Chemistry and Physics of Solid Surfaces VI

Ralf Vanselow, Russell Howe (Herausgeber)

Buch | Softcover

XVII, 667 Seiten

2011
Springer Berlin (Verlag)
978-3-642-82729-7 (ISBN)

Artikel merken

This volume contains review articles which were written by the invited speak ers of the seventh International Summer Institute in Surface Science (ISISS), held at the University of Wisconsin - Milwaukee in July 1985. The form of ISISS is a set of tutorial review lectures presented over a one-week period by internationally recognized experts on various aspects of surface science. Each speaker is asked, in addition, to write a review article on his lecture topic. No single volume in the series Chemistry and Physics of Solid Surfaces can possibly cover the entire field of modern surface science. However, the series as a whole is intended to provide experts and students alike with a comprehensive set of reviews and literature references, particularly empha sizing the gas-solid interface. The collected articles from previous Summer Institutes have been published under the following titles: Surface Science: Recent Progress and Perspectives, Crit. Rev. Solid State Sci. 4, 125-559 (1974) Chemistry and Physics of Solid Surfaces, Vols. I, II, and III (CRC Press, Boca Raton, FL 1976, 1979 and 1982), Vols. IV and V, Springer Ser. Chern. Phys., Vols. 20 and 35, (Springer, Berlin, Heidelberg 1982 and 1984). The field of catalysis, which has provided the major impetus for the de velopment of modern surface science, lost two of its pioneers during 1984 and 1985: Professors G.-M. Schwab (1899-1984) and p.k. Emmett (1900-1985).

1. Georg-Maria Schwab: Early Endeavours in the Science of Catalysis.- References.- 2. The Life and Times of Paul H. Emmett.- 3. Three Decades of Catalysis by Metals.- 3.1 Bifunctional Catalysis.- 3.2 Characterization of Dispersed Metals.- 3.2.1 Chemisorption Isotherms.- 3.2.2 Application of Extended X-Ray Absorption Fine Structure.- 3.2.3 Application of Nuclear Magnetic Resonance.- 3.3 Hydrocarbon Reactions on Metals.- 3.3.1 Hydrogenolysis.- 3.3.2 Hydrogenation and Dehydrogenation.- 3.3.3 Isomerization.- 3.4 Bimetallic Catalysts.- 3.4.1 Metal Alloys as Catalysts.- 3.4.2 Bimetallic Aggregates of Immiscible Components.- 3.4.3 Bimetallic Clusters.- 3.5 Summary.- References.- 4. Molecular Organometallic Chemistry and Catalysis on Metal-Oxide Surfaces.- 4.1 Synthesis.- 4.2 Structure Determination by Physical Methods.- 4.2.1 Infrared Spectroscopy.- 4.2.2 Laser Raman Spectroscopy.- 4.2.3 Inelastic Electron Tunneling Spectroscopy.- 4.2.4 Extended X-Ray Absorption Fine Structure Spectroscopy.- 4.2.5 Ultraviolet-Visible Reflectance Spectroscopy.- 4.2.6 Nuclear Magnetic Resonance (NMR).- 4.2.7 Temperature-Programmed Decomposition.- 4.2.8 High-Resolution Transmission Electron Microscopy.- 4.2.9 Other Methods and General Points.- 4.3 Reactivity.- 4.4 Catalytic Activity.- 4.5 Supported Metals with Simple Structures Derived from Supported Organometallics.- 4.6 Summary.- References.- 5. Catalysis by Molybdena-Alumina and Related Oxide Systems.- 5.1 Nature of the Catalyst.- 5.2 Nature of the Catalytic Centers.- 5.3 The Chemisorption of Hydrogen on the Catalytic Centers.- 5.4 Relationships with Catalysis.- References.- 6. Structure and Catalytic Performance of Zeolites.- 6.1 Introduction to Zeolites.- 6.2 Some Structural Considerations.- 6.3 Fundamentals of Catalysis by Zeolites: A Resumè.- 6.4 Converting a Zeolite to Its Catalytically Active Form.- 6.5 Influence of Intergrowths on Catalytic Performance.- 6.6 Siting and Energetics of Guest Species Inside Zeolite Catalysts.- 6.7 Evaluating Currently Unsolved Zeolitic Structures.- 6.8 Analogy Between Zeolitic and Selective Oxidation Catalysts.- References.- 7. Structural Characterization of Molecules and Reaction Intermediates on Surfaces Using Synchrotron Radiation.- 7.1 Principles of X-Ray Absorption.- 7.1.1 General Features.- 7.1.2 Surface Extended X-Ray Absorption Fine Structure.- 7.1.3 Near Edge X-Ray Absorption Fine Structure.- 7.1.4 Apparatus.- 7.2 SEXAFS Studies of Polyatomic Adsorbates.- 7.2.1 Structure of Formate on the Cu{100} Surface.- 7.2.2 Structure of Formate on the Cu{110} Surface.- 7.2.3 Structure of Methoxy on the Cu{100} Surface.- 7.3 NEXAFS Studies of Polyatomic Adsorbates.- 7.3.1 Oxidation Intermediates on Cu{100} and Cu{110}.- 7.3.2 Hydrocarbons on Pt{111}.- 7.3.3 Sulfur-Containing Hydrocarbons on Pt{111}.- 7.4 Conclusions and Outlook.- References.- 8. Effects of Surface Impurities in Chemisorption and Catalysis.- 8.1 Experimental Details.- 8.2 Discussion.- 8.2.1 Electronegative Impurities.- a) Chemisorption.- b) Catalytic Activity.- c) Catalytic Selectivity.- 8.2.2 Electroneutral Impurities.- a) Copper Overlayer Structure.- b) Chemisorption.- c) Catalytic Activity.- 8.2.3 Electropositive Impurities.- a) Chemisorption.- b) Carbon Monoxide Dissociation Kinetics.- c) Methanation Kinetics.- d) Promotion of Higher Hydrocarbon Formation.- e) Electronic Compensation Effects.- 8.2.4 Related Theory.- 8.3 Conclusions.- References.- 9. Thermodynamics and Kinetics in Weakly Chemisorbed Phases.- 9.1 Evaluation of the Isosteric Heat and Entropy of Adsorption.- 9.2 Correlation BetweenThermodynamic and Kinetic Experiments.- 9.3 Structural and Thermodynamic Data on Weakly Chemisorbed Phases.- 9.3.1 Phase Diagram for N2 Adsorbed on Ni{110} and Data for N2 on Ni {100}.- 9.3.2 The Isosteric Heat of Adsorption and the Entropy in the Adsorbed Phase for N2/Ni{110} and N2/NHIOO}.- 9.3.3 Carbon Monoxide on Low-Index Copper Single Surfaces.- 9.3.4 Thermodynamic Measurements at Very Small Coverages.-

Erscheint lt. Verlag	22.12.2011
Reihe/Serie	Springer Series in Surface Sciences
Zusatzinfo	XVII, 667 p.
Verlagsort	Berlin
Sprache	englisch
Maße	152 x 229 mm
Gewicht	984 g
Themenwelt	Naturwissenschaften ► Chemie ► Physikalische Chemie
	Naturwissenschaften ► Physik / Astronomie ► Atom- / Kern- / Molekularphysik
	Naturwissenschaften ► Physik / Astronomie ► Festkörperphysik
	Naturwissenschaften ► Physik / Astronomie ► Theoretische Physik
	Technik ► Maschinenbau
Schlagworte	catalysis • Chemistry • Surface • Surface Science
ISBN-10	3-642-82729-2 / 3642827292
ISBN-13	978-3-642-82729-7 / 9783642827297
Zustand	Neuware