Cyclic ß-Ketoesters
Synthesis & Reactions
Seiten
2010
Nova Science Publishers Inc (Verlag)
978-1-61668-282-8 (ISBN)
Nova Science Publishers Inc (Verlag)
978-1-61668-282-8 (ISBN)
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The chemistry of cyclic ss-ketoesters has received considerable attention because they serve as highly important intermediates in many organic synthesis. The wide application of these compounds in organic synthesis, depends chiefly on the reactivity of the methylene group. This title review the syntheses and reactions of cyclic ss-ketoesters.
The chemistry of cyclic ss-ketoesters has received considerable attention because they serve as highly important intermediates in many organic synthesis. The wide application of these compounds in organic synthesis, depends chiefly on the reactivity of the methylene group, and the ready hydrolysis of the ester group, and its substituted derivatives to carboxlic acids and ketones. The syntheses and reactions of cyclic ss-ketoesters are reviewed in a formal way.
The chemistry of cyclic ss-ketoesters has received considerable attention because they serve as highly important intermediates in many organic synthesis. The wide application of these compounds in organic synthesis, depends chiefly on the reactivity of the methylene group, and the ready hydrolysis of the ester group, and its substituted derivatives to carboxlic acids and ketones. The syntheses and reactions of cyclic ss-ketoesters are reviewed in a formal way.
Carboxylation of ketones; Intramolecular condensation & cyclization of Six-membered rings; Isomerization; Dieckmann condensation (intramolecular Claisen condensation); Miller & Nord Reaction:; Esters of *,*-diethylacetonedicarboxylic acid; Cyclic *-keto esters from cyclic ketones & ethyl cyanoacetate; Claisen acylation & carboethoxylation of ketones & esters; Homologation of ketones with ethyl diazoacetate; Synthesis of carboethoxycyclohexanone; Synthesis of carboethoxycyclohexanone; The enamine acylation & alkylation of carbonyl compound; Synthesis of 2-Carboethoxycyclohexanone; Synthesis of N-containing cyclic O-keto esters; Synthesis of N,N-Difluoro-O-ketoesters.
| Erscheint lt. Verlag | 1.7.2010 |
|---|---|
| Zusatzinfo | Illustrations |
| Verlagsort | New York |
| Sprache | englisch |
| Maße | 230 x 155 mm |
| Gewicht | 200 g |
| Themenwelt | Naturwissenschaften ► Chemie ► Organische Chemie |
| ISBN-10 | 1-61668-282-5 / 1616682825 |
| ISBN-13 | 978-1-61668-282-8 / 9781616682828 |
| Zustand | Neuware |
| Informationen gemäß Produktsicherheitsverordnung (GPSR) | |
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