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Metal-Organic Framework Materials (eBook)

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2014
John Wiley & Sons (Verlag)
978-1-118-93158-5 (ISBN)

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Metal-Organic Frameworks (MOFs) are crystalline compounds consisting of rigid organic molecules held together and organized by metal ions or clusters. Special interests in these materials arise from the fact that many are highly porous and can be used for storage of small molecules, for example H2 or CO2. Consequently, the materials are ideal candidates for a wide range of applications including gas storage, separation technologies and catalysis.  Potential applications include the storage of hydrogen for fuel-cell cars, and the removal and storage of carbon dioxide in sustainable technical processes. MOFs offer the inorganic chemist and materials scientist a wide range of new synthetic possibilities and open the doors to new and exciting basic research. 

Metal-Organic Frameworks Materials provides a solid basis for the understanding of MOFs and insights into new inorganic materials structures and properties. The volume also reflects progress that has been made in recent years, presenting a wide range of new applications including state-of-the art developments in the promising technology for alternative fuels. The comprehensive volume investigates structures, symmetry, supramolecular chemistry, surface engineering, recognition, properties, and reactions. 
The content from this book will be added online to the Encyclopedia of Inorganic and Bioinorganic Chemistry: http://www.wileyonlinelibrary.com/ref/eibc


Metal-Organic Frameworks (MOFs) are crystalline compounds consisting of rigid organic molecules held together and organized by metal ions or clusters. Special interests in these materials arise from the fact that many are highly porous and can be used for storage of small molecules, for example H2 or CO2. Consequently, the materials are ideal candidates for a wide range of applications including gas storage, separation technologies and catalysis. Potential applications include the storage of hydrogen for fuel-cell cars, and the removal and storage of carbon dioxide in sustainable technical processes. MOFs offer the inorganic chemist and materials scientist a wide range of new synthetic possibilities and open the doors to new and exciting basic research. Metal-Organic Frameworks Materials provides a solid basis for the understanding of MOFs and insights into new inorganic materials structures and properties. The volume also reflects progress that has been made in recent years, presenting a wide range of new applications including state-of-the art developments in the promising technology for alternative fuels. The comprehensive volume investigates structures, symmetry, supramolecular chemistry, surface engineering, recognition, properties, and reactions.

Leonard R. MacGillivray is an Associate Professor of Chemistry at the University of Iowa. His research focuses on processes of molecular self-assembly, particularly its application to organic synthesis. In 2002, he was awarded a 2002 National Science Foundation CAREER Award and a Research Corporation Research Innovation Award. In 2004, he received the Young Investigator Award of the Inter-American Photochemical Society and the Etter Early Career Award of the American Crystallographic Association. Dr. MacGillivray was elected a Fellow of the Royal Society of Chemistry in 2006 and received a 2007 Cope Scholar Award from the American Chemical Society. He has published 140 manuscripts and sits on six editorial boards. Charles M. Lukehart, Professor, Vanderbilt University in Nashville, Tennessee is Section Editor for Organometallic Chemistry and Solid State, Materials, Nanomaterials and Catalysis in King: Encyclopedia of Inorganic Chemistry, 2nd Edition.

Contributors xi

Series Preface xv

Volume Preface xvii

Part 1: Design and Synthesis 1

Porous Coordination Polymer Nanoparticles and Macrostructures 3
Julien Reboul and Susumu Kitagawa

Nanoscale Metal-Organic Frameworks 19
Kyriakos C. Stylianou, Inhar Imaz and Daniel Maspoch

Mesoporous Metal-Organic Frameworks 39
Yao Chen and Shengqian Ma

Porphyrinic Metal-Organic Frameworks 67
Chao Zou, Min Zhao and Chuan-De Wu

Fluorinated Metal-Organic Frameworks (FMOFs): Concept, Construction, and Properties 85
Pradip Pachfule and Rahul Banerjee

Synthesis and Structures of Aluminum-Based Metal-Organic Frameworks 99
Norbert Stock

Polyrotaxane Metal-Organic Frameworks 115
Stephen J. Loeb and V. Nicholas Vukotic

Photoreactive Metal-Organic Frameworks 135
Anjana Chanthapally and Jagadese J. Vittal

Edible Metal-Organic Frameworks 159
Ross Stewart Forgan

Mechanochemical Approaches to Metal-Organic Frameworks 173
Tomislav Friscic

Part 2: Post-Modification 193

Postsynthetic Modification of Metal-Organic Frameworks 195
Andrew D. Burrows

Part 3: Properties and Applications 219

Functional Magnetic Materials Based on Metal Formate Frameworks 221
Ran Shang, Sa Chen, Zhe-Ming Wang and Song Gao

Metal-Organic Frameworks from Single-Molecule Magnets 245
Athanassios D. Katsenis, Euan K. Brechin and Giannis S. Papaefstathiou

Open Metal Sites in Metal-Organic-Frameworks 259
Yabing He and Banglin Chen

Gas Storage in Metal-Organic Frameworks 283
Muwei Zhang, Hao Li, Zachary Perry and Hong-Cai Zhou

Metal-Organic Frameworks for Removal of Harmful Gases 303
Jian Liu, B. Peter McGrail, Denis M. Strachan, Jun Liu, Jian Tian and Praveen K. Thallapally

Adsorption of Hydrocarbons and Alcohols in Metal-Organic Framework Materials 321
Debasis Banerjee, Benjamin J. Deibert, Hao Wang and Jing Li

Metal Uptake in Metal-Organic Frameworks 343
Michaele J. Hardie

Photoreactive Properties Hosted in Metal-Organic Frameworks 363
Victoria J. Richards, Thomas J. Reade, Michael W. George and Neil R. Champness

Semiconducting Metal-Organic Frameworks 373
Zhengtao Xu

Patterning Techniques for Metal-Organic Frameworks 387
Paolo Falcaro and Mark J. Styles

Metal-Organic Frameworks in Mixed-Matrix Membranes 403
Harold B. Tanh Jeazet and Christoph Janiak

Electrochemical Properties of Metal-Organic Frameworks 419
Frédéric Jaouen and Adina Morozan

Applications of Metal-Organic Frameworks to Analytical Chemistry 443
Na Chang, Cheng-Xiong Yang and Xiu-Ping Yan

Recent Solid-State NMR Studies of Quadrupolar Nuclei in Metal-Organic Frameworks 457
Yining Huang, Jun Xu, Farhana Gul-E-Noor and Peng He

Part 4: Nets 471

Single-Crystal to Single-Crystal Transformations in Metal-Organic Frameworks 473
Subhadip Neogi, Susan Sen and Parimal K. Bharadwaj

Interpenetration and Entanglement in Coordination Polymers 523
Stuart R. Batten

Index 539

Contributors


Debasis Banerjee Rutgers University, Piscataway, NJ, USA
• Adsorption of Hydrocarbons and Alcohols in Metal-Organic Framework Materials
Rahul Banerjee CSIR-National Chemical Laboratory, Pune, India
• Fluorinated Metal-Organic Frameworks (FMOFs): Concept, Construction, and Properties
Stuart R. Batten Monash University, Melbourne, VIC, Australia and King Abdulaziz University, Jeddah, Saudi Arabia
• Interpenetration and Entanglement in Coordination Polymers
Parimal K. Bharadwaj Indian Institute of Technology Kanpur, Uttar Pradesh, India
• Single-Crystal to Single-Crystal Transformations in Metal-Organic Frameworks
Euan K. Brechin The University of Edinburgh, Edinburgh, UK
• Metal-Organic Frameworks from Single-Molecule Magnets
Andrew D. Burrows University of Bath, Bath, UK
• Postsynthetic Modification of Metal-Organic Frameworks
Neil R. Champness University of Nottingham, Nottingham, UK
• Photoreactive Properties Hosted in Metal-Organic Frameworks
Na Chang Tianjin Polytechnic University, Tianjin, PR China
• Applications of Metal-Organic Frameworks to Analytical Chemistry
Anjana Chanthapally National University of Singapore, Singapore
• Photoreactive Metal-Organic Frameworks
Banglin Chen University of Texas at San Antonio, San Antonio, TX, USA
• Open Metal Sites in Metal-Organic-Frameworks
Sa Chen Peking University, Beijing, PR China
• Functional Magnetic Materials Based on Metal Formate Frameworks
Yao Chen University of South Florida, Tampa, FL, USA
• Mesoporous Metal-Organic Frameworks
Benjamin J. Deibert Rutgers University, Piscataway, NJ, USA
• Adsorption of Hydrocarbons and Alcohols in Metal-Organic Framework Materials
Paolo Falcaro Commonwealth Scientific and Industrial Research Organization (CSIRO), Clayton South, VIC, Australia
• Patterning Techniques for Metal-Organic Frameworks
Ross Stewart Forgan University of Glasgow, Glasgow, UK
• Edible Metal-Organic Frameworks
Tomislav Friščić McGill University, Montreal, QC, Canada
• Mechanochemical Approaches to Metal-Organic Frameworks
Song Gao Peking University, Beijing, PR China
• Functional Magnetic Materials Based on Metal Formate Frameworks
Michael W. George University of Nottingham, Nottingham, UK
• Photoreactive Properties Hosted in Metal-Organic Frameworks
Farhana Gul-E-Noor The University of Western Ontario, London, ON, Canada
• Recent Solid-State NMR Studies of Quadrupolar Nuclei in Metal-Organic Frameworks
Michaele J. Hardie University of Leeds, Leeds, UK
• Metal Uptake in Metal-Organic Frameworks
Peng He The University of Western Ontario, London, ON, Canada
• Recent Solid-State NMR Studies of Quadrupolar Nuclei in Metal-Organic Frameworks
Yabing He Zhejiang Normal University, Jinhua, PR China
• Open Metal Sites in Metal-Organic-Frameworks
Yining Huang The University of Western Ontario, London, ON, Canada
• Recent Solid-State NMR Studies of Quadrupolar Nuclei in Metal-Organic Frameworks
Inhar Imaz ICN2 – Institut Catala de Nanociencia i Nanotecnologia, Barcelona, Spain
• Nanoscale Metal-Organic Frameworks
Christoph Janiak Heinrich-Heine-Universität, Düsseldorf, Germany
• Metal-Organic Frameworks in Mixed-Matrix Membranes
Frédéric Jaouen Université Montpellier II, Montpellier, France
• Electrochemical Properties of Metal-Organic Frameworks
Athanassios D. Katsenis National and Kapodistrian University of Athens, Athens, Greece
• Metal-Organic Frameworks from Single-Molecule Magnets
Susumu Kitagawa Kyoto University, Kyoto, Japan
• Porous Coordination Polymer Nanoparticles and Macrostructures
Hao Li Texas A&M University, College Station, TX, USA
• Gas Storage in Metal-Organic Frameworks
Jing Li Rutgers University, Piscataway, NJ, USA
• Adsorption of Hydrocarbons and Alcohols in Metal-Organic Framework Materials
Jian Liu Pacific Northwest National Laboratory, Richland, WA, USA
• Metal-Organic Frameworks for Removal of Harmful Gases
Jun Liu Pacific Northwest National Laboratory, Richland, WA, USA
• Metal-Organic Frameworks for Removal of Harmful Gases
Stephen J. Loeb University of Windsor, Windsor, ON, Canada
• Polyrotaxane Metal-Organic Frameworks
Shengqian Ma University of South Florida, Tampa, FL, USA
• Mesoporous Metal-Organic Frameworks
Daniel Maspoch ICN2 – Institut Catala de Nanociencia i Nanotecnologia, Barcelona, Spain and Institució Catalana de Recerca i Estudis Avançats (ICREA), Barcelona, Spain
• Nanoscale Metal-Organic Frameworks
Adina Morozan Université Montpellier II, Montpellier, France
• Electrochemical Properties of Metal-Organic Frameworks
Subhadip Neogi Indian Institute of Technology Kanpur, Uttar Pradesh, India
• Single-Crystal to Single-Crystal Transformations in Metal-Organic Frameworks
V. Nicholas Vukotic University of Windsor, Windsor, ON, Canada
• Polyrotaxane Metal-Organic Frameworks
Pradip Pachfule CSIR-National Chemical Laboratory, Pune, India
• Fluorinated Metal-Organic Frameworks (FMOFs): Concept, Construction, and Properties
Giannis S. Papaefstathiou National and Kapodistrian University of Athens, Athens, Greece
• Metal-Organic Frameworks from Single-Molecule Magnets
Zachary Perry Texas A&M University, College Station, TX, USA
• Gas Storage in Metal-Organic Frameworks
B. Peter McGrail Pacific Northwest National Laboratory, Richland, WA, USA
• Metal-Organic Frameworks for Removal of Harmful Gases
Thomas J. Reade University of Nottingham, Nottingham, UK
• Photoreactive Properties Hosted in Metal-Organic Frameworks
Julien Reboul Kyoto University, Kyoto, Japan
• Porous Coordination Polymer Nanoparticles and Macrostructures
Victoria J. Richards University of Nottingham, Nottingham, UK
• Photoreactive...

Erscheint lt. Verlag 19.9.2014
Reihe/Serie EIC Books
EIC Books
EIC Books
Sprache englisch
Themenwelt Naturwissenschaften Chemie Anorganische Chemie
Naturwissenschaften Chemie Organische Chemie
Technik Maschinenbau
Schlagworte Anorganische Chemie • Applications • arise • CARS • Chemie • Chemistry • compounds • crystalline • Example • FACT • Frameworks • Gas • highly • ideal candidates • Including • Inorganic Chemistry • many • Materials • Materials Science • Materialwissenschaften • Metal • Metallorganische Verbindungen • Metalorganic • MOFs • Molecules • Nanomaterialien • nanomaterials • Nanotechnologie • nanotechnology • organic • Poröse Materialien • Poröse Materialien • Porous • Porous Materials • Range • rigid • Special • Storage • wide
ISBN-10 1-118-93158-0 / 1118931580
ISBN-13 978-1-118-93158-5 / 9781118931585
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