Thermometric Titrimetry (eBook)

International Series of Monographs in Analytical Chemistry

L. S. Bark, S. M. Bark (Autoren)

R. Belcher, H. Freiser (Herausgeber)

eBook Download: PDF

2016 | 1. Auflage
138 Seiten
Elsevier Science (Verlag)
978-1-4831-5742-9 (ISBN)

Infos

Thermometric Titrimetry covers the significant progress in the application of thermometric titrimetry to routine analysis and as a research tool in the investigations of the basic phenomena associated with chemical reactions. This book is composed of 10 chapters and starts with a brief presentation of the basic principles of the technique. The succeeding chapters deal with the apparatus and several reactions involved in thermometric titrimetry, including neutralization, oxidation-reduction, and precipitation. A chapter focuses on the advantages of the technique for the determination of important commercial chemical, such as water and various chemical systems. The remaining chapters examine the use of some solvents as indicators, the industrial application of thermometric titrimetry, and an investigation of complex formation. This book will be of great value to analytical and laboratory chemists.

Inhalt

Front Cover 1
Thermometric Titrimetry 4
Copyright Page 5
Table of Contents 6
INTRODUCTION 8
CHAPTER 1. BASIC PRINCIPLES OF THE TECHNIQUE 12
THERMOMETRIC TITRATIONS 14
MULTICOMPONENT SYSTEMS 20
ORGANIC INDICATORS 23
SUMMARY 23
CALIBRATION TECHNIQUES FOR THERMOMETRIC ANALYSIS 25
REFERENCES 31
CHAPTER 2. APPARATUS 32
DIFFERENTIAL THERMOMETRIC TITRATIONS 42
REFERENCES 51
CHAPTER 3. NEUTRALISATION REACTIONS IN AQUEOUS SOLUTIONS 53
REFERENCES 60
CHAPTER 4. OXIDATION-REDUCTION REACTIONS 61
Potassium permanganate in acidic medium 61
Potassium dichromate 62
Peroxy compounds as oxidants 63
Cerium (IV) in acid solution 64
Hypochlorite as an oxidant 65
Iodine-thiosulphate reactions 65
Other reactants 67
REFERENCES 67
CHAPTER 5. PRECIPITATION REACTIONS 68
Precipitation of insoluble sulphates 68
The precipitation of halides 69
Oxalate as a precipitant 71
Miscellaneous precipitants 73
REFERENCES 75
CHAPTER 6. REACTIONS INVOLVING COMPLEX FORMATION 77
THE DETERMINATION OF METAL IONS VIA COMPLEX FORMATION 77
REFERENCES 90
CHAPTER 7. TITRATIONS IN NON-AQUEOUS MEDIA 92
ACID-BASE SYSTEMS 93
REFERENCES 104
CHAPTER 8. USE OF THE SOLVENT AS AN INDICATOR 105
CATALYMETRIC-THERMOMETRIC TITRATIONS 106
REFERENCES 110
CHAPTER 9. INDUSTRIAL ANALYSIS 111
PHARMACEUTICAL ANALYSIS 113
REFERENCES 114
CHAPTER 10. ADDITIONAL DATA AVAILABLE FROM ENTHALPOGRAMS 115
Investigations of complex formation 115
REFERENCES 125
AUTHOR INDEX 128
SUBJECT INDEX 132
OTHER TITLES IN THE SERIES IN ANALYTICAL CHEMISTRY 138

Produkt-Details

• Erscheint lt. Verlag: 27.10.2016
• Sprache: englisch
• Themenwelt: Naturwissenschaften ► Chemie ► Analytische Chemie
• Themenwelt: Technik
• ISBN-10: 1-4831-5742-3 / 1483157423
• ISBN-13: 978-1-4831-5742-9 / 9781483157429