Analysis of the New Metals (eBook)

Titanium, Zirconium, Hafnium, Niobium, Tantalum, Tungsten and Their Alloys

W. T. Elwell, D. F. Wood (Autoren)

eBook Download: PDF

2016 | 1. Auflage
288 Seiten
Elsevier Science (Verlag)
9781483185842 (ISBN)

Infos

Analysis of the New Metals: Titanium, Zirconium, Hafnium, Niobium, Tantalum, Tungsten and their Alloys focuses on methods for the analysis of titanium, zirconium, hafnium, niobium, tantalum, tungsten, and their alloys. Emphasis is on the procedures used in Imperial Metal Industries (Kynoch) Limited's laboratories for the analysis of these metals. These procedures include the oxide-resin procedure, solution procedure, and the point-to-plane spectrographic procedure. Comprised of six chapters, this book begins with an overview of special procedures for obtaining representative samples, including the use of titanium or zirconium sponge (Kroll process) as well as titanium granules (ICI sodium process). Subsequent chapters discuss the identification of titanium and its alloys such as aluminum, boron, calcium, carbon, and copper by means of the point-to-plane spectrographic procedure, a Fuess metal spectroscope, and chemical spot-tests; spectroscopic analysis of zirconium, zirconium alloys, and ionide-refined hafnium; and spectroscopic analysis of niobium, tantalum, tungsten, and their alloys. This monograph will be useful for undergraduate students, educators, practitioners, and researchers in metallurgy.

Inhalt

Front Cover 1
Analysis of The New Metals: Titanium, Zirconium, Hafnium, 
 
4 
Copyright Page 5
Table of Contents 6
PREFACE 10
ACKNOWLEDGEMENTS 13
CHAPTER I. INTRODUCTION 14
1. SAMPLING 14
2. GENERAL INFORMATION 17
CHAPTER II. TITANIUM AND ITS ALLOYS 22
3. TYPICAL SPECIFICATIONS (COMPOSITION)— TITANIUM PRODUCTS 22
4. ALUMINIUM 22
5. BORON 28
6. CALCIUM 32
7. CARBON 33
8. CHLORINE 41
9. CHROMIUM 46
10. COBALT 48
11. COPPER 52
12. HYDROGEN 57
13. IRON 63
14. MAGNESIUM 64
15. MANGANESE 75
16. MOISTURE 78
17. MOLYBDENUM 80
18. NICKEL 86
19. NITROGEN 90
20. OXYGEN AND HYDROGEN 95
21. PHOSPHORUS 108
22. SILICON 111
23. SILVER 116
24. SODIUM 117
25. TIN 122
26. TITANIUM 124
27. TUNGSTEN 129
28. VANADIUM AND CHROMIUM 134
29. ZINC 137
30. ZIRCONIUM 139
IDENTIFICATION OF TITANIUM ALLOYS 143
31. POINT-TO-PLANE SPECTROGRAPHIC PROCEDURE 143
32. USING A FUESS METAL SPECTROSCOPE 145
33. CHEMICAL SPOT-TESTS 149
CHAPTER III. ZIRCONIUM, HAFNIUM AND THEIR ALLOYS 151
34. TYPICAL ANALYSIS OF ZIRCONIUM, ZIRCONIUM ALLOYS AND HAFNIUM IONIDE-REFINED 151
35. ALUMINIUM 152
36. BORON 155
37. CADMIUM 160
38. CALCIUM 164
39. CARBON 168
40. CHLORINE 168
41. CHROMIUM 169
42. COBALT 171
43. COPPER AND MOLYBDENUM 174
44. HYDROGEN 177
45. IRON 177
46. LEAD 178
47. LITHIUM 180
48. MAGNESIUM 183
49. MANGANESE 183
50. MOLYBDENUM AND COPPER 183
51. NICKEL 185
52. NIOBIUM 186
53. NITROGEN 193
54. OXYGEN AND HYDROGEN 193
55. PHOSPHORUS 193
56. SILICON 193
57. SODIUM 194
58. TANTALUM 195
59. TIN AND LEAD 198
60. TITANIUM 205
61. TUNGSTEN 206
62. URANIUM 209
63. VANADIUM 212
64. ZINC 213
SPECTROSCOPIC ANALYSIS OF ZIRCONIUM, ZIRCONIUM ALLOYS AND HAFNIUM 215
65. IDENTIFICATION OF ZIRCONIUM ALLOYS: USING A FUESS METAL SPECTROSCOPE 217
66. IDENTIFICATION OF ZIRCONIUM ALLOYS I POINT-TO-PLANE PROCEDURE 218
67. IMPURITIES IN ZIRCONIUM: POINT-TO-PLANE PROCEDURE 218
68. IMPURITIES IN ZIRCONIUM! OXIDE-RESIN PROCEDURE 222
69. BORON, CADMIUM AND LEAD IN ZIRCONIUM: CARRIER-DISTILLATION PROCEDURE 229
70. RARE EARTHS IN ZIRCONIUM: OXIDE-RESIN PROCEDURE 231
71. CALCIUM IN ZIRCONIUM! OXIDE-RESIN PROCEDURE 236
72. IMPURITIES IN HAFNIUM: POINT-TO-PLANE PROCEDURE 237
73. IMPURITIES IN HAFNIUM: OXIDE-RESIN PROCEDURE 239
74. ZIRCONIUM IN HAFNIUM: SOLUTION PROCEDURE 242
75. ZIRCONIUM IN HAFNIUM: POINT-TO-PLANE PROCEDURE 244
76. ALLOYING CONSTITUENTS IN ZR20: X-RAY FLUORESCENCE PROCEDURE 245
CHAPTER IV. NIOBIUM AND ITS ALLOYS 247
77. TYPICAL SPECIFICATION (COMPOSITION) FOR REACTOR-GRADE NIOBIUM 247
78. ALUMINIUM 247
79. BORON 250
80. CARBON 250
81. CHROMIUM 250
82. COPPER AND ZINC 251
83. HYDROGEN 252
84. IRON 252
85. MOLYBDENUM AND TUNGSTEN 255
86. NICKEL 258
87. NITROGEN 259
88. OXYGEN AND HYDROGEN 260
89. SILICON 260
90. TITANIUM 261
91. TUNGSTEN 262
92. VANADIUM 264
93. ZIRCONIUM (OR HAFNIUM) 264
SPECTROSCOPIC ANALYSIS OF NIOBIUM 268
94. IMPURITIES IN NIOBIUM: OXIDE-RESIN PROCEDURE 269
95. BORON, CADMIUM, LEAD AND TIN IN NIOBIUM: CARRIER-DISTILLATION PROCEDURE 
273 
CHAPTER V. TANTALUM AND ITS ALLOYS 274
96. CARBON 274
97. IRON 274
98. MOLYBDENUM AND TUNGSTEN 274
99. NITROGEN 275
100. OXYGEN AND HYDROGEN 275
101. ZIRCONIUM 275
CHAPTER VI. TUNGSTEN AND ITS ALLOYS 277
102. BORON 277
103. CARBON 278
104. HYDROGEN 278
105. IRON 278
106. MOLYBDENUM 278
107. NICKEL 280
108. NITROGEN 280
109. OXYGEN AND HYDROGEN 281
110. PHOSPHORUS 281
111. TITANIUM 282
112. ZIRCONIUM (OR HAFNIUM) 282
APPENDICES 284
APPENDIX 1 284
APPENDIX 2 286
APPENDIX 3 288
INDEX 294

Produkt-Details

• Erscheint lt. Verlag: 29.7.2016
• Sprache: englisch
• Themenwelt: Naturwissenschaften ► Chemie ► Analytische Chemie
• Themenwelt: Technik ► Maschinenbau
• ISBN-13: 9781483185842 / 9781483185842