Expert Level of Dental Resins - Material Science & Technology (eBook)

Detailed discussion of the formulation, production and properties of dental resins and dental resin composites.

Ralf Janda (Autor)

eBook Download: EPUB

2022 | 1. Auflage
1243 Seiten
tredition (Verlag)
978-3-347-71292-8 (ISBN)

Infos

Resin materials are broadly used in dentistry for almost all indications, and they will gain even more importance in the future. Especially the increasing performance and efficiency of the CAD/CAM technology and 3D-printing open possibilities to use resins which were not used up to now in dentistry. Besides dentists, dental students or dental technicians, there are many other specialists such as researchers, material scientists, industrial developers or experts of adjoining professional disciplines who are technically engaged in dental resins. The 'Expert Level' is the third book of the series 'Dental Resins - Material Science & Technology'. The 'Expert Level' includes all information and data presented in the 'Basic Level' and 'Advanced Level' of this series, but enormously expands the knowledge base. From a total database of 8.198 references, 1.707 were selected and used for this textbook. It comprises more than 1,000 manuscript pages, 384 figures and 124 tables. The 'Expert Level' describes very accurately and comprehensively all details of the material science and technology of dental polymers and composites. Furthermore, their production methods and applications are discussed in detail. Therefore, this book is a unique treatise of the complete present knowledge about dental resins and dental resin composites. This includes the discussion of the - raw/starting materials together with the explanation and presentation of their chemical structures and properties, their CAS Numbers and the names of the manufacturers. - amounts of the raw/starting materials usually used to formulate the finished products. - important material and toxicological properties of the starting materials and the finished products. - detailed description of the production processes of essential starting materials such as the syntheses of essential monomers, the silanization of inorganic fillers or the manufacturing of unfilled and filled splinter polymers. - detailed description of the formulation and the properties of the finished products. Furthermore, for many commercial endproducts rather detailed formulations as well as the exact production processes are described. All ISO standards that are relevant for dental resins are listed, too. Furthermore, many essential methods to test the mechanical, chemical and toxicological properties are also presented and explained. The 'Expert Level' enables every scientist with a good chemical knowledge not only to understand how dental polymers function, but also to develop new and improved products.

Ralf Janda was born in 1953 in Berlin. He obtained his Abitur (secondary school-leaving examination in 1973 and pursued chemistry at the Free University Berlin (FUB) from 1973 to 1978, thereby obtaining the degree Diploma-Chemist (summa cum laude). While working as a scientific assistant and researcher at the FUB he wrote his doctoral thesis and graduated in 1979 as a natural science doctor, Dr. rer. nat. (summa cum laude). His professional career as a scientific assistant and lecturer at the FUB came to an end in 1980. Ralf Janda also joined the dental industry in this year as head of research and development. He worked for many internationally leading dental companies (Kulzer GmbH, Germany, Degussa AG-Dental Division, today Degudent/Dentsply GmbH, Germany, Dentsply/Detech GmbH, Germany, Dentsply INC., USA, Dentaurum GmbH & Co. KG, Germany) in different leading positions as head of: R&D, production, quality assurance, dental technology, worldwide project leader until 2003. During this time, he was a member of many dental standard commissions, and from 1987 to 2000, he was also a member of the drug commission A at the drug institute of the Federal Republic of Germany. In 2003, he joined the cosmetic industry specialized on light-curing artificial nail products and stayed there until 2017. In addition to his professional pursuits, Ralf Janda has maintained a lengthy and extensive scientific career as a researcher and lecturer at numerous universities, beginning at the FUB in 1978. From 1988 to 1990, he was a lecturer at the Faculty of Material Sciences of the Technical University Berlin, where he taught resin composite materials. From 1991 to 1999, he worked as a researcher and lecturer for non-metallic dental materials at the dental department of the Medical Faculty of the Johann Wolfgang Goethe-University, Frankfurt/M. In 1992, he obtained his Habilitation (qualification for a teaching career at universities) and the degree Privatdozent (associate professor) in dental material science at the same university. From 1999 to 2004, Ralf Janda was Privatdozent at the Center of Dental Medicine of the Medical Faculty, Charité, Humboldt-University Berlin. From 2004 to 2021 he worked as a researcher and lecturer at the dental clinic of the Medical Faculty of the Heinrich Heine University, Düsseldorf. In 2006, he was appointed as apl. Professor (adjunct professor) in dental material science. Since 2021 he put his focus on writing textbooks about dental materials.

Textauszug

Abbreviations and Chemicals

Abbreviations important in the context of this book or the dental literature are given in accordance with IUPAC [80-83]. Information given here is important for all levels of this book series.

Monomers

4-Met = 4-methacryloyloxypropyl trimellitic acid (Fig. 74b-2)

4-Meta = 4-methacryloyloxypropyl trimellitic anhydride (Fig. 74b-2)

AA = acrylic acid (Fig. 17b)

BADEP = N,N'-diethyl-1,3-bis(acrylamido)-propane (Fig. 63e)

BDMA = butanediol dimethacrylates (Fig. 18b-1a)

Bis-EDMA(2) = bis-EMA(2) = 2,2-bis[4(3'-methacryloyloxy)ethoxyphenyl)]propane (Fig. 18b-1)

Bis-GMA = 2,2-bis[4(3'-methacryloyloxy-2'-hydroxy)propoxyphenyl]propane (Fig. 18b-1)

BMDU = methylene-4,4’-N,N’-bis-cyclohexylamine carbamate of 3-methacryloyl-2- hydroxypropoxy benzene (author’s knowledge) (Fig. 18b-1a)

BMP = bis-(2-methacryloyloxy)ethyl phosphate (Fig. 70e)

DiPEPA = dipentaerythritol monohydroxy pentaacrylate (Fig. 17b-1)

DDMA = 1,12-dodecandiol dimethacrylate (Fig. 18b-1)

EDMA = ethylene glycol dimethacrylate (Fig. 18b-1a)

EHA = 2-ethylhexyl acrylate (Tab. 2e)

EMA = ethyl methacrylate (Fig. 18ba-2)

Epoxy acrylate oligomer = 2,2-bis[acryloyloxy(2'-hydroxypropyloxy)phenyl]propane (Fig. 17b)

FurfurylMA = Furfuryl methacrylate (Fig. 18ba-2)

GDMA = glycerol dimethacrylate (Fig. 66e)

GPDM = glycerol phosphate dimethacrylate (Fig. 74b-1)

GPTA = glyceryl propoxy triacrylate = 3-[2,3-bis(3-prop-2-enoyloxypropoxy)propoxy]propyl prop-2-enoate (Fig. 17b-1)

HDDMA = 1,6-Hexanediol dimethacrylate (Fig. 18b-1)

HEMA = hydroxyethyl methacrylate (Fig. 18ba-2)

HPMA = hydroxypropyl methacrylate (Fig. 18ba-2)

HPPMA = 2-hydroxy-3-phenoxypropyl methacrylate (Fig. 73b)

i-BuMA = iso-butyl methacrylate (Fig. 18ba-2)

MA = methyl acrylate (Fig. 17b)

MASA = N-methacryloyl-5-aminosalicylic acid (Fig. 74b-2)

MDP = 10-methacryloyloxydecyl dihydrogen phosphate (Fig. 74b-1)

MDTP = MDTP = methacryloyloxydecyl dihydrogen thiophosphate (Fig. 132a-2)

MEP = 2-methacryloyloxyethyl dihydrogen phosphate (Fig. 74b-1)

MEPP = 2-methacryloyloxy ethylphenyl phosphate (Fig. 74b-1)

MMA = methyl methacrylate (Fig. 18ba-2)

MPS = 3-(methacryloyloxy)propyl trimethoxysilane (Fig. 41ba)

NMA = N-acryloylaspartic acid (Fig. 74b-2)

NMG = N-methacryloylglycine (Fig. 74b-2)

NP8EO8A = nonyl phenol (EO)8 acrylate (Fig. 17b)

PEG-400-DMA = polyethylene glycol 400 dimethacrylate (Fig. 18b-1a)

PENTA = dipentaerythritol pentaacrylate monophosphate (Fig. 74b-1)

PETMP = pentaerythritol tetra(3-mercaptopropionate) (Fig. 6e)

Phenyl-P = 2-methacryloyloxyethyl phenyl phosphate (Fig. 70e)

PMDM = pyromellitic dianhydrate dimethacrylate (Fig. 70e)

PMGDM = pyromellitic dianhydride glycerol dimethacrylate adduct (Fig. 74b-3)

TEGDMA = triethylene glycol dimethacrylate (Fig. 18b-1)

TMP9EOTA = ethoxylated trimethylolpropane triacrylate (Fig. 17b-1)

TMPMP = trimethylolpropane tris(3-mercaptopropionate) (Fig. 6e)

TRIM = 1,1,1-trimethylolpropane trimethacrylate (Fig. 18b-1a)

TTEGDMA = tetraethylene glycol dimethacrylates (Fig. 18b-1)

UDA = 7,7,9-trimethyl-4,13-dioxo-3,14-dioxa-5,12diazahexadecane-1,16-dioxy-diacrylate (Fig. 17b)

UDMA = 7,7,9-trimethyl-4,13-dioxo-3,14-dioxa-5,12-diazahexadecane-1,16-dioxy-dimethacrylate (Fig. 18b-1) VBATDT = 6-(4-Vinylbenzyl-n-propyl)-amino-1,3,5-triazine-2,4-dithiol (Fig. 132a-1)

Thermoplastics/Duromers

ABS = acrylonitrile butadiene styrene copolymer

APE = aromatic polyester

CA = cellulose acetate

E/P = ethylene propylene copolymer

EP = epoxy polymer, epoxide

ETFE = ethylene tetrafluoroethylene copolymer

EVA = ethylene vinyl acetate copolymer

HDPE = high density polyethylene

HMWPE = high molecular weight polyethylene

LDPE = low density polyethylene

LLDPE = linear low density polyethylene

MF = aminoplastic

PA = polyamide

PAA = polyacrylic acid

PAN = polyacrylonitrile

PBTP = polybutylene terephthalate

PC = polycarbonate

PDMS = polydimethylsiloxane

PE = polyethylene

PEEK = polyaryletheretherketone

PEMA = polyethyl methacrylate

PEI = polyetherimide

PEO = polyethylene oxide

PES = polyethersulfone

PETP = polyethylene terephthalate

PF = phenol formaldehyde resin, phenoplastic

PI = polyimide

PMMA = polymethyl methacrylate

POM = polyoxymethylene

PP = polypropylene

PPE = polyphenylene ether

PPO = polyphenylene oxide

PPS = polyphenylene sulfide

PS = polystyrene

PSU = polysulfone

PTFE = polytetrafluoroethylene

PU = polyurethane

PVAC = polyvinyl acetate

PVAL = polyvinyl alcohol

PVC = polyvinyl chloride

PVC-P = soft PVC - plasticized

PVC-U = hard PVC - unplasticized

Q = silicone rubber, silicone elastomer, polysiloxane rubber

SAN = styrene acrylonitrile copolymer

SB = styrene butadiene copolymer, high impact PS = HIPS

SP = saturated polyester

TPU = thermoplastic polyurethane

UF = urea-formaldehyde resin

UHMWPE = ultra high molecular weight polyethylene

UP = unsaturated polyester

VPE or XLPE = cross-linked polyethylene

Elastomers/Rubbers

ABR = acrylate butadiene rubber

AU = polyester urethane rubber

BR = butadiene rubber, polybutadiene

EPR = ethylene propylene rubber

E-SBR = styrene-butadiene rubber

EU = polyether urethane rubber

FKM = fluoro rubber

IIR = isoprene isobutene rubber = butyl rubber

IR = cis-1,4-polyisoprene = synthetic rubber

NBR = acrylonitrile butadiene rubber = nitrile rubber

NCR = acrylonitrile chloroprene rubber

NIR = acrylonitrile isoprene rubber

NR = natural rubber

PBR = vinylpyridine butadiene

PDMS = polydimethylsiloxane

PSO = polysiloxane

PSR = polysulfide rubber

Composite Resins/Composite Plastics

AFP = asbestos fiber-reinforced plastic

BFK = boric fiber-reinforced plastic

CFK = carbon fiber-reinforced plastic

FK = fiber-reinforced plastic

GFK = glass fiber-reinforced plastic

MFK = metal fiber-reinforced plastic

MWK = metal whiskers fiber-reinforced plastic

SFK = synthetic fiber-reinforced plastic

UD = unidirectional fiber-reinforced plastic

Initiators/Synergists/Catalysts/Stabilizers/Antioxidants

A1010 = pentaerythritol tetrakis[3-(3,5-di-tert.butyl-4-hydroxyphenyl)-propionate] (Fig. 47b)

benzpinacol (Fig. 45a)

BDK = benzyl dimethyl ketal (Fig. 35ba)

BEA = 2-n-butoxyethyl-4-(dimethylamino) benzoate (Fig. 52a)

BHT = 4-hydroxy-3,5-di-tert-butyltoluene (Fig. 47b)

BPO = DBPO = dibenzoyl peroxide (Fig. 27b)

CQ = camphorquinone (Fig. 33b)

copper naphthenate = Cu(II)-naphthenate mineral spirits (8 mass% Cu) (Fig. 23e)

DHEPT = N,N-bis(hydroxyethyl)-p-toluidine (Fig. 30ba)

DHPBZ = 2,5-dimehylhexane-2,5-diperbenzoate (Fig. 28ba)

DMAEMA = DMEM = 2-(dimethylamino)ethyl methacrylate (Fig. 52a)

DMAG = N,N-dimethylaminoglutethimide (Fig. 22e)

DMAPAA = 4-N,N-dimethylaminophenylacetic acid (Fig. 22e)

DMB = 2-(dimethylamino)ethyl benzoate (Fig. 52a)

DMPT = N,N-dimethyl-p-toluidine (Fig. 22e)

DMSX = N,N-dimethyl-sym-m-xylidine (Fig. 22e)

TBPEH = t-butyl-per-2-ethylhexanoate (Fig. 28ba)

TBPIN = t-butyl-perisononanoate (Fig. 28ba)

EPD = EDMAB = ethyl-4-(dimethylamino) benzoate (Fig. 52a)

EGDPM = 3-diethylamino-propionate methacrylate (Fig. 52a)

Ester chloride = beta-phenylethyl dibutylamino acetic acid ethyl ester chloride (Fig. 23e)

gamma-terpinene = p-mentha-1,4-diene (Fig. 4e)

HQ = hydroquinone (Fig. 46b)

HQME = hydroquinone monomethyl ether (Fig. 2e)

MBF = methyl benzoylformate (Fig. 49a)

NDMH = N,N'-dimethyl,-N,N'-di(methacryloxy ethyl)-1,6-hexanediamine...

Produkt-Details

• Erscheint lt. Verlag: 12.9.2022
• Reihe/Serie: Dental Resins - Material Science & Technology
• Reihe/Serie: Dental Resins - Material Science & Technology
• Verlagsort: Ahrensburg
• Sprache: englisch
• Themenwelt: Medizin / Pharmazie ► Zahnmedizin
• Schlagworte: 3D Printing • 4-Meta • Adhesion • alginate insulation • Anionic • Antioxidant • artificial teeth • autopolymerizing • bioactive composite • Bioadhesion • Bond strength • bulk-fill • cad/cam technology • camphorquionone • catalyst • cationic • ceramic resin bond • cojet • Color Stability • comosite coping • compomer • composite bridge frames • composite formulation • composite veneer • curing device • degree of conversion • Dental • Dental adhesives • Dental Composite • dental composites • dental curing devices • Dental materials • Dental materials science • Dental polymer • dental resin • dental resins • dental technology • dentin adhesive • dentin etchant • dentisry • denture base resins • denture reline resin • Dentures • discoloration • enamel adhesive • enamel dentin adhesives • enamel etchant • filler for resin composites • filling composite • finished product formulation • flexural modulus • flexural strength • formulation adhesive • free radical • Giomer • Hardness • heat curing • heat-curing • Hybrid composite • impression material • industrial production process • Inhibition • inhibition layer • initiator • intraoral scanning • Ivocerin • light-curing • light curing composite • Luting Cement • luting composite • manufacturer • manufacturing process • Material Testing • MDP • mechanical properties • metal resin bond • microfill • microfiller composite • micro-hybrid composite • Nanocomposite • Nanoparticle • Ormocer • Orthodontics • photo curing • photocuring • photoinitiator • Polyaddition • polyaddition silicone • polycondensation • polycondensation silicone • Polyether • Polymerization • polymerization rate • polysiloxanes • Polysulfide • Radiation curing • radical • Raw Materials • redox initiator • Resin cement • resin luting composite • resin resin bond • resin teeth • resin veneer • ring-opening polymerization • rocatec • Sealant • self-adhesive • self-adhesive composite • self curing • Self-curing • Self-etch • Shrinkage • shrinkage stress • silanes for dental filler • silanization process inorganic filler • silicoater • Silicone • Solubility • stabilizer • starting materials • sulfinic initiator • Surface energy • surface treatment • synthesis Bis-GMA • synthesis monomer • synthesis UDMA • TBB initiator • test method • thiol-ene • toxicity of dental resins • water sorption
• ISBN-10: 3-347-71292-7 / 3347712927
• ISBN-13: 978-3-347-71292-8 / 9783347712928