Molecular and Chemical Physics, Chemistry, Biological Effects, Geo and Planetary Sciences, New Resources, Dynamic Pressures, High Pressure Safety (eBook)
557 Seiten
Elsevier Science (Verlag)
9781483148526 (ISBN)
High Pressure Science and Technology, Volume 2 contains the proceedings of the Association Internationale for Research and Advancement of High Pressure Science and Technology's VIIth International Conference held in Le Creusot, France, from July 30 to August 3, 1979. The papers explore a wide range of topics relating to high pressure science and technology, including molecular and chemical physics; melting and dense fluids; liquid crystals; molecular thermophysical properties; light scattering; intermolecular spectroscopy; high-temperature, high-pressure fluids; and properties of earth materials. This volume is comprised of 128 chapters and begins by calculating equations of state for static molecular and metallic hydrogen using the density functional method. The following chapters discuss the effect of density on the induced near infrared absorption spectrum of solid molecular hydrogen at 4.2 K; vibrational relaxation in highly compressed hydrogen; the dual melting curves of carbon tetrachloride; and the statistical theory of polymorphic phase transitions and crystallization. Alkane chain conformation as a function of pressure is also examined, along with high pressure thermodynamics and phase equilibria of fluid mixtures. The remaining sections focus on the lithosphere, athenosphere, and the behavior of dense materials. This book will be a valuable resource for materials scientists, metallurgists, physicists, chemists, and mechanical engineers.
Front Cover 1
High Pressure Science and Technology 4
Copyright Page 5
Table of Contents 6
CONTENTS Volume 1 17
Part VI: MOLECULAR AND CHEMICAL PHYSICS 28
CHAPTER 1. MOLECULAR AND METALLIC HYDROGEN A UNIFIED DENSITY FUNCTIONAL APPROACH 28
ABSTRACT 28
ACKNOWLEDGMENT 33
CHAPTER 2. EFFECT OF DENSITY ON THE INDUCED NEAR INFRARED ABSORPTION SPECTRUM OF SOLID MOLECULAR HYDROGEN AT 4.2 K 35
REFERENCES 41
CHAPTER 3. MELTING OF 4He AT ROOM TEMPERATURE 42
ABSTRACT 42
1. INTRODUCTION 42
2 - EXPERIMENTAL 42
3 - RESULTS 44
4 - CONCLUSIONS 44
REFERENCES 45
CHAPTER 4. SOUND VELOCITY AND EQUATION-OF STATEMEASUREMENTS IN HIGH PRESSURE FLUID AND SOLID HELIUM 46
ABSTRACT 46
INTRODUCTION 46
EQUIPMENT 46
DISCUSSION 48
REFERENCES 48
CHAPTER 5. SOLID NITROGEN AT PRESSURES UP TO 410 KBAR 49
ABSTRACT 49
INTRODUCTION 49
EXPERIMENTAL 49
RESULTS AND DISCUSSION 50
ACKNOWLEDGMENT 51
CHAPTER 6. NEUTRON DIFFRACTION STUDY OF SOLID PARAHYDROGEN AT PRESSURE UP TO 5 KBAR 52
REFERENCES 54
CHAPTER 7. EQUATION OF STATE FOR NONTRANSITIONAL METALS AND METALLIC HYDROGEN 55
ABSTRACT 55
REFERENCES 58
CHAPTER 8. PROPERTIES OF H2, Kr, and Xe INSULATOR HYDRIDES 59
ABSTRACT 59
INTRODUCTION 59
RESULTS AND DISCUSSION 61
CONCLUSIONS 64
REFERENCES 64
CHAPTER 9. EXPERIMENTAL STUDY OF THE VIBRATIONAL RELAXATION (V-T) IN HIGHLY COMPRESSED HYDROGEN 65
INTRODUCTION 65
THEORETICAL MODELS 66
EXPERIMENTAL RESULTS AND DISCUSSION 67
CONCLUSION 70
REFERENCES 70
CHAPTER 10. ULTRASONIC VELOCITY RATIO MEASUREMENTS IN SOLID HYDROGEN TO PRESSURES IN EXCESS OF 60 KBAR 72
ABSTRACT 72
INTRODUCTION 72
EXPERIMENTAL DETAILS 72
RESULTS AND DISCUSSION 74
CHAPTER 11. THE DUAL MELTING CURVES OF CARBON TETRACHLORIDE 75
INTRODUCTION 75
EXPERIMENTAL APPARATUS 75
RESULTS AND DISCUSSION 76
REFERENCES 77
CHAPTER 12. TRIPLET INTERACTIONS IN DENSE NOBLE GASES 78
ABSTRACT 78
INTRODUCTION 78
POTENTIALS 78
RESULTS 79
THREE-BODY CONTRIBUTIONS 80
CONCLUSION 81
REFERENCES 81
CHAPTER 13. THE PHASE DIAGRAM OF ETHANE UNDER HIGH PRESSURE 82
ABSTRACT 82
INTRODUCTION 82
APPARATUS 82
RESULTS AND DISCUSSION 83
REFERENCES 84
CHAPTER 14. THE COEXISTENCE SURFACE OF NEON-XENON NEAR THE CRITICAL DOUBLE POINT 85
ABSTRACT 85
INTRODUCTION 85
RESULTS AND DISCUSSION 85
REFERENCES 87
CHAPTER 15. ON A STATISTICAL THEORY OF POLYMORPHIC PHASE TRANSITIONS AND CRYSTALLIZATION 88
REFERENCES 91
CHAPTER 16. LIQUID CRYSTALS AND PLASTIC CRYSTALS AT HIGH PRESSURE 92
ABSTRACT 92
INTRODUCTION 92
EXPERIMENTAL 94
HIGH PRESSURE RESULTS 95
ACKNOWLEDGEMENT 98
REFERENCES 98
CHAPTER 17. EQUATION OF STATE OF ORIENTATIONALLY DISORDERED SOLIDS AND INTERNAL PHONON RADIATION PRESSURE 99
INTRODUCTION 99
THERMODYNAMICS OF INTERNAL PRESSURE 100
DEFINITION 100
APPROXIMATIVE COMPRESSIBILITY DATA FOR 102
WORK OF INTERNAL PRESSURE DURING THERMAL EXPANSION 103
REFERENCES 104
CHAPTER 18. ELLIPTIC PHASE BOUNDARIES BETWEEN NEMATIC AND SMECTIC PHASES 106
ABSTRACT 106
DISCUSSION 109
REFERENCES 109
CHAPTER 19. SMECTIC POLYMORPHISM OF SOME BIS-(4,4'-n-ALKOXY-BENZYLIDENE)-1,4-PHENYLENEDIAMINES UP TO 3 KBAR BY DIFFERENTIAL THERMAL ANALYSIS (DTA) 110
ABSTRACT 110
INTRODUCTION 110
EXPERIMENTAL 110
RESULTS 110
CONCLUSIONS 111
REFERENCES 112
CHAPTER 20. ALKANE CHAIN CONFORMATION AS A FUNCTION OF PRESSURE 113
INTRODUCTION 113
EXPERIMENTAL 113
RESULTS AND DISCUSSION 115
CONCLUSIONS 115
REFERENCES 115
CHAPTER 21. DIELECTRIC CONSTANT AND PVT MEASUREMENTS ON PLASTIC CRYSTALS AT LOW TEMPERATURES UP TO 3000 BAR 116
ABSTRACT 116
APPARATUS 116
RESULTS AND COMMENTS 117
REFERENCES 118
CHAPTER 22. EQUATION OF STATE OF CRYSTALLINE AND SEMICRYSTALLINE POLYMERS 119
ABSTRACT 119
ASSUMPTIONS 119
RESULTS 120
CHAPTER 23. HIGH PRESSURE THERMODYNAMICS AND PHASE EQUILIBRIA OF FLUID MIXTURES: SURVEY AND RECENT RESULTS 122
ABSTRACT 122
INTRODUCTION 122
PHASE EQUILIBRIA IN FLUID BINARY MIXTURES CONTAINING CF4 AND CHF3 122
KINETICS OF LIQUID-LIQUID PHASE SEPARATION 124
REFERENCES 127
CHAPTER 24. THERMOPHYSICAL PROPERTIES OF NOBLE GASES AT ROOM TEMPERATURE UP TO 1 GPa 129
INTRODUCTION 129
EXPERIMENTAL APPARATUSES AND RESULTS 129
DISCUSSION 133
REFERENCES 135
CHAPTER 25. THE ELECTRICAL CONDUCTIVITY OF MOLTEN ALKALI METAL HALIDES AT HIGH PRESSURES 136
ABSTRACT 136
INTRODUCTION 136
EXPERIMENTAL 137
RESULTS AND DISCUSSION 137
ACKNOWLEDGEMENT 138
REFERENCES 138
CHAPTER 26. THE EFFECTS OF ISOTOPIC SUBSTITUTION IN THE DIFFUSION OF WATER UNDER PRESSURE 139
ABSTRACT 139
INTRODUCTION 139
EXPERIMENTAL 140
RESULTS 140
DISCUSSION 140
REFERENCES 141
CHAPTER 27. CORRELATION OF THE GLASS TRANSITION AND THE PRESSURE DEPENDENCE OF VISCOSITY IN LIQUIDS 142
CHAPTER 28. THE VISCOSITY OF ARGON AT PRESSURES UP TO 9 KBAR 144
ABSTRACT 144
EXPERIMENTAL PROCEDURE 144
RESULTS AND DISCUSSION 144
REFERENCES 146
CHAPTER 29. p-V-T RELATIONS FOR HBr-H2O MIXTURES UP TO 550° C AND 1500 BAR 147
INTRODUCTION 147
EXPERIMENTAL 147
RESULTS 148
REFERENCES 149
CHAPTER 30. P-V-T STUDY NEAR THE CRITICAL POINT OF A PURE SUBSTANCE 150
CHAPTER 31. THE EFFECT OF PRESSURE ON THE VELOCITY OF SOUND IN TOLUENE UP TO 2600 BAR 152
ABSTRACT 152
INTRODUCTION 152
APPARATUS 152
RESULTS AND DISCUSSION 152
REFERENCES 154
CHAPTER 32. ANALYSIS OF FORMAL DEFINITION OF THE FUGACITY 155
ABSTRACT 155
FUGACITY AND THE GIBBS FUNCTION 155
FUGACITY AND THE IDEAL GAS STATE 156
REFERENCES 158
CHAPTER 33. STUDY OF THE PRESSURE INDUCED MULTICRITICAL POINT OF NH4CI BY SECOND HARMONIC GENERATION OF LIGHT 159
ABSTRACT 159
SECOND HARMONIC EXPERIMENT 159
THEORETICAL INTERPRETATION 159
OPTICAL OBSERVATIONS 160
BIBLIOGRAPHY 160
CHAPTER 34. RAYLEIGH AND RAMAN DEPOLARIZED LIGHT SCATTERING BY ISOTROPIC MOLECULES 161
ABSTRACT 161
INTRODUCTION 161
GENERAL THEORY 161
REFERENCES 163
CHAPTER 35. THE DEPOLARIZATION FACTOR OF LIGHT SCATTERED FROM XENON NEAR ITS CRITICAL POINT 164
ABSTRACT 164
INTRODUCTION 164
THEORETICAL 164
EXPERIMENTAL RESULTS AND ANALYSIS 165
REFERENCES 166
CHAPTER 36. RECENT PROGRESS IN INFRARED RAMAN AND RAYLEIGH SPECTROSCOPY OF MOLECULAR INTERACTIONS IN DENSE FLUIDS 167
INTRODUCTION 167
ATOMS 167
HOMOPOLAR DIATOMICS 169
POLAR DIATOMICS 172
CONCLUSION 174
SUCCINT BIBLIOGRAPHY 174
CHAPTER 37. ANHARMONIC LATTICE VIBRATIONS IN SOLID a and .-N2 176
ABSTRACT 176
INTRODUCTION 176
CRYSTAL MODEL AND CALCULATION 177
RESULT AND DISCUSSION 177
CONCLUSION 178
CHAPTER 38. PRESSURE DEPENDENCE OF NUCLEAR QUADRUPOLE RESONANCE FREQUENCIES IN IONIC AND MOLECULAR SOLIDS 179
CHAPTER 39. FAR INFRARED SPECTROSCOPY OF MOLECULAR INTERACTIONS UNDER PRESSURE 181
ABSTRACT 181
INTRODUCTION 181
GENERAL ASPECTS OF PRESSURE EFFECT 181
EXPERIMENTAL CONDITIONS 182
COLLISION INDUCED ABSORPTION IN GAS AND LIQUID PHASES 183
MOLECULAR SOLIDS 184
BIBLIOGRAPHY 188
CHAPTER 40. FAR-INFRARED AND RAMAN STUDY OF SOLID CH4 UNDER HIGH PRESSURE 189
ABSTRACT 189
INTRODUCTION 189
RAMAN SPECTRA 190
FAR-INFRARED SPECTRA 190
CHAPTER 41. PRESSURE DEPENDENCE OF THE ABSORPTION SPECTRUM OF ß-CAROTENE 192
REFERENCES 192
CHAPTER 42. EFFECT OF HYDROSTATIC PRESSURE ON THE EXCITON ABSORPTION SPECTRA OF Cu2O CRYSTALS 193
ABSTRACT 193
INTRODUCTION 193
EXPERIMENTAL PROCEDURE 194
EXPERIMENTAL RESULTS 195
DISCUSSION 196
ACKNOWLEDGEMENTS 199
REFERENCES 199
CHAPTER 43. STUDIES ON SOLID NH3 AND CO2 TO 11 GPa 200
ABSTRACT 200
INTRODUCTION 200
EXPERIMENT 200
RESULTS 201
DISCUSSION 201
CONCLUSIONS 202
ACKNOWLEDGEMENTS 202
REFERENCES 202
CHAPTER 44. THE EFFECT OF PRESSURE ON THE RAMAN SPECTRUM OF NH4I 203
ABSTRACT 203
INTRODUCTION 203
REFERENCES 205
CHAPTER 45. MATRIX - ISOLATION - RAMAN -SPECTROSCOPY AT HIGH PRESSURE AND AT LOW TEMPERATURE 206
Abstract 206
Introduction 206
Experiments and Results 207
Discussion 207
CHAPTER 46. SPECTROSCOPIC STUDIES OF LOCAL CENTRES IN CRYSTALS UNDER HYDROSTATIC PRESSURE AT LOW TEMPERATURES: O2 IONS IN ALKALI HALIDES 209
ABSTRACT 209
INTRODUCTION 209
EXPERIMENTAL RESULTS AND DISCUSSION 209
REFERENCES 212
CHAPTER 47. HIGH PRESSURE PLASMA RESEARCH 213
CHAPTER 48. PVT DATA OF WATER AND CONCENTRATED NACI SOLUTIONS TO 600° C AND 4 KBAR 215
ABSTRACT 215
INTRODUCTION 215
EXPERIMENTAL 215
RESULTS AND DISCUSSION 216
ACKNOWLEDGEMENT 217
REFERENCES 217
CHAPTER 49. HIGH PRESSURE STUDIES OF LIQUID BISMUTH AND LIQUID LEAD 218
ABSTRACT 218
INTRODUCTION 218
LIQUID BISMUTH STUDY AT HIGH PRESSURE 218
THE MELTING OF LEAD AT HIGH PRESSURE 220
REFERENCES 220
CHAPTER 50. THERMAL CONDUCTIVITY AND DENSITY MEASUREMENTS OF LIQUID MERCURY 221
ABSTRACT 221
INTRODUCTION 221
EXPERIMENTAL DEVICES 221
RESULTS 222
Part VII: CHEMISTRY 224
CHAPTER 51. PROGRESS IN HIGH PRESSURE ASSISTED ORGANIC SYNTHESIS 224
ABSTRACT 224
INTRODUCTION 224
HIGH PRESSURE SYNTHESIS 224
CONCLUSION 230
REFERENCES 230
CHAPTER 52. HIGH-PRESSURE HIGH-RESOLUTION NUCLEAR MAGNETIC RESONANCE: PRESSURE DEPENDENCE OF THE HINDERED ROTATION OF THE AMIDEGROUP IN HIGHER AMIDES 231
CHAPTER 53. THE DECOMPOSITION OF DI-TERT. BUTYLPEROXIDE AT HIGH PRESSURES AND TEMPERATURES 234
ABSTRACT 234
INTRODUCTION 234
RESULTS AND DISCUSSION 234
CHAPTER 54. PAIRING UNDER PRESSURE 237
INTRODUCTION 237
References and Footnote 243
CHAPTER 55. POSITIVE AND NEGATIVE ACTIVATION VOLUMES IN THE DEALDOLIZATION OF DIACETONE ALCOHOL AT HIGH PRESSURE 244
CHAPTER 56. THE Q-e SCHEME AND THE PRESSURE DEPENDENCE OF REACTIVITY RATIOS IN FREE RADICAL MULTICOMPONENT POLYMERIZATIONS 246
ABSTRACT 246
INTRODUCTION 246
THE METHOD 246
CONCLUSION 247
REFERENCES 248
CHAPTER 57. EFFECT OF HIGH PRESSURE ON THE RATE OF ELECTRODE REACTION OF METAL COMPLEX 249
ABSTRACT 249
INTRODUCTION 249
EXPERIMENTAIS 250
RESULTS 250
DISCUSSIONS 250
CONCLUSION 250
LITERATURES 251
CHAPTER 58. HIGH-PRESSURE RADICAL POLYMERIZATION OF ETHYLENE BY MEANS OF A TUBULAR REACTOR THE PREHEATER OF WHICH IS REPLACED BY AN AUTOCLAVE REACTOR IN WHICH POLYMERIZATION TAKES PLACE 252
INTRODUCTION 252
EXPERIMENTAL RESULTS 252
POSSIBLE EXPLANATION 253
CHAPTER 59. EFFECT OF PRESSURE ON THE RATE OF LIQUID PHASE ISOMERIZATION OF DIETHYL MALEATE TO DIETHYL FUMARATE OVER A SOLID BASE CATALYST 254
ABSTRACT 254
INTRODUCTION 254
EXPERIMENTAL 254
RESULTS AND DISCUSSION 255
CHAPTER 60. HIGH PRESSURE GASPHASE COMBUSTION 257
Literature 263
CHAPTER 61. COMBUSTION OF LEAN GAS UNDER PRESSURE 264
CHAPTER 62. THE INTERPRETATION OF VOLUMES OF ACTIVATION OF CHEMICAL REACTIONS IN SOLUTION 267
REFERENCES 269
CHAPTER 63. NIR SPECTROSCOPIC DETERMINATION OF REACTION VOLUMES OF HYDROGEN BONDING EQUILIBRIA 270
ABSTRACT 270
INTRODUCTION 270
THEORETICAL 270
EXPERIMENTAL 271
RESULTS AND CONCLUSIONS 271
REFERENCES 272
CHAPTER 64. HIGH PRESSURE SYNTHESIS OF DIHYDROPYRANES AND DERIVATIVES 273
ABSTRACT 273
INTRODUCTION 273
RESULTS 273
REFERENCES 275
CHAPTER 65. RADICAL POLYMERIZABILITY OF N-(3,5-DI-TERT-BUTYL-4-HYDROXY)-BENZYLACRY LAMIDE UNDER HIGH PRESSURE 276
ABSTRACT 276
INTRODUCTION 276
EXPERIMENTAL 276
RESULTS AND DISCUSSION 277
CHAPTER 66. INFRARED SPECTROSCOPIC FLOW REACTORS FOR SOLID-FLUID REACTIONS AT HIGH TEMPERATURE AND PRESSURE 279
ABSTRACT 279
ACKNOWLEDGEMENT 281
VIII: BIOLOGICAL EFFECTS 282
CHAPTER 67. HIGH PRESSURE STOPPED-FLOW STUDIES OF FAST CONFORMATIONAL CHANGES IN PROTEINS 282
ABSTRACT 282
INTRODUCTION 282
CONFORMATIONAL EQUILIBRIUM IN CHYMOTRYPSIN 282
THE ALKALINE ISOMERIZATION OF CYTOCHROME 283
CONCLUSION 284
ACKNOWLEDGEMENT 284
REFERENCES 284
CHAPTER 68. THE EFFECT OF HIGH PRESSURES UPON PROTEIN-LIGAND COMPLEXES 285
CHAPTER 69. LYSOGENIC BACTERIA UNDER HIGH PRESSURES 286
ABSTRACT 286
INFLUENCE OF PRESSURE ON THE INDUCTION OF E. COLI CELLS LYSOGENIC FOR BACTERIOPHAGE LAMPA 286
MECHANISM OF PRESSURE EFFECTS ON BIOLOGICAL SYSTEMS 289
REFERENCES 292
CHAPTER 70. EFFECTS OF HELIUM PRESSURE ON BIOLOGICAL MEMBRANES. A PHARMACOLOGICAL APPROACH TO THE HIGH PRESSURE NERVOUS SYNDROME 293
ABSTRACT 293
References 295
IX: GEO AND PLANETARY SCIENCES 296
CHAPTER 71. A STUDY OF VELOCITY AND ABSORPTION OF ELASTIC WAVES IN ROCKS AT HIGH PRESSURES AND TEMPERATURES 296
ABSTRACT 296
CHAPTER 72. EXPERIMENTAL OBSERVATIONS OF POLYMORPHIC TRANSITIONS IN CALCITE UNDER HIGH PRESSURE 298
ABSTRACT 298
INTRODUCTION 298
HIGH PRESSURE APPARATI!S 298
POLYMORPHIC TRANSITIONS OF CALCITE 299
CONCLUSION 300
REFERENCES 300
CHAPTER 73. INTERNAL FRICTION IN TERRESTRIAL ROCKS AT HIGH PRESSURES 301
ABSTRACT 301
REFERENCES 303
CHAPTER 74. THE ROLE OF WATER IN QUARTZ DEFORMATION 304
ABSTRACT 304
CHAPTER 75. EXPERIMENTAL STUDY OF THE PRESSURE EFFECT ON THE VISCOSITY OF HYDROUS MAGMATIC MELTS 305
REFERENCES 307
CHAPTER 76. DIFFUSION COEFFICIENTS FOR MAJOR PETROGENIC OXIDES AND SOME COMPONENTS OF FLUID IN A WATERALBITE MELT AT HIGH PRESSURES AND TEMPERATURES 308
ABSTRACT 308
REFERENCES 310
CHAPTER 77. SOME NEW THEORETICAL RESULTS ON THE GRÜNEISEN PARAMETER 311
ABSTRACT 311
INTRODUCTION 311
GRÜNEISEN PARAMETER AND EQUATION OF STATE NEAR TO A PRESSURE INDUCËPPOLYMORPHIC PHASE TRANSITION 311
REFERENCES 314
CHAPTER 78. SEISMIC ANISOTROPY OF THE CLINOPYROXENES, OLIVINES AND GARNETS AT HIGH PRESSURE 315
ABSTRACT 315
INTRODUCTION 315
CLINOPYROXENES 315
OLIVINES 316
GARNETS 316
CHAPTER 79. SHAPE OF THE SELECTED PHASE SEPARATION SURFACES IN SOME AREAS WITHIN THE EARTH'S MANTLE 317
ABSTRACT 317
INTRODUCTION 317
CLAUSIUS-CLAPEYRON' S EQUATIONS 317
PHASE SEPARATION SURFACES 318
CHAPTER 80. ELECTRICAL CONDUCTIVITY MEASUREMENTS ON PYROXENES AND OLIVINES UNDER THERMODYNAMICALLY DEFINED CONDITIONS 321
ABSTRACT 321
INTRODUCTION 321
EXPERIMENTAL DETAILS 322
RESULTS OF THE CONDUCTIVITY MEASUREMENTS 323
DISCUSSION 325
REFERENCES 326
CHAPTER 81. RAMAN SPECTRA AND STRUCTURE OF STISHOVITE 328
ABSTRACT 328
EXPERIMENTAL 328
RESULTS 329
INTERPRETATION 330
REFERENCES 330
CHAPTER 82. ANALYSIS OF THE CONCOMITANT DENSITY AND REFRACTIVE INDEX CHANGES PRODUCED BY PRESSURE,TEMPERATURE AND NEUTRON IRRADIATION IN SILICA GLASS AND QUARTZ 331
ABSTRACT 331
INTRODUCTION 331
THEORETICAL CONSIDERATIONS 331
RESULTS 332
REFERENCES 333
CHAPTER 83. CHANGES OF THE ELASTICAL AND STRUCTURAL CHARACTERISTICS OF QUARTZ AT HIGH PRESSURE AND TEMPERATURE 334
ABSTRACT 334
CHAPTER 84. ETUDE PAR ANALYSE THERMIQUE DIFFERENTIELLE SOUS HAUTES PRESSIONS ET BASSES TEMPERATURES DES CHANGEMENTS D'ETAT DE CORPS DISPERSES 336
APPAREILLAGE 336
RESULTATS 337
BIBLIOGRAPHIE 338
X: NEW RESOURCES 339
CHAPTER 85. IN SITU FRACTURE RELATED TO ENERGY AND RESOURCE RECOVERY 339
ABSTRACT 339
INTRODUCTION 339
CONFINING PRESSURE 340
EXPLOSIVE SEQUENCING 340
HYDRAULIC FRACTURING 341
RUBBLE BEHAVIOR 342
REFERENCES 344
CHAPTER 86. APPAREILLAGE POUR L'ETUDE DU COMPORTEMENT DES ROCHES A KEROGENE SOUS PRESSION EN FONCTION DE DIFFERENTS FACTEURS 350
ABSTRACT 350
INTRoeucriasf 350
DESCRIPTION DE L'APPAREILLAGE 350
MODE OPERATOIRE 351
RENSEIGNEMENTS FOURNIS 352
CONCLUSION 353
CHAPTER 87. EXPLOSIVE-INDUCED DAMAGE IN POROUS SANDSTONE 354
APPLICATIONS OF HOT ISOSTATIC PRESSING FOR RADIOACTIVE WASTE CONTAINMENT IN SYNTHETIC MINERALS 361
HOT ISOSTATIC PRESSING OF REPROCESSING WASTES 362
MONOLITHIC SPENT FUEL CANISTERS OF SYNTHETIC CORUNDOM 362
REFERENCES 363
ABSTRACT 354
INTRODUCTION 354
DESCRIPTION OF THE EXPERIMENT 355
EXPERIMENTAL RESULTS 355
SCANNING ELECTRON MICROSCOPE ANALYSIS 356
NUMERICAL CALCULATIONS 357
CONCLUSION 360
ACKNOWLEDGEMENTS 360
REFERENCES 360
XI: DYNAMIC PRESSURES 364
CHAPTER 88. HIGH-PRESSURE AND HIGH-TEMPERATURE BEHAVIOR OF SIMPLE AND COMPLEX MOLECULAR LIQUIDS 364
ABSTRACT 364
INTRODUCTION 364
DIATOMICSYSTEMS: MOLECULAR HYDROGEN AND NITODGEN 366
HYDROCARBONS 368
REFERENCES 370
CHAPTER 89. HIGH PRESSURE EFFECTS ON THE MOLECULAR ELECTRONIC STRUCTURE OF CONDENSED EXPLOSIVES 371
ABSTRACT 371
CHAPTER 90. THERMODYNAMICAL EXPRESSIONS FOR THE PARAMETERS OF THE LINEAR RELATIONSHIP Us=a + bUp 372
INTRODUCTION 372
CHAPTER 91. COURBES DE FUSION A HAUTE PRESSION ET COEFFICIENT DE GRUNEISEN POUR QUELQUES METAUX 375
ABSTRACT 375
INTRODUCTION 375
LOI DE FUSION ET FORMULATION DU COEFFICIENT DE GRUNEISEN 376
CALCUL DE LA COURBE DE FUSION 376
RESULTATS NUMERIQUES 378
CONCLUSIONS 381
REFERENCES 381
CHAPTER 92. EQUATION OF STATE FOR QUADRATIC MATERIALS 382
CHAPTER 93. CALCUL DES POLAIRES DE CHOC DES CORPS A STRUCTURE ISOTROPE COMPACTE A L'AIDE DU POTENTIEL DE MORSE 383
SUMMARY 383
INTRODUCTION 383
I - Forme des équations d'état 383
II - Déterminatiom de la polaire de choc à partir du potentiel de MORSE 385
III - Applications 387
REFERENCES 391
CHAPTER 94. DETERMINATION THERMODYNAMIQUE DE LA LOI D'EVOLUTION DE LA POROSITE, POUR UN MATERIAU DUCTILE POREUX 392
INTRODUCTION 392
RECHERCHE DE LA LOI D'EVOLUTION DE LA POROSITE 392
DONNEES EXPERIMENTALES OBTENUES SUR LE FER POREUX 393
DEPOUILLEMENT DES DONNEES EXPERIMENTALES 393
DETERMINATION PRATIQUE DE LA LOI EXPERIMENTALE 394
CONCLUSION 394
REFERENCES 394
CHAPTER 95. SOME NEW DEVELOPMENTS IN SHOCK WAVE RESEARCH 395
ABSTRACT 395
INTRODUCTION 395
RECENT DEVELOPMENTS 395
CLOSURE 400
ACKNOWLEDGEMENTS 400
REFENCES 401
CHAPTER 96. LASER-GENERATED SHOCKWAVE EXPERIMENTS AT EXTREME HIGH PRESSURES 402
ABSTRACT 402
INTRODUCTION 402
DIAGNOSTICSFOR LASER-GENERATED SHOCK EXPERIMENTS 402
RELATED PHYSICS EXPERIMENTS 403
REFERENCES 404
CHAPTER 97. LASER DRIVEN SHOCK WAVES AND TWINNING IN IRON 405
ABSTRACT 405
INTRODUCTION 405
METALLURGICAL OBSERVATIONS IN LASER-SHOCKED IRON 405
SHOCK DECAY 406
REFERENCES 407
CHAPTER 98. IMPEDANCE-MATCH EXPERIMENTS USING LASER-DRIVEN SHOCK WAVES 408
INTRODUCTION 408
APPARATUS 408
IMPEDANCE-MATCHING EXPERIMENTS 408
CHAPTER 99. CRYSTAL LATTICE DEFORMATION OF SODIUM CHLORIDE SUBJECTED TO A SHOCK WAVE 411
INTRODUCTION 411
ANALYSIS OF THE RESULTS 412
REFERENCES 413
CHAPTER 100. FLASH X-RAY DIFFRACTION STUDIES TO 100 GPa 414
CHAPTER 101. PROSPECTS FOR GENERATING 1-10 TPa PRESSURES WITH A RAILGUN 416
ABSTRACT 416
INTRODUCTION 416
PRINCIPLE OF OPERATION 416
LIMITS OF OPERATION 417
SIMULATION OF RAILGUN PERFORMANCE 418
CONCLUSION 419
REFERENCES 419
Acknowledgements 419
CHAPTER 102. THE ELECTRIC GUN: A NEW METHOD FOR GENERATING SHOCK PRESSURES IN EXCESS OF 1 TPa 420
ABSTRACT 420
CHAPTER 103. THERMOSHOCK GENERATION IN SOLIDS IRRADIATED BY AN INTENSE PULSED RELATIVISTIC ELECTRON BEAM 423
Abstract 423
CHAPTER 104. HIGH VELOCITY PLANE LAUNCHING BY MULTIPLE STAGING DEVICE 427
ABSTRACT 427
INTRODUCTION 427
THE NUMERICAL CALCULATIONS 427
THE EXPERIMENTAL STUDY 428
THE COMPARISON CALCULATION-EXPERIMENT 428
CONCLUSION AND ACKNOWLEDGEMENTS 428
BIBLIOGRAPHY 428
CHAPTER 105. HUGONIOT MEASUREMENTS NEAR 50 MBAR 434
ABSTRACT 434
INTRODUCTION 434
MEASUREMENTS 435
RESULTS 437
References 440
CHAPTER 106. NUMERICAL CALCULATIONS OF EXPLOSION-INDUCED COMPRESSION OF MATTER IN CONICAL SYSTEM 441
CHAPTER 107. PRODUCTION OF SUPER-HIGH LOADS OF MATTER IN CONICAL EXPLOSION SYSTEMS 444
INTRODUCTION 444
EXPERIMENTAL RESEARCH 444
REFERENCES 449
CHAPTER 108. HUGONIOT ELASTIC LIMITS AND COMPRESSION PARAMETERS FOR BRITTLE MATERIALS 450
INTRODUCTION 450
EXPERIMENTAL METHOD 450
ELASTIC-PLASTIC BEHAVIOR 451
HUGONIOT ELASTIC LIMITS 452
HIGH STRESS REGIME 452
TEXT REFERENCES 453
CHAPTER 109. METALLOGRAPHIC INVESTIGATIONS ON PHASE TRANSITIONS IN IMPACT LOADED STEELS 460
INTRODUCTION 460
EXPERIMENTAL 460
METALLOGRAPHIC OBSERVATIONS 461
REFERENCES 462
CHAPTER 110. DETERMINATION EXPERIMENTALE DU COMPORTEMENT ELASTO-PLASTIQUE, SOUS CHOC, D'UN VERRE 463
INTRODUCTION 463
DETERMINATION DE LA LIMITE ELASTIQUE D HUGONIOT 463
MESURE DU DEVIATEUR DES CONTRAINTES 464
INTERPRETATION ET CONCLUSION 465
REFERENCES 465
CHAPTER 111. ELASTIC AND PLASTIC PROPERTIES OF URANIUM DIOXIDE FROM 5 TO 330 GPa 466
ABSTRACT 466
INTRODUCTION 466
PROCEDURE 466
MATERIALS 467
RESULTS 467
DISCUSSION 467
REFERENCES 469
CHAPTER 112. IMPACT INDUCED TENSILE FAILURE IN STEEL 470
ABSTRACT 470
APPROACH 470
RESULTS 471
CHAPTER 113. ELECTRICAL ACTIVITY IN SHOCK-LOADED POLYMERS 473
ABSTRACT 473
INTRODUCTION 473
SHOCK-INDUCED CONDUCTION 473
SHOCK-INDUCED POLARIZATION 477
SUMMARY 478
REFERENCES 479
CHAPTER 114. POSSIBLE SHOCK-INDUCED PHASETRANSITION IN Ca2GeO4, DEDUCED FROM ELECTRICAL CONDUCTIVITY MEASUREMENTS 481
ABSTRACT 481
INTRODUCTION 481
EXPERIMENTAL METHODS 481
RESULTS 482
REFERENCES 483
CHAPTER 115. SHOCK COMPRESSION OF LIQUID METHANE AND THE PRINCIPLE OF CORRESPONDING STATES 484
ABSTRACT 484
INTRODUCTION 484
EXPERIMENT 484
THEORY 486
ACKNOWLEDGEMENTS 488
REFERENCES 488
CHAPTER 116. ELECTRICAL CONDUCTIVITY OF SHOCKED WATER AND AMMONIA 489
ABSTRACT 489
INTRODUCTION 489
EXPERIMENT 489
References 491
CHAPTER 117. THERMAL RELAXATION IN A LIQUID UNDER SHOCK COMPRESSION 492
REFERENCES 494
CHAPTER 118. MEASUREMENTS ON THE HUGONIOT OF SAMARIUM 495
ABSTRACT 495
INTRODUCTION 495
EXPERIMENTAL APPARATUS 495
ACHIEVEMENT OF THE RESULTS 496
RESULTS 496
INTERPRETATION OF THESE RESULTS 496
ACKNOWLEDGEMENTS 496
BIBLIOGRAPHY 496
CHAPTER 119. FERROELECTRIC CERAMICS: ENERGY CONVERSION UNDER SHOCK WAVE 498
ABSTRACT 498
I. INTRODUCTION 498
II. EXPERIMENTAL PROCEDURE 498
III. EXPERIMENTAL RESULTS fcj 499
IV. DYNAMIC ADIABATIC CURVE OF PZT 500
REFERENCES 500
XII: HIGH PRESSURE SAFETY 501
CHAPTER 120. ASSESSMENT OF THE FRAGMENT HAZARD FROM RUPTURE OF HP VESSELS 501
Generation of Fragments 501
fragments.Fragment Initial Velocity 501
Fragment Flight 501
Fragment Penetration and Perforation into Reinforced Concrete Targets 502
Penetration into Other Targets 503
Overall Response of Target 503
Penetration into People 503
CHAPTER 121. SAFETY ASPECTS OF DESIGN, MANUFACTURE AND OPERATION OF FORGED VESSELS FOR HIGH PRESSURE SERVICE 504
INTRODUCTION 504
USER'S SPECIFICATION 504
DESIGN 504
MANUFACTURE 505
SERVICE 506
TROUBLES TO AVOID 507
CONCLUSION 508
References 508
CHAPTER 122. PROTECTION DES APPAREILS HAUTES PRESSIONS PAR RIDEAUX METALLIQUES FLEXIBLES 511
INTRODUCTION 511
RAPPEL SUR LE CALCUL DES RECIPIENTS SOUS HAUTES PRESSIONS. 511
RAPPEL SUR LES ENERGIES INTERNES DE DEFORMATION. 511
DEFINITION ET CALCUL DES PROTECTIONS METALLIQUES FLEXIBLES 512
ELEMENTS D'IDENTIFICATION D'UN RIDEAU METALLIQUE FLEXIBLE 513
REFERENCES 513
CHAPTER 123. PROBABILITY OF THE EARTHQUAKE INITIATED BY THE PHASE TRANSFORMATION FROM THE METASTABLE STATE 514
ABSTRACT 514
INTRODUCTION 514
THEPROBABILITY OF TRANSITION 514
GEOPHYSICAL IMPLICATIONS 517
CHAPTER 124. EXPLOSIVE CONTAINMENT 518
ABSTRACT 518
VESSELS 518
RESPONSE 519
CHAPTER 125. POST DEADLINE PAPERS 521
ABSTRACT 521
INTRODUCTION 521
SHOCK WAVE DATA AND THE CORE 522
CONCLUSIONS 525
ACKNOWLEDGMENTS 526
REFERENCES 526
CHAPTER 126. METHOD FOR PREPARING CUBIC BORON NITRIDE 528
INTRODUCTION 528
EXPERIMENTAL 528
DESCRIPTION OF THE MATERIAL 530
DISCUSSION 531
CHAPTER 127. ELASTICITY AND PHASE TRANSFORMATIONS IN RUTILESTRUCTURED COMPOUNDS 533
ABSTRACT 533
INTRODUCTION 533
DISCUSSION 534
ACKNOWLEDGMENT 540
REFERENCES 540
CHAPTER 128. RAMAN SPECTRA OF SUPERCRITICAL PHASES AND CRYSTALLINE SOLIDS OF n-H2 AND n-D2 UNDER VERY HIGH PRESSURES 542
ABSTRACT 542
INTRODUCTION 542
EXPERIMENTAL 542
RESULTS 542
DISCUSSION 543
REFERENCES 544
AUTHOR INDEX 546
SUBJECT INDEX 554
| Erscheint lt. Verlag | 23.5.2017 |
|---|---|
| Sprache | englisch |
| Themenwelt | Naturwissenschaften ► Chemie |
| Naturwissenschaften ► Physik / Astronomie ► Mechanik | |
| Technik ► Maschinenbau | |
| ISBN-13 | 9781483148526 / 9781483148526 |
| Informationen gemäß Produktsicherheitsverordnung (GPSR) | |
| Haben Sie eine Frage zum Produkt? |
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