In-situ Structure Characterization of Elastomers during Deformation and Fracture (eBook)

Karsten Brüning (Autor)

eBook Download: PDF

2014 | 2014
XIV, 124 Seiten
Springer International Publishing (Verlag)
978-3-319-06907-4 (ISBN)

Infos

This thesis offers novel insights into the time-dependent structural evolution of polymers under deformation. In-situ tensile experiments at high-brilliance synchrotron sources allowed to characterize the material with unrivaled resolution in time and space. The strain-induced crystallization in natural rubber was studied by wide-angle X-ray diffraction. Special emphasis was put on the establishment of new structure-property relationships to give a more in-depth understanding of the mechanical performance of rubber parts, e.g. in tear fatigue loading. To this end, the kinetics of strain-induced crystallization were investigated, subjecting the material to high strain rates. The local structure around a crack tip was observed by scanning wide-angle X-ray diffraction. Ultra-small angle X-ray scattering served to study filled elastomers under deformation, from specially prepared model filler systems to industrially relevant carbon black filled rubbers. Other methods include electron microscopy coupled with in-situ tensile testing and optical dilatometry to examine cavitation in rubbers.

The underlying theory as well as a literature review are covered by an extensive introductory chapter, followed by a description of the experimental techniques. The results are presented in more detail than in the original journal publications.

Inhalt

Introduction.- Motivation and Objectives.- Experimental.- Results.- Conclusion and Outlook.- Appendix.

Produkt-Details

• Erscheint lt. Verlag: 21.6.2014
• Reihe/Serie: Springer Theses
• Reihe/Serie: Springer Theses
• Zusatzinfo: XIV, 124 p. 82 illus., 51 illus. in color.
• Verlagsort: Cham
• Sprache: englisch
• Themenwelt: Naturwissenschaften ► Chemie ► Organische Chemie
• Themenwelt: Naturwissenschaften ► Physik / Astronomie
• Themenwelt: Technik ► Maschinenbau
• Schlagworte: Cavitation • Crystallization Kinetics • Elastomer Deformation and Fracture • Mechanical Properties of Polymers • Natural Rubber Reinforcement • Polymers Under Deformation • Strain-induced Crystallization • Synchrotron Small and Wide-Angle X-ray Scattering & Diffraction • Synchrotron X-ray Radiation • Time-dependent Structure Evolution in Polymers • WAXD, SAXS, USAXS, SEM
• ISBN-10: 3-319-06907-1 / 3319069071
• ISBN-13: 978-3-319-06907-4 / 9783319069074