Spain

and

Center on Bioengineering, Biomaterials and Nanomedicine (CIBER-BBN)

Spain

Carolina Belver

Universidad Autónoma de Madrid

Departamento de Química Física Aplicada

Facultad de Ciencias

c/Francisco Tomás y Valiente 7

28049 Madrid

Spain

Rogier Besselink

University of Twente

MESA+ Institute for Nanotechnology

Drienerlolaan 5

7522 NB Enschede

The Netherlands

Sara A. Bilmes

Universidad de Buenos Aires

Facultad de Ciencias Exactas y

Naturales

INQUIMAE

Departamento de Química

Inorgánica

Analítica y Química Física

Pabellón 2

Intendente Güiraldes 2160

Ciudad Universitaria

C1428EHA Buenos Aires

Argentina

Jochanan Blum

The Hebrew University of Jerusalem

Institute of Chemistry

Centre for Nanoscience and Nanotechnology

91904 Jerusalem

Israel

Cédric Boissière

Université Pierre et Marie Curie (Paris VI)

Laboratoire de Chimie de la Matière Condensée de Paris

4 place Jussieu, Tour 54, E.5, C 54–55

75252 Paris Cedex

France

Christian Bonhomme

Université Pierre et Marie Curie

CNRS – Collège de France

Laboratoire de Chimie de la Matière Condensée de Paris

11 place Marcelin Berthelot

75005 Paris

France

José Maurício A. Caiut

University of São Paulo

FFCLRP

Department of Chemistry

Av. Bandeirantes 3900

14040-901 Ribeirão Preto

Brazil

María Lourdes Calzada

Consejo Superior de Investigaciones Científicas (CSIC)

Instituto de Ciencia de Materiales de Madrid (ICMM)

C/Sor Juana Inés de la Cruz, 3, Cantoblanco

28049 Madrid

Spain

Luis D. Carlos

University of Aveiro

Physics Department and CICECO

3810-193 Aveiro

Portugal

Hessel L. Castricum

University of Amsterdam

Van 't Hoff Institute for Molecular Sciences

Science Park 9041098 XH Amsterdam

The Netherlands

Yolanda Castro

CSIC

Instituto de Cerámica y Vidrio

Kelsen 5, Campus de Cantoblanco

28040 Madrid

Spain

Li-Hua Chen

Wuhan University of Technology

State Key Laboratory of Advanced Technology for Material Synthesis and Processing

Luoshi Road 122

Wuhan 430070

China

Seon-Jin Choi

Korea Advanced Institute of Science and Technology

Department of Materials Science and Engineering

291 Daehak-ro, Yuseong-gu

Daejeon 305-701

Republic of Korea

Rosaria Ciriminna

CNR

Istituto per lo Studio dei Materiali Nanostrutturati

via Ugo La Malfa 153

90146 Palermo

Italy

Montserrat Colilla

Universidad Complutense de Madrid

Instituto de Investigación Sanitaria Hospital 12 de Octubre i+12

Facultad de Farmacia

Departamento de Química Inorgánica y Bioinorgánica

Plaza Ramón y Cajal s/n

28040 Madrid

Spain

and

Center on Bioengineering, Biomaterials and Nanomedicine (CIBER-BBN)

Spain

Thibaud Coradin

Sorbonne Universités

UPMC Univ Paris 06

CNRS, UMR 7574

Laboratoire de Chimie de la Matière Condensée de ParisJussieu

75005 Paris

France

Olivier Dautel

Ecole Nationale Supérieure de Chimie de Montpellier

Architectures Moléculaires et Matériaux Nanostructurés

CNRS UMR 5253 ICGM

8 rue de l'Ecole Normale

34296 Montpellier Cedex

France

Enrico Della Gaspera

CSIRO

Materials Science and Engineering

Clayton, Victoria 3168

Australia

M. Depardieu

Université de Bordeaux

Centre de Recherche Paul Pascal

Office 115, UPR 8641-CNRS

115 Avenue Albert Schweitzer

33600 Pessac

France

Rupali Deshmukh

ETH Zurich

Department of Materials

Laboratory for Multifunctional Materials

Vladimir-Prelog-Weg 5

8093 Zurich

Switzerland

Verónica de Zea Bermudez

University of Trás-os-Montes e Alto Douro

Chemistry Department and CQ-VR

5000-801 Vila Real

Portugal

Molíria V. dos Santos

São Paulo State University – UNESP

Institute of Chemistry

Lab Mat Foton

CP 355

14801-970 Araraquara

Brazil

Bruce Dunn

University of California, Los Angeles

Department of Materials Science and Engineering

California NanoSystems Institute

410 Westwood Plaza

Los Angeles, CA 90095

USA

Alicia Durán

CSIC

Instituto de Cerámica y Vidrio

Kelsen 5, Campus de Cantoblanco

28040 Madrid

Spain

Eleni K. Efthimiadou

National Center of Scientific Research “Demokritos”

Institute of Nanoscience and Nanotechnology

Sol–Gel Laboratory

Agia Paraskevi Attikis

15310 Athens

Greece

Paolo Falcaro

CSIRO Process Science and Engineering

Materials Science and Engineering

Gate 5, Normanby Road

Clayton, VIC 3168

Australia

César Fernández-Sánchez

César Fernández-Sánchez

Consejo Superior de Investigaciones

Científicas (CSIC)

Instituto de Microelectrónica de

Barcelona (IMB-CNM)

Carrer dels Til.lers

Campus de la Universitat

Autònoma de Barcelona

08193 Bellaterra, Catalunya

Spain

Rute Amorim S. Ferreira

University of Aveiro

Physics Department and CICECO

3810-193 Aveiro

Portugal

Vânia Teixeira Freitas

University of Aveiro

Physics Department and CICECO

3810-193 Aveiro

Portugal

Shuhei Furukawa

Kyoto University

Institute for Integrated Cell Material Sciences (WPI-iCeMS)

Yoshida, Sakyo-ku

Kyoto 606–8501

Japan

Marco Faustini

Université Pierre et Marie Curie (Paris VI)

Laboratoire de Chimie de la Matière Condensée de Paris

4 place Jussieu, Tour 54, E.5, C 54–55

75252 Paris Cedex

France

Andrea Feinle

Salzburg University

Materials Chemistry

Hellbrunner Straße 34

5020 Salzburg

Austria

Francisco M. Fernandes

Sorbonne Universités

UPMC Univ Paris...

Produkt-Details

• Erscheint lt. Verlag: 3.9.2015
• Sprache: englisch
• Themenwelt: Naturwissenschaften ► Chemie
• Themenwelt: Technik
• Schlagworte: Anorganische Chemie • Chemie • Chemistry • Dünne Schichten, Oberflächen u. Grenzflächen • Dünne Schichten, Oberflächen u. Grenzflächen • Inorganic Chemistry • Materials Science • Materialwissenschaften • Nanomaterial • Nanomaterialien • nanomaterials • Nanostrukturiertes Material • Nanotechnologie • nanotechnology • Oberflächen- u. Kolloidchemie • Oberflächen- u. Kolloidchemie • Surface & Colloid Chemistry • synthesis shaping wet-chemical processes organic-inorganic hybrid powders particles fibers optical electrical magnetic properties diffraction NMR Raman IR membrane energy biomaterials photonics electronics • Thin Films, Surfaces & Interfaces
• ISBN-10: 3-527-67083-1 / 3527670831
• ISBN-13: 978-3-527-67083-3 / 9783527670833