Activated Metals in Organic Synthesis

P. Cintas (Autor)

Buch | Hardcover

256 Seiten

1993
Crc Press Inc (Verlag)
978-0-8493-7863-8 (ISBN)

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Activated Metals in Organic Synthesis discusses fundamental principles of the generation of activated, highly reactive metals, and their applications in organic synthesis. Following an introductory chapter on basic forms of metals the chapters in Part 1 are devoted to common strategies utilized for the preparation of active metals. These strategies include vaporization and subsequent co-condensation of metal atoms, in addition to depassivating methods employed commonly in laboratory syntheses. Chapters in Part 2 discuss relevant organic transformations in which metal activation plays a crucial role. Specific topics covered include metal-induced reductive methods; pinacolic, Reformatsky-, and Barbier-type reactions; McMurry ketone-olefin coupling; and the Bernet-Vasella reaction. Each chapter is followed by literature citations ranging from specific references to significant reviews. Many structural formulas are provided, making it easy to follow each synthesis. The book will be an important reference for students, organic chemists, and researchers in all areas of organometallic chemistry.

Cintas/, P.

Metal Activation: Basic Forms of Metals. Metal Vapor Chemistry. Depassivating Methods. Metal-Mediated Reactions: Reductions. Reductive Carbonyl Coupling Reactions. Addition Reactions to Carbonyl Compounds. Cyclizations. The Bernet-Vasella Reaction. Index.

Erscheint lt. Verlag	18.5.1993
Reihe/Serie	New Directions in Organic & Biological Chemistry
Zusatzinfo	4 Tables, black and white
Verlagsort	Bosa Roca
Sprache	englisch
Maße	156 x 234 mm
Gewicht	539 g
Einbandart	gebunden
Themenwelt	Naturwissenschaften ► Chemie ► Organische Chemie
ISBN-10	0-8493-7863-X / 084937863X
ISBN-13	978-0-8493-7863-8 / 9780849378638
Zustand	Neuware